Question

i (6 pts) Show detailed arrow includin tautomerization steps for the formation of a neolignan a alcohol shown below. ing mechanisms, including all resonance structures and nd a lig OH OH он он HO Ho 7. (10 pts) Draw out the biosynthetic process for the formation of myristicin from phosphoenylpyruvate (PEP) and erythrose-4-phosphate. Make sure to write out important intermediates involved он Ho H3co но' o он о 0 myristicin

Answer 1

Page No Date ,や Resonance structuxes 6 oH (-ㄧㄧㄣ dlatisw PA upting orv

Page No Date ling Keaction oupl +거 Cyclisalfon CIL) 贝 OH ca,거 a吋

Page No Date CoaH On pynvic acis enylhpse t phosphae DAHP Aldol type OH Co Ho 02H OH on Fr1NH 2 CO2H CO2H 애 Gly Cho?smi acidl Co2H can NH olehychradcse

NH O2 NADPH Phenyl alanine cinnamic aci SAM 0.2,NADPH ơn RedD Conifeyy alcohol 01 Conifony acetate 2/NADPH SAM он Eugenel yeo orfe OH 0