planar SiH4 is unstable because silicon is larger in size and there are four hydrogen to form bond, there is steric replusion so they tend to move farther and form tetraheral to increase the bond angle to 109 degree 28 min
Consider a planar SiH4 molecule. (a) Construct a molecular orbital energy diagram for PLANAR SiH4. Place the valence e...
Part C they probably mean silicon not sulfur. Our homeworks are always covered in typos :( Consider a planar SiH4 molecule. (a) What is its point group symmetry? (b) How many ligand group orbitals (LGOs) are there for this molecule? Determine the symmetry of each LGO. (c) What are the symmetries of the valence orbitals on sulfur? (d) Construct a molecular orbital energy diagram for planar SiH4. Place the valence electrons in the diagram. (e) Do you expect planar SiH4...
Consider the diatomic molecule NF. (a) Draw the shape of the 2 pz orbital on N. How many nodes does this orbital have? Show the nodes in your diagram. (b) Construct a molecular orbital energy diagram for NF. For this drawing consider both the s and p valence orbitals on each atom, but do not include orbital mixing. Show how the electrons are placed in the MO's. (c) How would orbital mixing alter the MO energy diagram you just constructed?...
Construct the molecular orbital diagram of He2 using appropriate molecular orbital labels and arrows to represent electrons. a) Sketch each molecular orbital. Explain HOW you identify an antibonding orbital. b) Identify the linear combination of atomic orbitals for each molecular orbital. Explain WHY there are two molecular orbitals. Explain why the He2 molecule is NOT observed experimentally. c)
Construct an approximate molecular orbital energy diagram for homonuclear diatomic F2. Considering only the valence atomic orbitals on fluorine. Show the sigma and pi interaction between orbitals of the same symmetry and then rank these on your diagram in terms of increasing energy (be sure to draw pictures of the orbital interactions or the final MOs). Write out the electron configuration and determine the bond order of F2.
13. (14 pts) MO Theory Draw the complete (core and valence) molecular orbital energy level diagram for the homonuclear diatomic molecule Be2. Use standard MO symbols to label the energy levels (That is: o, o, , or n*, as needed, with subscripts indicating which atomic orbitals formed them.) a. Sketch the molecular orbital formed when two 2p orbitals, one each on each Be atom, overlap to form a o antibonding MO b. Using your MO energy level diagram in (a),...
Construct the molecular orbital diagram for H. Answer Bank Energy Atom Molecule Atom Identify the bond order. Oo O 0.5 01 1.5 02
construct molecular orbital energy diagram of clf4
(a) Draw a molecular orbital energy diagram for Cl2 and show which orbitals are occupied with electrons. (b) How many bands are expected in the photoelectron spectrum of the valence electrons for Cl2? Why? (c) Draw the shape of the r* orbital in Cl2. (d) What is the bond order for Cl2? (e) Is Cl2 diamagnetic or paramagnetic?
The molecular orbital energy diagram for the valence orbitals of the NO– ion is shown below. Use this diagram to answer the following questions. a) What is the bond order in NO– ? b) Is NO– diamagnetic, or is it paramagnetic? How can you tell? c) Which has the larger bond distance, NO– or NO? * O2p T2p T2p G2s
Upon Inspecting a molecular orbital diagram for homonuclear diatomic molecule, you see that this molecule has electrons in bonding orbitals and 6 electrons in anti-bonding orbitals. What is the bond order for this molecule, and would you predict for it to be stable or unstable? O Bond order - 2 stable Bond order - 1, unstable O Bond order 1, stable Bond order 0, unstable : Bond order 2 unstable