Question

In each reaction box, place the best reagent and conditions from the list below.


In each reaction box, place the best reagent and c


In each reaction box, place the best reagent and c


In each reaction box, place the best reagent and c




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Answer #1
Concepts and reason

The concept is to synthesize different products from different reactants by using the list of reagents provided.

Fundamentals

PCC is an oxidising agent, which oxidise primary alcohol to aldehyde.

Alkenes are converted to alcohols by means of hydration, hydroboration-oxidation.

LiAlH4{\rm{LiAl}}{{\rm{H}}_{\rm{4}}} is strong reducing agent and NaBH4{\rm{NaB}}{{\rm{H}}_{\rm{4}}} mild reducing agents.

The reaction is,

1) BH in THE
2) H2O2/NaOH
OH
1-methylcyclohex-1-ene
2-methylcyclohexanol

The reaction is,

Acc CIMC ,
3) PCC in CH2Cl2
ОН
2-methylcyclohexanol
2-methylcyclohexanone

The reaction is,

1) HOCH,CH,OH, cat, H+
Doenen en
ó
o
ethyl 3-oxobutanoate

The reaction is,

2) LiAlH4
ОН

The reaction is,

e o
2) H20, H307
en
OH
OH
4-hydroxybutan-2-one

The reaction is,

1) Liale,
1) LiAlH4
OH
acetic acid
OH
2) H2O
ethanol

The reaction is,

3) PCC
no srce
OH
ethanol
acetaldehyde

The reaction is,

1) N85CFH, en Hom
4) NH2CH3, cat. H30*
I
H
acetaldehyde
(E)-N-ethylidenemethanamine

Ans:

Thus, the correct choice of reagents is,

1) B2H, in THE
2) H2O2/NaOH
3) PCC in CH2Cl2

Thus, the correct choice of reagents is,

1) HOCH2CH2OH, cat, H
2) LiAlH4
3) H20, H30+

Thus, the correct choice of reagents is,

1) LiAlH4
2) H20
3) PCC
4) NHẠCHy, cat. Hạch

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