Sometimes equilibria for complex ions are described in terms of dissociation constants, Kd. For the complex ion AlF63− the dissociation reaction is:
AlF63− ⇌ Al3+ + 6F− and Kd = [Al3+][F−]6 divided by [AlF63−] =2×10−24
Calculate the value of the formation constant, Kf, for AlF63−.
Sometimes equilibria for complex ions are described in terms of dissociation constants, Kd. For the complex...
Silver (I) ions in aqueous solutions react with NH3(aq) to form a complex ion according to the following reaction: Ag+ + 2NH3(aq) ---> Ag(NH3)2+ with a formation constant, Kf of 1.5 x 107. Calculate the solubility in g/L, of AgCN(s) (Ksp = 2.2 x 10-16) in 0.75M NH3(aq)
Question #9 Release kinetics. The dissociation constant KD for the release of oxygen from oxymyoglobin is 10-6 M, where the KD = [Mb][O2]/[MbO2], the rate constant for the combination of O2 with myoglobin is 2 x 107 M-1s-1. a) What is the rate constant for the dissociation of O2 from myoglobin? b) What is the mean duration of the oxymyoglobin complex?
I need help with the formation constant (Kf) in question 3 at the bottom. anything else you might catch would be greatly appreciated as wel ? Please refer to the 'CALCULATIONS' section for help filling in the ponowing uvie. Equilibrium Concentrations anal Initial Concentrations (after mixing."before" rxn) [Fe3+ (SCN) (FeNCS2+1 | [Fe3+] [SCN) (sve question 2) 0.0bolcom/0.colum Tube 1 10.100M 1 (C) 10.ol 1o. oloom/0.000loom 6.43.10" 0.0099 3.65 1.560 Tube 3 |0.00 50omo.coolcom 4.85x100 .00495 5 1.03.10 Tube 4 16.002.500.oooloom...
Calculate concentration of species in a solution containing a complex ion. Close Problem In the presence of excess OH-, the Al3+(aq) ion forms a hydroxide complex ion, Al(OH)4-. Calculate the concentration of free Al3+ ion when 1.21×10-2 mol Al(CH3COO)3(s) is added to 1.00 L of solution in which [OH- ] is held constant (buffered at pH 12.60). For Al(OH)4-, Kf = 1.1×1033. [Al3+] = M
Complex Reaction Equilibria: EDTA Titrations 1. Adenosine triphosphate (ATP) is a tetradentate ligand. This means that ATP (A) binds to four metal ions. (B) binds to metal ions with a charge of 4+. (C) occupies six coordination positions of the metal ions only. (D) binds to divalent metal ions. (E) uses four atoms to bind to the metal ion. 2. Which of the following statements is true about an auxiliary complexing agent? (A) Increases the conditional formation constant (B) Forms...
In the presence of excess OH-, the Al3+(aq) ion forms a hydroxide complex ion, Al(OH)4-. Calculate the concentration of free Al3+ ion when 1.32×10-2 mol Al(NO3)3(s) is added to 1.00 L of solution in which [OH- ] is held constant (buffered at pH 13.00). For Al(OH)4-, Kf = 1.1×1033. [Al3+] = ?M
A) Consider the insoluble compound zinc hydroxide, Zn(OH)2. The zinc ion also forms a complex with ammonia. Write a balanced net ionic equation to show why the solubility of Zn(OH)2(s) increases in the presence of ammonia and calculate the equilibrium constant for this reaction. For Zn(NH3)42+, Kf = 2.9×109. Specify states such as (aq) or (s) and provide K. K = ______ B) Consider the insoluble compound nickel(II) hydroxide, Ni(OH)2. The nickel ion also forms a complex with cyanide ions....
Ethylenediamine (shown below) is a chelate that is typically abbreviated as "end" The formation constants, K_F, of octahedral Ni^2+ complex ions at 25 degree C are: Write the reactions for the formation and the formation constants (in terms of concentrations) for each complex ion The Delta H_f of the two complex ions are the same to two significant figures How do you explain the difference in formation constants? If NH_3 were added to an aqueous solution of [Ni(en)_3]^2+ such that...
A) Consider the insoluble compound cobalt(II) hydroxide , Co(OH)2. The cobalt(II) ion also forms a complex with ammonia . Write a balanced net ionic equation to show why the solubility of Co(OH)2(s) increases in the presence of ammonia and calculate the equilibrium constant for this reaction. For Co(NH3)62+, Kf = 7.7×104. Use the pull-down boxes to specify states such as (aq) or (s). _____ + _____ = _____ + _____ K = B) Consider the insoluble compound nickel(II) carbonate ,...
Be sure to answer all parts. Commercial silver-plating operations frequently use a solution containing the complex Ag+ ion. Because the formation constant (Kf) is quite large, this procedure ensures that the free Ag+ concentration in solution is low for uniform electrodeposition. In one process, a chemist added 9.0 L of 5.0 M NaCN to 90.0 L of 0.17 M AgNO3. Calculate the concentration of free Ag+ ions at equilibrium. See your textbook for Kf values. × 10 M (Enter your...