Question

Does a reaction occur when aqueous solutions of potassium carbonate and lead(II) acetate are combined? If...

Does a reaction occur when aqueous solutions of potassium carbonate and lead(II) acetate are combined?
If a reaction does occur, write the net ionic equation. Use the solubility rules provided in the OWL Preparation Page to determine the solubility of compounds. Use the pull-down boxes to specify states such as (aq) or (s). If a box is not needed leave it blank.

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Answer #1

Yes, a precipitation reaction occurs between aqueous solution of potassium carbonate and lead(II) acetate.Precipitates of lead carbonate are formed in this reaction.

Molecular equation

K2CO3(aq)+Pb (CH3COO)2(aq) - - >2CH3COOK(aq)+PbCO3(s)

For writing ionic equation, dissociate soluble compounds into its ions. However, insoluble compounds or precipitates are not dissociated.

Ionic equation

2K+(aq) +CO32-(aq)+Pb2+(aq) +2CH3COO-(aq) ---->2CH3COO-(aq) +2K+(aq)+PbCO3(s)

For writing net ionic equation, cancel the ions that are common on both sides i. e. Spectator ions. K+ and CH3COO- are cancelled out on both sides of the equation.

Net ionic equation

CO32-(aq)+Pb2+(aq)--->PbCO3(s)

Carbonates are insoluble except carbonates of group 1 (alkali metals) like Na+,K+ etc. Or NH4+.Thus,potassium carbonate is soluble while lead carbonate is insoluble.

Acetates are soluble. That is why, both lead acetate and potassium acetate are soluble.  

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