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Organic Chemistry

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1. Predict the oxidation product of treating dihydronaphthalene with the reagents shown below. Only draw one enantiomer if more than one is possible. Include H'son chirality centers. (THF = tetrahydrofuran) (ABOVE)

2. Alcohols can be oxidized by chromic acid derivatives. One such reagent is pyridinium chlorochromate, (C5H5NH )(ClCrO3–), commonly known as PCC. Draw theproposed (neutral) intermediate and the organic product in the oxidation of 1-butanol by PCC when carried out in an anhydrous solvent such as CH2Cl2.image from custom entry tool
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Answer #1

1) OsO4 . THF CO 2) H2S OH OH ΟΗ HN OH

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