Homework Answers
tosylate i.e alkyl sulfonates undergoes the SN2 reaction
only and no rearrangement and forms the Sn2 product
only
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VI. (12 pts) Give the structure of all possible substitution products for the following. Give a detailed mechanism. OTS...
VI. (12 pts) Give the structure of all possible substitution products for the following. Give a...
VI. (12 pts) Give the structure of all possible substitution products for the following. Give a detailed mechanism. OTs MeOH
Show the following mechanism for the reaction below. Give all the possible products that can be...
Show the following mechanism for the reaction below. Give all the possible products that can be formed plus circle and label the major and minor products. (6 pts) H2SO4 MeOH
5. Give the products of the following reactions. You DO NOT need to show a detailed mechanism but...
5. Give the products of the following reactions. You DO NOT need to show a detailed mechanism but do show ALL reaction intermediates. (30 pts) LiAIH4 G CH3-C-00HE (b) F (c) OH CH3 6. Give the product of the following reactions and in each case give a detailed reaction mechanism by which it is formed. (40 pts, 10 each) pH 4-5 ca. H2S4 HBrJ (c)--/SH NaOH I (d) H CH3 H CH3
5. Give the products of the following reactions....
3. There are two possible substitution products fr products and a complete mechanism for their for...
3. There are two possible substitution products fr products and a complete mechanism for their for IUPAC system and circle the major product. Ustitution products from the reaction of 3,3-dimethyl-2-butanol with aq. HBr. Draw the mechanism for their formation, including all intermediates. Name both products based on the :OH MW: 102. Ts-gimo 4. Based on the reaction above, calculate the theoretical yield for the reaction based on 2.0 g of the 3,3-dimethyl-2- butanol and 5 mL of the 48% HBr....
Show the complete detailed mechanism for the following reaction. Provide all possible products and indicate specific...
Show the complete detailed mechanism for the following
reaction. Provide all possible products and indicate specific
stereochemistry or regio-chemistry if appropriate
Cl B. NaOH. H,O → 2 350°C products
Short Answer Section (43 pts) – showing work helps! Substitution vs. Elimination (12 pts). Predict all...
Short Answer Section (43 pts) – showing work helps! Substitution
vs. Elimination (12 pts). Predict all major product(s) of each of
the following reactions and indicate the predominant mechanistic
pathways (Sn1, Sn2, E1, E2). Remember to consider rearrangements.
Mechanism #1 (10 pts). Draw a stepwise mechanism to account for the
following transformation. Br mechanism(s)? NaOH Cl mechanism(s)?
NaOEt OTs for this reaction, circle the major product mechanism(s)?
O K Cl for this reaction, circle the major product mechanism(s)?
NaOCH3 H2O...
Please show the mechanism showing all possible substitution products. SN1 and SN2 only. Thank you. Determine...
Please show the mechanism showing all possible substitution
products. SN1 and SN2 only. Thank you.
Determine the major substitution product(s) for each of the following reactions. In addition, please state the mechanism that is employed in the formation of each product. (8 points) Br NaOCH 3 CH3OH H20 Heat
I. (15 pts) Complete the following reaction. Write the structure of all elimination products. Determine the...
I. (15 pts) Complete the following reaction. Write the structure of all elimination products. Determine the major product. Write a detailed mechanism H2SO4 heat
and the structure of the in pts) e detailed mechanism the structure of the product, th...
and the structure of the in pts) e detailed mechanism the structure of the product, th e arrow to show electron movement. (8 for the following reaction. Us in ccl Bry s. Complete the following, use arrow to show the clectron movement. (Spts) ル _.
Present the products and give a detailed mechanism, using the curved arrow notation, for the following...
Present the products and give a detailed mechanism, using the curved arrow notation, for the following reactions:
VI. (12 pts) Give the structure of all possible substitution products for the following. Give a detailed mechanism. OTs MeOH
Show the following mechanism for the reaction below. Give all the possible products that can be formed plus circle and label the major and minor products. (6 pts) H2SO4 MeOH
5. Give the products of the following reactions. You DO NOT need to show a detailed mechanism but do show ALL reaction intermediates. (30 pts) LiAIH4 G CH3-C-00HE (b) F (c) OH CH3 6. Give the product of the following reactions and in each case give a detailed reaction mechanism by which it is formed. (40 pts, 10 each) pH 4-5 ca. H2S4 HBrJ (c)--/SH NaOH I (d) H CH3 H CH3
5. Give the products of the following reactions....
3. There are two possible substitution products fr products and a complete mechanism for their for IUPAC system and circle the major product. Ustitution products from the reaction of 3,3-dimethyl-2-butanol with aq. HBr. Draw the mechanism for their formation, including all intermediates. Name both products based on the :OH MW: 102. Ts-gimo 4. Based on the reaction above, calculate the theoretical yield for the reaction based on 2.0 g of the 3,3-dimethyl-2- butanol and 5 mL of the 48% HBr....
Show the complete detailed mechanism for the following
reaction. Provide all possible products and indicate specific
stereochemistry or regio-chemistry if appropriate
Cl B. NaOH. H,O → 2 350°C products
Short Answer Section (43 pts) – showing work helps! Substitution
vs. Elimination (12 pts). Predict all major product(s) of each of
the following reactions and indicate the predominant mechanistic
pathways (Sn1, Sn2, E1, E2). Remember to consider rearrangements.
Mechanism #1 (10 pts). Draw a stepwise mechanism to account for the
following transformation. Br mechanism(s)? NaOH Cl mechanism(s)?
NaOEt OTs for this reaction, circle the major product mechanism(s)?
O K Cl for this reaction, circle the major product mechanism(s)?
NaOCH3 H2O...
Please show the mechanism showing all possible substitution
products. SN1 and SN2 only. Thank you.
Determine the major substitution product(s) for each of the following reactions. In addition, please state the mechanism that is employed in the formation of each product. (8 points) Br NaOCH 3 CH3OH H20 Heat
I. (15 pts) Complete the following reaction. Write the structure of all elimination products. Determine the major product. Write a detailed mechanism H2SO4 heat
and the structure of the in pts) e detailed mechanism the structure of the product, th e arrow to show electron movement. (8 for the following reaction. Us in ccl Bry s. Complete the following, use arrow to show the clectron movement. (Spts) ル _.
Present the products and give a detailed mechanism, using the curved arrow notation, for the following reactions:
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