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show all work please thanks!!! 2. (6 pts total: 2 pts each) Complete the following transformations by indicating the...
1. (4 pts) Rank each of the following carbocations in order of stability (1 most stable...
1. (4 pts) Rank each of the following carbocations in order of stability (1 most stable and 4 least stable). н н сH н Н,с Н,с" H сH; CH3 Hас- H 2. (6 pts total; 2 pts each) Complete the following transformations by indicating the reactant structure or the major organic product(s). Place your answer(s) in the space provided. Be certain to indicate stereochemistry where applicable. Cl2 Он cat. H2SO H-о Br Br conc. HBra) сн сна 3. (10 pts...
any of four structua 4. (18 pts total) Butylbromide is the common name of having the...
any of four structua 4. (18 pts total) Butylbromide is the common name of having the molecular formula C4HoBr. Two of these isomers, n-butylbromide and sec-butylbromide, can be prepared from the same alkene, 1-butene. indicating all necessary reagents, and/or the major organic product(s). Place your answer(s) in the space provided. Be certain to indicate stereochemistry where applicable a. (3 pts each) In the space provided below, complete each transformation by 1-butene Reagents Reagents n-butylbromide sec-butylbromide b. (6 pts) Free radical...
1. For each of the following transformations, provide the missing reagents/conditions, starting material, or major organic...
1. For each of the following transformations, provide the missing reagents/conditions, starting material, or major organic products) as appropriate. You may ignore stereochemistry. All transformations requiring you to fill in reagents can be accomplished in two or fewer steps namorangorang NaOH (cat) moldana 1. Cros, pyridine 2. Hicato c. OYO TA Dono 1. Et Cui 2. H* workup 3. NaBH, MOH modello 1. PhMgBr, E1,0 2 H workup 3. conc. H2SO4 Duplication of this problem ser for any purpose other...
9. Give answers for each part of the question in the space provided. Give the major...
9. Give answers for each part of the question in the space provided. Give the major organic product(s), the starting material (reactant), or the reagent(s) as indicated in the synthetic transformations below. If two or more products form in approximately equal amounts, draw structures of both. Indicate stereochemistry where appropriate. Cl2 CCl4 NaoMe Br Me MeOH ~ 1. B2H6 2. H2O2, NaOH 1.KMnO4, NaOH, heat 2. H3O+ Br KOt-Bu t-BuOH
show all work please thank you!! 1. (6 pts total: 2 pts each) Proteins that catalyze...
show all work please thank you!!
1. (6 pts total: 2 pts each) Proteins that catalyze chemical reactions in living systems are called enzymes. The basic building blocks of proteins are called amino acids and have the general structure pictured below, left, where R is a substituent containing one of many organic functional groups. Some representative examples of amino acids found in nature are pictured here as well (R groups only) Opo CH HO-C-H HC-C-CH₂ CH₂SH H-C-H H,NFCO,H. Threonine Valine...
4. Multiple Choice Place your answer in the space provided. (2 pts. each; 12 pts. total)...
4. Multiple Choice Place your answer in the space provided. (2 pts. each; 12 pts. total) Which is NOT true of the aldol condensation? A. It accomplishes the formation of a new carbon-carbon bond B. The enolate is favored at equilibrium (assume NaOH as the base) C. The key step is the mechanism is attack of the enolate ion on a carbonyl carbon atom D. Dehydration of the aldol product is often observed and is irreversible. _Which sets of hydrogen...
1. (6 pts total; 2 pts each) Proteins that catalyze chemical reactions in living systems are...
1. (6 pts total; 2 pts each) Proteins that catalyze chemical reactions in living systems are called enzymes. The basic building blocks of proteins are called amino acids and have the general structure pictured below, left, where R is a substituent containing one of many organic functional groups. Some representative examples of amino acids found in nature are pictured here as well (R groups only) сн. н 0:00 HO-C-H. HỌC-C-CH, CH,SH H-C-H H2N -CO,H H An Amino Acid Threonine Valine...
2. Draw, in the provided spaces/ boxes, the major organic products of the following transformations. Be...
2. Draw, in the provided spaces/ boxes, the major organic products of the following transformations. Be sure to indicate appropriate stereochemistry. If the reaction generates enantiomers, draw one and write tenantiomer' 1. Cl2, H20 2. NaOH На Pd/C 1.Hg(OAc)2 CH,OH 2. NABH 1. CH CO H 2. Hао* Н,с" HC @) 1. ВНа, THF 2. H202, NaOH Br2 CH2CI2 (E)-5-methylhept-3-ene MeOH conc'd H3PO4 ОН Br NAOCH3
show all work please thank you!!! 8. (4 pts. total; 2 pts. each) In the space...
show all work please thank you!!!
8. (4 pts. total; 2 pts. each) In the space provided below, explain the following atomic properties. Be succinct. Electronegativity (X^) Polarizability 9. (4 pts) Trifluoroacetic acid (CF3CO2H: pK = 0.23) and acetic acid (CH3CO2H; pk= 4.75) are monoprotic acids (meaning they can dissociate only one H ion/molecule of acid). Using your knowledge of structure, explain why the acid dissociation (Ka) of acetic acid is greater than that for trifluoroacetic acid. Place your answer...
