Question

A solution containing the following was prepared: 0.15 M Pb2. 1.5% 10.6 M Pb4t, 1.5x 106 M Mn2. 0.15 M MnO4, and 0.88 M HNO3.

C) Calculate the value of Ece for this system at equilibrium. Number cell D) Determine the pH at which the given concentratio

A solution containing the following was prepared: 0.15 M Pb2. 1.5% 10.6 M Pb4t, 1.5x 106 M Mn2. 0.15 M MnO4, and 0.88 M HNO3. For this solution, the following balanced reduction half-reactions and overall net reaction can occur E-1.690 V E1.507 v A) Determine Eocell. AG®, and K for this reaction Number Number Number cell B) Calculate the value for the cell potential, Ecel, and the free energy, AG, for the given conditions Number Number cell Scroll down for the rest of the question
C) Calculate the value of Ece for this system at equilibrium. Number cell D) Determine the pH at which the given concentrations of Pb2,Pb Mn2, and MnO would be at equilibrium. Number pH
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Answer #1

2.363 RT -0.183,-0.056 Lo 51 LAcHvit = 17370 J 7 37oJ 5 (0-1沪 o.ossile 055/ 0-153- 0S91​​t r 023gs o-ro 59丿 14- = 4.0.35

> This helps partially but the Ecell and pH is wrong.

mochi12 Mon, Dec 6, 2021 2:10 PM

> To find Ecell you do:
0.183-(0.0591/10)xlog((Pb2+)^5 x (MnO4-)^2 x (H+)^16 / (Mn2+)^2 x (PB4+)^5) like shown above but that's it. You don't subtract anything.

To find the pH you do:
Your K=(Pb2+)^5 x (MnO4-)^2 x (H+)^16 / (Mn2+)^2 x (PB4+)^5)
and then negative log that value to find pH.

mochi12 Mon, Dec 6, 2021 5:36 PM

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A solution containing the following was prepared: 0.15 M Pb2. 1.5% 10.6 M Pb4t, 1.5x 106 M Mn2. 0.15 M MnO4, and 0.88 M HNO3. For this solution, the following balanced reduction half-reactions and o...
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