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Starting with benzene, show a sequence of laboratory reactions which could be used to produce the...

Starting with benzene, show a sequence of laboratory reactions which could be used to produce the compound named in each part of this question:

A. m-Chloroethylbenzene

B. benzyl alcohol

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Answer #1

A. First we carry out Friedel Craft Acylation in presence of anhydrous AlCl3. The acylated product is then chlorinated. Acyl group is a meta directing deactivating group. Thus the chlorine ion gets at the meta position. Next we reduce the acyl group to ethyl group by H2

   

B. Here again we carry out Friedel Craft reaction. But instead of Acylation we carry out Alkylation. Thus we obtain Toluene. This toluene is then oxidised to benzoic acid using KMnO4 . The last step is to convert benzoic acid to benzyl alcohol by reduction using H2

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