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OH من بلد 애 얘 HO- H-A 1. LiAlH,, ether (excess) 2. H+, H,0 H,0 (excess) H.SO.
Determine the structures of compounds K-Y in the following reaction sequences. NH MgBr Ho 1. LIAIH4, ether 2. HO 1. NaOH → M- Mchu >N 2. CH CH Br 2. CH,OH ola.ompelen 1. LIAIH., ether PBrs > p 1. PICH) » Q" 2. Bu- H R 2. H2O NaCN OH PBrya 1 V 1. LIAIH, ether 2. 0 .CHMgBrother 2. CH,OH Challe CHET (excess) NaOH, a HGG OCH CHO X- NaOCH,CHY CH.CH OH 2. NHCI
1. The major product that completes the following reaction is, MgBr , ether 2) H+, H,0 2. The starting material that completes the following reaction is, HO OH H
What product is expected from the following reaction? Ho 1. LAIH, ether . 2. Hj0 H Оно OH OH O Ho CH CH
draw the product 20. 0 H,C 21. soch 0 CH,OH 0 1 . LiAlH4, ether 2 H3o CH, 24. CHCH-C-a+ 25. 0 0 OH al 26. OCH, HC
1. H 1. LIAIH4 / dry ether 1. LiaiH, / dry ether 2. aqueous H2SO4 O H Bous H.SO O 2. W H₂SO4 H2SO4 OH Hoc H3C0 a = Electrophilic addition b=E2 Elimination c=Syl Nucleophilic substitution d=SN2 Nucleophilic substitution e= Electrophilic aromatic substitution f=Carbonyl nucleophilic addn g=Nucleophilic subs at carbonylacyl Xfer) h = Conjugate (nucleophilic) addn Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a -i for your answers
Choose the best approach OH CHCH OH CH3CHCH HBr HCH HO.H Mg ether C103.2 pyridine HO. CHAMBE ether B CHIM BI HO , HP ether LiAIH HO.H Mg CHI Ho, H D ether
Which of the following reactions with produce 1-butanol as one of the products? (Assume excess lithium aluminum hydride and water.) A 1) LiAlH4 +LiAIH, HO 2) HO 1) LiAlH4 +LiAlH, +HO 2) HO 1) LiAlH4 + LiAlH +HO 2) HO OH =0 1) LiAlH4 +LiAIH4 +HO 2) HO = 1) LiAlH4 +LiAIH4 +HO N(CH3)2 2) HO
Provide the product for the following reaction І. Br HOCH,CH,OH Mg/ether H2SO, Н,0° 2. H,0 но он ОН он IV он у Predict the product of the following synthesis. 1. Br2, H20 2. NaOH, HO 3. CH2OH, H+ OCH, н,со OCH, A B с OCH OCH OCH, D E Predict the product for the following reaction. OH Acid Catalyst + 25 °C O А D с B
NO, 00) 1.80.H.SO 2 онкона 3.HO pp.) 2 Na NDIO 1.2.2,0 2 DO XS PCC HO CH ON OH XSHCIO NH إياها NINH w.) OH OH XS Bobbitt's SiO, CH2Cl2 ww.) OH 1. XS KMnONaOH(aq). A 2. H,O* HO 1. NaNO.HCI 2. H,PO (a) CHO NH yy.) NH 1. NaNO, HCl(conc) 2. D.PO 1. LITHF 2. D20 14 aaa) wo NaBHJEICH bbb.) су Cl2 FeBry HO НО. Feb COL) H 1 KM. NOW 2. Ho didd) cleum com) NO 1....
List in Order (a) 0 EtNH, (excess) ОН H2SO4 (cat.) OCH3 + CH,OH (excess) + H2O CI NH -02 S- HÓ: OH Hd 0–CH OCH CI LOH Hac +N-H H NH A HON A HO OH H ---CH ام وی ام H 0 CH Step #1 Step #2 Step #3 D E H2O, H2SO4 (cat.) ОН Step #1 Step #2 Step #3 Step #4 Step #5 Step #6 N ОН 0 H S- HO HO NH 0 H sos-0 B...