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Explain why lead (IV) alkyl halides can form stable five coordinate complexes more easily than their silicon analogues a...

Explain why lead (IV) alkyl halides can form stable five coordinate complexes more easily than their silicon analogues and comment on the strength of the relevant carbon bonds.

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Answer #1

The notable thing is that lead (Pb) is a metal, whereas silicon (Si) is a metalloid.

The size of Pb is more than that of Si.

Hence, Pb can form stable five coordinate complexes more easily than their silicon analogs.

The Pb-C bond is stronger than the Si-C bond.

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