Question

Learning Goal: To learn how to use the Nernst equation. The standard reduction potentials listed in...

Learning Goal:

To learn how to use the Nernst equation.

The standard reduction potentials listed in any reference table are only valid at standard-state conditions of 25 ∘C and 1 M . To calculate the cell potential at non-standard-state conditions, one uses the Nernst equation,

E=E∘−2.303RTnFlog10Q

where E is the potential in volts, E∘ is the standard potential in volts, R=8.314J/(K⋅mol) is the gas constant, T is the temperature in kelvins, n is the number of moles of electrons transferred, F=96,500C/(mol e−) is the Faraday constant, and Q is the reaction quotient.

Substituting each constant into the equation the result is

E=E∘−0.0592 Vnlog10Q

Figure

of 0

Consider the reaction

Mg(s)+Fe2+(aq)→Mg2+(aq)+Fe(s)

at 85 ∘C , where [Fe2+]= 3.50 M and [Mg2+]= 0.310 M .

Part A

Part complete

What is the value for the reaction quotient, Q , for the cell?

Express your answer numerically.

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--

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Correct

Part B

Part complete

What is the value for the temperature, T , in kelvins?

Express your answer to three significant figures and include the appropriate units.

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--

Q =

8.86×10−2

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Incorrect; Try Again; 6 attempts remaining

Part C

Part complete

What is the value for n ?

Express your answer as an integer and include the appropriate units (i.e. enter mol for moles).

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--

T

T T

=

317 Value K Units

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Part D

Part complete

Calculate the standard cell potential for

Mg(s)+Fe2+(aq)→Mg2+(aq)+Fe(s)

Express your answer to three significant figures and include the appropriate units.

n

n n

=

nothing Value nothing Units

0 0
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