Step 1: React phenol with sodium hydroxide Step 2: Add 2-Chlorobutane The product(s) is/are __________. an ether...
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Step 1: React phenol with sodium hydroxide
Step 2: Add 2-Chlorobutane
The product(s) is/are __________.
an ether
an alcohol
an ether and an alkene
an alkene
an alcohol and an alkene
In the reaction above, which type of reaction is occurring?
|
free radical halogenation |
||
|
acid-base followed by SN2 and E2 |
||
|
SN1 |
||
|
oxidation-reduction |
||
|
oxidation reduction followed by SN1 |
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Step 1: React phenol with sodium
hydroxide
Step 2: Add 2-Chlorobutane
The product(s) is/are __________.
an ether...
1. Why is it important to mix the phenol with sodium hydroxide before adding the chlorobutane?...
1. Why is it important to mix the phenol with sodium hydroxide before adding the chlorobutane? What happens during this time? 2. Why does phenol react with sodium hydroxide? Why does ethanol not react to the extent that phenol does with sodium hydroxide? 3. What is the better nucleophile, sodium phenoxide or phenol? Why? 4. Why do you need to rinse your product with ice water instead of room temperature water?
1) Consider the free radical monochlorination of 3-methylpentane and answer the following: a) How...
1) Consider the free radical monochlorination of 3-methylpentane and answer the following: a) How many products (including stereoisomers) are formed? _______ b) How many are chiral? ________ c) Would the major product of free radical bromination possess a chiral carbon? Yes or No 2) Which of the following functional groups can be generated in one step via SN2 or SN1 reaction? (Enter all that apply) a) Aldehyde b) Alcohol c) Alkene d) Alkyne e) Amine f) Carboxylic Acid g) Ester...
1) Consider the free radical monochlorination of 3-methylpentane and answer the following: a) How many products...
1) Consider the free radical monochlorination of 3-methylpentane and answer the following: a) How many products (including stereoisomers) are formed? _______ b) How many are chiral? ________ c) Would the major product of free radical bromination possess a chiral carbon? Yes or No 2) Which of the following functional groups can be generated in one step via SN2 or SN1 reaction? (Enter all that apply) a) Aldehyde b) Alcohol c) Alkene d) Alkyne e) Amine f) Carboxylic Acid g) Ester...
How would one go about synthesizing benzyl methyl ether via Williamson-Ether Synthesis from these chemicals available?...
How would one go about synthesizing benzyl methyl ether
via Williamson-Ether Synthesis from these chemicals available? The
5 chemicals (with red caps) in the top row from left to right are:
2-Chloro-norbornane, Benzyl chloride, 2-Chloro-2-methyl propane,
4-Chloro-1-butanol, and Chlorobutane.
Second question: What is the mechanism for said
reaction? (formula)
Reactions EXIT +-C1 HOMCI 9:39 Esterification Alcohol Halogenation Alkyl Halide Solvolysis Alkene Hydration Hydroboration Alkene Bromination Alkene Dihydroxylation Epoxidation Diels Alder Aldol Grignard Addition Benzene Nitration Friedel-Crafts Add Chloride Carbonyl Reduction...
1. In both the sodium iodide test and the silver nitrate test, why does 2-bromobutane react faster...
1. In both the sodium iodide
test and the silver nitrate test, why does 2-bromobutane react
faster than 2-chlorobutane?
Bromine is a better leaving group since it is a weaker base than
chlorine is.
2. a. Why does benzyl chloride react under both
SN1 and SN2 conditions?
Benzyl
chloride is a primary alkyl halide, hence reactive under SN2
conditions.
The
primary carbocation formed due to the departure of Cl- is
stabilized by the pi electrons in the benzene ring.
b. Why is...
C. Indicate which is the late-detemning step. d. Is it the same mechanism as in question...
C. Indicate which is the late-detemning step. d. Is it the same mechanism as in question 1? Why or why not? 3. Explain why El and Sx1 mechanisms follow first order reaction kinetics, whereas E2 and SN2 mechanisms follow second order reaction kinetics. 4. Which is the better nucleophile in a protic solvent: chloride ion or bromide ion? Try to explain this in terms of the nature of the chloride ion and the bromide ion. 5. For the synthesis of...
52.Which are the characteristics and factors that reactions? SN1: 3'alcehels,a altehels E3: laus factors that influence SN2, SN1, E2, E1, and ElcB s should be the major product and machanism...
52.Which are the characteristics and factors that reactions? SN1: 3'alcehels,a altehels E3: laus factors that influence SN2, SN1, E2, E1, and ElcB s should be the major product and machanism of he reaction bertween a secondary alyl halide and an alkoxide? ow can one determine whether an alkyl halide wil roduce a single alkene upon elimination with strong base? tween a tertiary alkyl halide and water? 55.What is the mechanism of the reaction be 56. What change could be made...
Question 28 1 pts Imagine that a scientist mixes bromoethane and sodium tert-butoxide in 2-methyl-2-propanol. What...
