Which of the following statements are FALSE, given the following
bond dissociation energies? Assume that bond energies accurately
determine heats of reaction. Check all that are false.
BE[H-H] = 436 kJ/mol
BE[H-N] = 393 kJ/mol
BE[H-O] = 460 kJ/mol
BE[O=O] = 499 kJ/mol
1. NH(g) + H2(g) ---> NH2(g) + H(g) is an exothermic reaction.
2.ΔH°f[H(g)] = 218 kJ/mol
3. ΔH°[H2O(g) ---> 2 H(g) + O(g)] = 920 kJ/mol
4. An H-H bond is stronger than an H-O bond.
5. ΔH°f[H2O(g)] = -234.5 kJ/mol
Which of the following statements are FALSE, given the following bond dissociation energies? Assume that bond...
Calculate the enthalpy for the reaction below using the following bond dissociation energies. • H-H 436 kJ/mol O-H 460 kJ/mol 0-0 180 kJ/mol • 0=0 498 kJ/mol H -774 kJ/mol -654 kJ/mol 654 kJ/mol 774 kJ/mol
1. Bond Dissociation Energies and Free Radicals Bond Bond Dissociation Energies (kJ/mol) Bond BDE Bond BDE (kJ/mol) (kJ/mol) H-H 436 CH3-H 439 H-F 570 CH3CH2-H 432 H-CI 432 (CH3CH2 413 BDE Bond (kJ/mol) 10-N 350 0-0 180 F-F O-H 0-C O-F 460 BDE (kJ/mol) | 200 180 159 | H-Br H-I 366 298 404 350 O-C1200 O-Br (CH3)3C-H C-C (sigma) C=C(pi) 210 C1-C1243 Br-Br 193 243 0 -I 220 I-I | 151 A. The enzyme methane monooxygenase catalyzes a remarkably...
Calculate AH® for the reaction using the given bond dissociation energies. CH, (g) +202(9) — CO2(g) + 2 H2O(g) Bond AH° (kJ/mol) 0-0 | 142 H-0 459 C-H 411 C=0 799 O=0 498 C-0 358 This reaction is kJ/mol AH° = O endothermic. O exothermic.
Part A. Given the bond dissociation energies (in kJ/mol) for the following diatomic molecules Cl2 (243), F2 (158), H2 (436), O2 (498), N2 (945) choose the one(s) that could be broken by using blue light (λ=465 nm). Part B. Given the bond energies (in kJ/mol) of the following bonds: F–F (155), F–Cl (193), and Cl–Cl (243), estimate the molar enthalpy of formation of ClF(g), that is find ∆H for the following reaction ½Cl2(g) + ½F2(g) → ClF(g)
8. Given the following bond dissociation energies, what is the AF" for the formation of hydrogen chloride? H2(g) + Cl2(g) → 2 HCI(g) Bond Energy (kJ/mol) Bond 436 243 432 H-H Cl-CI H-Cl A) 185 kJ/mol. B) -92.5 k.J/mol. C) 92.5 kJ/mol. D) -185 kJ/mol.? E) 277.5 kJ/mol.
Question 2 4 pts Use the given average bond dissociation energies (BDE) to estimate A Hreaction for the combustion of hydrogen in oxygen that produces water: 2H2 (8) + O26 --> 2H20 (6) Bond BDE(kJ/mol) H-H 436 0-0 498 H-O 460
Bond Dissociation Energies (for A-B Bond broken AH, kJ/mol Bond broken → A A4, kJ/mol + B) Bond broken mo H-H CH3CH2CH2-H (CH3)2CH-H (CH3)3C-H 436 423 413 400. H-Br 366 CH3CH2CH2-Br 294 (CH3)2CH-Br 298 (CH3)3C-Br292 Br-Br 193 H-CI 432 CH3CH2CH2-CI 354 (CH3)2CH-CI 355 (CH3)3C-CI 349 CI-CI 243 Alkane halogenation is a two-step reaction, as shown below. Using the table of bond dissociation energies, calculate the enthalpy of each step and the enthalpy of the overall reaction. Step 1: Number CH3CHCH3...
Given the following: O2 (g) + 2F2 (g)------> 2OF2 (g) delta H=+24.5 kJ/mol Bond dissociation energies: F2= 159 kJ/mol; O2 (double bond) = 498 kJ/mol Calculate the bond strength of the O-F bonds in OF2.
Calculate AH for the following reaction using the given bond dissociation energies. >co,g)+2H,0(g) AH° (kJ/mol) CHg)20,g) Bond 142 О-О Н-О 459 С-Н 411 799 O O 498 С-О 358 Number ΔΗ. kJ/ mol This reaction is endothermic exothermic
Question 6 0.5 pts The table below contains the bond dissociation energies for common bonds. 410 Dissociation energy Bond (kJ/mol) |C-c 350 CNC 611 C-H 350 (c=0 799 0-0 180 O=O 498 460 C-O H-o Calculate the bond dissociation energy required for breaking all the bonds in a mole of water molecules, H20. Express your answer numerically, in terms of kJ/mol, and to three significant figures.