ADraw the reactant required to produce each major product. Be sure to indicate the correct stereochemistry where...
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praw the reactant required to produce each major product. Be sure to indicate the Walle! indicate the correst dereichemistry where appropria нс с Cl, CH CI, hv NH OCHS Kąco, (a base) then CH,BI 1. Na (metal) 2. butyl bromide OCH, 1. Brg, hv, CHCI HC- 2. methanolysis NH2 1. mesyl chloride, pyridine 2. NH3 1. TICI, py 2. H20 (hydrolysis) 1.TSCI, K2CO3 2. Nal (acetone) Page 5 of 8
write a major product for each of the following reaction,
indicate appropriate stereochemistry
1. Br2, hv (a) 2. NaOCH3, Cн,Он, Д 1. x's NaNH2 3. KMnO4, H30 X, cold (c) .CI 2. Br Br 3. K, NH3(), CH3CH2OH 4. CHCI3 NaOH(aq) 1. H2SO4 Он (b) 2. CH3COOOH 3. Нао х
3. (21 points) Provide the major product for each reaction below. Be sure to indicate appropriate stereochemistry when OH HBr 90°C CH,CH OH Br CH,CH, ONa CH,CH, OH NaN, acetone - water (solvent) н,со, 1. TSCI, pyridine 2. LiBr, acetone 9. H.Co
3. Identify (draw the structure showing stereochemistry where required) ALL of the missing reactant, reagents, or major product to complete the following transformations. а. Nal НРО, b. H2SO4 Но KMnO4 NH2 d. он Br2 CH2CI2 CHCI кон f. но" 1. excess Hg(OAc)2, H2O/THF OH 2. NaBH g- 1. еxcess BH,/ THF 2.H2O2 h.
Draw the structure of the one major product expected for each
of the following reactions. Indicate stereochemistry where
applicable
Chemistry 2310 Ch 8 and 10 Test-Addition Reactions of Alkenes and Intro to Radicals 1.) BH3 Br. k) PhCO3H 1.) O 2.) DMS Ni H3C n) HO 1.) H2SO4 heat 2.) Br2 1.) Br2, light 2.) NaOEt 3.) Ch. H2O o) 1.) Cl2, light 2.) NaOEt 3.) Os followed by DMS p) 1.) BH3 THF followed by H202/HO 2.) TsCl, pyridine...
Draw the major expected organic product(s) for each of the
following reactions. Be sure to indicate stereochemistry when
needed.
OH 1) TsCl, pyr 2) NaBr Br HS Give neutral product. بیاہ 1) SOCl2, pyridine 2) NaSH OH Br DBU d 1) PBr 3 2) KOt-Bu OH
Draw the major product(s) or reagents for the following
reactions. Pay attention to stereochemistry where appropriate. Put
a box or circle around your final answer.
1. NaN Br g. 2. H2 (xs), Pod 1. xs LAH 2. H20 h. NH2 3. ethyl iodide (xs) 1. NaNO2, HC 2. CuCN NH2 3. PhMgBr (xs) 4. Hyo xs LiAI(OR) H 0 1. Br2. FeBr 2. SOCI2. Py NH2 k.
write a major product for each of the following reaction,
indicate appropriate stereochemistry
1. NBS, hv, CC14 Tag 1. Xz; x's NaNH2 2. (CH3)3COK, (CH3)3COH, A 3. OHC = CHO, toluene, A 2. ă Br 3. H2 , Lindlar's catalyst 3. RCOZH; H30°x, H2O 1(x'sNaHz; ~ X (C) = 2. K, NH3(1), CH3CH2OH 3. CH2l2, Zn(Cu)
predict the major product for each transformation
below,indicate the stereochemistry where appicable.assume all
reaction will take place
(28 points) Predict the major product(s) for each transformation below. Indicate the stereochemistry where applicable. Assume that all the reactions will take place. BE TEA, CH,Cl2 heat hv NaNH, DMF De Cl,H,O OH 1. Hg(OAc)2(aq). 2. NaBH(aq) CICCIA 1.03,CH,CI 2. S
7. Predict the product(s) of each of the following reactions include stereochemistry where important and indicate the mechanism (S, S,2, El, E2). 80°C a 2-chloro-2-methylbutane NaOH Н.о b. (R)-2-chloropentane Nac c-H DMSO с1 (снс. Cн, CH,ОН d. trans-1-chloro-3-methylcyclohexane+ NaOC(CH) e. 2-chloro-3-phenylbutane Н.о f. trans-1-bromo-3-methyleyclopentane Nal acetone NaOCH THон g 2-chloro-2-methylbutane EIOH h R-3-bromo-2-methylpentane . trans-1-bromo-2-isopropyleyclohexane CHCOK NaSH Н,о j. 1-bromopropaе NaOCH снон CH коссH). I-bromobutane m. cis-1-chloro-3-methyleyclobutane Nal DMSO сHсH,он n. (R)-2-iodo-2-phenylethane NaOH o. 1-iodobutane p. 2-bromo-3-methylbutane KOC(CH). но (S)-3-chlorocyclopentene...