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what is the "electrochemical area" of a metal surface in a dielectric liquid and how is...

what is the "electrochemical area" of a metal surface in a dielectric liquid and how is it different from the geometrical surface area

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Electrochemical surface area is the as area of the surface where the electron transfer is taking place. On the other hand, the geometrical surface area is just the summation of the physical area covered by the metal surface. In reality the electrochemical surface area is always greater than the geometrical one. The ratio between electrochemical surface area to the geometrical surface area is called roughness factor.

The surface of the metal is not always smooth. So, for rough surface it gives more active sites for reaction. So it's important to have an idea about the electrochemical surface area to have idea about reaction rate.

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