The partition function at constant V, T is the sum of Boltzmann factors where the sum is over independent states, . Week #10's Lesson showed that Z is related to two state functions, U and F F=-k...
The partition function at constant V, T is the sum of Boltzmann factors where the sum is over independent states, . Week #10's Lesson showed that Z is related to two state functions, U and F F=-kT lnZ Using these two relations, derive the relationships between Z and the following state functions and C (a) Entropy: S k In Z + kT (oln Z/oT)v (b) Pressure: P- kT (oln ZƠVr (d) Gibbs Free Energy: G-kTInZ + kTV(OlnZ/aV)T (e) Heat Capacity: CV 2kT(@lnZ/aT)v +kT2(8 InZ/aT2
The partition function at constant V, T is the sum of Boltzmann factors where the sum is over independent states, . Week #10's Lesson showed that Z is related to two state functions, U and F F=-kT lnZ Using these two relations, derive the relationships between Z and the following state functions and C (a) Entropy: S k In Z + kT (oln Z/oT)v (b) Pressure: P- kT (oln ZƠVr (d) Gibbs Free Energy: G-kTInZ + kTV(OlnZ/aV)T (e) Heat Capacity: CV 2kT(@lnZ/aT)v +kT2(8 InZ/aT2