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11. What are the 2 purposes of annealing semi-crystallizable polymers.? Pick one of the purposes and explain what happens to

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Semi Crystalline polymers:

The polymers possessing both amorphous and crystalline areas are said to be semi- crystallisable polymers. In some polymers, there is a distinct boundary between the two crystalline and amorphous regions whereas, in some polymers, there is no such clear demarcation between the two regions.

The two purposes of annealing semi- crystallisable polymers are:

  1. Enhancement of crystallinity
  2. Enhancement of Mechanical properties such as heat conductivity and strength

The annealing of semi- crystallisable polymers can result in morphological alterations such as thickening of the polymer as a result of melting and recrystallization processes. The annealing time and annealing temperature are two important factors for enhancement of crystallinity in the semi- crystallisable polymers.

Two kinds of morphologies can be observed on annealing the semi- crystallisable polymers:

  1. Lamellar type polymer
  2. Spherulite type polymer

Both the morphologies are a result of crystallisation. Molecules are intertwined and there is a random arrangement of molecules before annealing while after annealing there is a more ordered arrangement of molecules resulting in higher crystallinity.

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