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Which of the compounds listed below is the only one that CAN self-condense in ethanolic solution of NaOH? a. 4-ethylbenz...

Which of the compounds listed below is the only one that CAN self-condense in ethanolic solution of NaOH? a. 4-ethylbenzaldehyde b. 2-Methyl-2-ethyl-pentanal c. 3-methylbutanal d. 2,2-dimethylpropanal e. benzaldehyde

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Answer #1

Solution:

The correct option is C ( 3-methylbutanal)

CH3 -CH(CH3) CH2 CHO

Self condensation reaction in the presence of ethanolic solution of NaOH of aldehyde or ketone is an example of aldol reaction. Thus, the aldehyde or ketone which contains α-hydrogen only able to give self condensation to form product.

Since, 3-methylbutanal contains α-hydrogens, hence it can be self condensed in ethanolic NaOH.

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