Complete the following reactions. Provide the missing reactant(s) OR major organic product(s). Show correct regio- and...
Complete the following reactions. Provide the missing reactant(s) OR major organic product(s). Show correct regio- and stereochemistry for products you draw, where applicable Сн,, Zn(Cu) 1. OSONMO, pyridine 2. NaHSO, H,0 H2O* g. V 1. BH-THF 2. 1,0,, NaOH, HO - Y 1. MCPBA 2.4,00 DCM H,802, H2O heat 1., 2. Zn, AcOH
1. (4 pts) Rank each of the following carbocations in order of stability (1 most stable and 4 least stable). н н сH н Н,с Н,с" H сH; CH3 Hас- H 2. (6 pts total; 2 pts each) Complete the following transformations by indicating the reactant structure or the major organic product(s). Place your answer(s) in the space provided. Be certain to indicate stereochemistry where applicable. Cl2 Он cat. H2SO H-о Br Br conc. HBra) сн сна 3. (10 pts...
any of four structua 4. (18 pts total) Butylbromide is the common name of having the molecular formula C4HoBr. Two of these isomers, n-butylbromide and sec-butylbromide, can be prepared from the same alkene, 1-butene. indicating all necessary reagents, and/or the major organic product(s). Place your answer(s) in the space provided. Be certain to indicate stereochemistry where applicable a. (3 pts each) In the space provided below, complete each transformation by 1-butene Reagents Reagents n-butylbromide sec-butylbromide b. (6 pts) Free radical...
1. For each of the following transformations, provide the missing reagents/conditions, starting material, or major organic products) as appropriate. You may ignore stereochemistry. All transformations requiring you to fill in reagents can be accomplished in two or fewer steps namorangorang NaOH (cat) moldana 1. Cros, pyridine 2. Hicato c. OYO TA Dono 1. Et Cui 2. H* workup 3. NaBH, MOH modello 1. PhMgBr, E1,0 2 H workup 3. conc. H2SO4 Duplication of this problem ser for any purpose other...
9. Give answers for each part of the question in the space provided. Give the major organic product(s), the starting material (reactant), or the reagent(s) as indicated in the synthetic transformations below. If two or more products form in approximately equal amounts, draw structures of both. Indicate stereochemistry where appropriate. Cl2 CCl4 NaoMe Br Me MeOH ~ 1. B2H6 2. H2O2, NaOH 1.KMnO4, NaOH, heat 2. H3O+ Br KOt-Bu t-BuOH
show all work please thank you!!
1. (6 pts total: 2 pts each) Proteins that catalyze chemical reactions in living systems are called enzymes. The basic building blocks of proteins are called amino acids and have the general structure pictured below, left, where R is a substituent containing one of many organic functional groups. Some representative examples of amino acids found in nature are pictured here as well (R groups only) Opo CH HO-C-H HC-C-CH₂ CH₂SH H-C-H H,NFCO,H. Threonine Valine...
4. Multiple Choice Place your answer in the space provided. (2 pts. each; 12 pts. total) Which is NOT true of the aldol condensation? A. It accomplishes the formation of a new carbon-carbon bond B. The enolate is favored at equilibrium (assume NaOH as the base) C. The key step is the mechanism is attack of the enolate ion on a carbonyl carbon atom D. Dehydration of the aldol product is often observed and is irreversible. _Which sets of hydrogen...
1. (6 pts total; 2 pts each) Proteins that catalyze chemical reactions in living systems are called enzymes. The basic building blocks of proteins are called amino acids and have the general structure pictured below, left, where R is a substituent containing one of many organic functional groups. Some representative examples of amino acids found in nature are pictured here as well (R groups only) сн. н 0:00 HO-C-H. HỌC-C-CH, CH,SH H-C-H H2N -CO,H H An Amino Acid Threonine Valine...
2. Draw, in the provided spaces/ boxes, the major organic products of the following transformations. Be sure to indicate appropriate stereochemistry. If the reaction generates enantiomers, draw one and write tenantiomer' 1. Cl2, H20 2. NaOH На Pd/C 1.Hg(OAc)2 CH,OH 2. NABH 1. CH CO H 2. Hао* Н,с" HC @) 1. ВНа, THF 2. H202, NaOH Br2 CH2CI2 (E)-5-methylhept-3-ene MeOH conc'd H3PO4 ОН Br NAOCH3
show all work please thank you!!!
8. (4 pts. total; 2 pts. each) In the space provided below, explain the following atomic properties. Be succinct. Electronegativity (X^) Polarizability 9. (4 pts) Trifluoroacetic acid (CF3CO2H: pK = 0.23) and acetic acid (CH3CO2H; pk= 4.75) are monoprotic acids (meaning they can dissociate only one H ion/molecule of acid). Using your knowledge of structure, explain why the acid dissociation (Ka) of acetic acid is greater than that for trifluoroacetic acid. Place your answer...
Complete the following reactions. Provide the missing reactant(s) OR major organic product(s). Show correct regio- and stereochemistry for products you draw, where applicable Сн,, Zn(Cu) 1. OSONMO, pyridine 2. NaHSO, H,0 H2O* g. V 1. BH-THF 2. 1,0,, NaOH, HO - Y 1. MCPBA 2.4,00 DCM H,802, H2O heat 1., 2. Zn, AcOH
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