Question

2. The arrows in the Jablonski diagram of Scheme 1 represent transformations that can be written explicitly as reactions, and thus have rate laws and rate constants associated with thenm For each arrow in the Jablonski diagram, write a chemical equation that represents that arrow. Example: Ru(bpy)*Ru(by)+ hv is the arow labelled emission. Please note that light (hv) should be indicated as a product or reactant where appropriate. Straight line arrows indicate processes involving light, wavy line arrows indicate processes not involving light, and bold arrows indicate processes involving the collision of two molecules. a. b. For each chemical equation, write the rate law. Example: rate kemiolRu(bpy) [DPA 2+1 [Ru(bpy)h" ISC Ru(bpy)al Emission IDPA TTA Emission TTTET Abs Non-Radiative Decay Decay 2 Times 2. [Ru(bpy)hl Scheme1. Mechanism, energetics of photochemical upconversion with [Ru(bpy)sP and DPA

Answer 1

enial Rea hion! Ru (bpy)s) Ru (bpy),J 2f A NRD 1 IDPA 2t 2t * Rat: + kew.mt Ru (lpy)3ј". kN.DtRu (lpYATTem.[Ru(beyn CS Scanned with CamScanner