Question 28 1 pts Imagine that a scientist mixes bromoethane and sodium tert-butoxide in 2-methyl-2-propanol. What type of reaction is likely to predominate? Remember to consider the type of alkyl halide that is involved, and remember also to consider whether the anion will act predominantly as a base or as a nucleophile or as both a base and a nucleophile. If the latter, consider the figure below to guide your decision. Finally, remember to consider the Apka rule, as it...
CHEM 232 Discussion Section Worksheet 10 1. Identify the fundamental mechanism(s) (E occur in each reaction...
CHEM 232 Discussion Section Worksheet 10 1. Identify the fundamental mechanism(s) (E occur in each reaction and fill in the hoves with the missing reagent(s) or product is no reaction, write no reaction Label each reaction as an "oxidation or reducir Mechanism Product(s) Starting Material Reagent(s) NX-1 Hâ‚‚SO4 tai mechanism(s) (EL52 SML S2. SNAC, addition, acid/base) that the missing reagent(s) or product(s). If there reaction as an "oxidation" or "reduction." N.: 42 E2 +2-(+1)= + 1 oxidation N/A (radical) SNA,...
An unknown mixture (dissolved in diethyl ether) contains only 2 of the following : benzoic acid,...
An unknown mixture (dissolved in diethyl ether) contains only 2 of the following : benzoic acid, phenol, aniline and napthalene. You use the acid-base extraction method and want to identify the 2 compounds in your original mixture. 1) To separate the organic acid you add NaOH and to separate the organic base you add HCl.In both cases these extractions are followed by extractions with water. Why do we add water? Why is this step important? (A clear explanation please). 2)When...
1. Why is it important to mix the phenol with sodium hydroxide before adding the chlorobutane? What happens during this time? 2. Why does phenol react with sodium hydroxide? Why does ethanol not react to the extent that phenol does with sodium hydroxide? 3. What is the better nucleophile, sodium phenoxide or phenol? Why? 4. Why do you need to rinse your product with ice water instead of room temperature water?
How would one go about synthesizing benzyl methyl ether
via Williamson-Ether Synthesis from these chemicals available? The
5 chemicals (with red caps) in the top row from left to right are:
2-Chloro-norbornane, Benzyl chloride, 2-Chloro-2-methyl propane,
4-Chloro-1-butanol, and Chlorobutane.
Second question: What is the mechanism for said
reaction? (formula)
Reactions EXIT +-C1 HOMCI 9:39 Esterification Alcohol Halogenation Alkyl Halide Solvolysis Alkene Hydration Hydroboration Alkene Bromination Alkene Dihydroxylation Epoxidation Diels Alder Aldol Grignard Addition Benzene Nitration Friedel-Crafts Add Chloride Carbonyl Reduction...
1. In both the sodium iodide
test and the silver nitrate test, why does 2-bromobutane react
faster than 2-chlorobutane?
Bromine is a better leaving group since it is a weaker base than
chlorine is.
2. a. Why does benzyl chloride react under both
SN1 and SN2 conditions?
Benzyl
chloride is a primary alkyl halide, hence reactive under SN2
conditions.
The
primary carbocation formed due to the departure of Cl- is
stabilized by the pi electrons in the benzene ring.
b. Why is...
C. Indicate which is the late-detemning step. d. Is it the same mechanism as in question 1? Why or why not? 3. Explain why El and Sx1 mechanisms follow first order reaction kinetics, whereas E2 and SN2 mechanisms follow second order reaction kinetics. 4. Which is the better nucleophile in a protic solvent: chloride ion or bromide ion? Try to explain this in terms of the nature of the chloride ion and the bromide ion. 5. For the synthesis of...
52.Which are the characteristics and factors that reactions? SN1: 3'alcehels,a altehels E3: laus factors that influence SN2, SN1, E2, E1, and ElcB s should be the major product and machanism of he reaction bertween a secondary alyl halide and an alkoxide? ow can one determine whether an alkyl halide wil roduce a single alkene upon elimination with strong base? tween a tertiary alkyl halide and water? 55.What is the mechanism of the reaction be 56. What change could be made...
Question 28 1 pts Imagine that a scientist mixes bromoethane and sodium tert-butoxide in 2-methyl-2-propanol. What type of reaction is likely to predominate? Remember to consider the type of alkyl halide that is involved, and remember also to consider whether the anion will act predominantly as a base or as a nucleophile or as both a base and a nucleophile. If the latter, consider the figure below to guide your decision. Finally, remember to consider the Apka rule, as it...
CHEM 232 Discussion Section Worksheet 10 1. Identify the fundamental mechanism(s) (E occur in each reaction and fill in the hoves with the missing reagent(s) or product is no reaction, write no reaction Label each reaction as an "oxidation or reducir Mechanism Product(s) Starting Material Reagent(s) NX-1 Hâ‚‚SO4 tai mechanism(s) (EL52 SML S2. SNAC, addition, acid/base) that the missing reagent(s) or product(s). If there reaction as an "oxidation" or "reduction." N.: 42 E2 +2-(+1)= + 1 oxidation N/A (radical) SNA,...
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