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20. Ethylenediaminetetraacetate (EDTA4-) is used as a complexing agent in chemical analysis. Solu...

20. Ethylenediaminetetraacetate (EDTA4-) is used as a complexing agent in chemical analysis. Solutions of EDTA4- are used to treat heavy metal poisoning by removing the heavy metal in the form of a soluble complex ion. The complex [Pb(EDTA]2- has Kf = 1.1 x 1018.

a. Calculate the concentration of Pb2+ in a saturated solution of Pb(OH)2, Ksp = 1.2 x 10-15.

b. Calculate the concentration of Pb2+ in a saturated solution of Pb(OH)2 buffered at pH 13.00

c. Calculate the concentration of Pb2+ in a 1.0 L solution containing 0.050 M Na4EDTA with 0.010 mole Pb(NO3)2 added (assume negligible volume change due to addition of this solid).

d. Consider a solution with 0.010 mole Pb(NO3)2 added to 1.0 L of an aqueous solution buffered at pH = 13.00 and also containing 0.050 M Na4EDTA. Does Pb(OH)2 precipitate from this solution?

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