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(References) Choose one reagent from the Table to carry out the following conversions (Use letters from the table t...
Question 9.27, 9.30 Choose one reagent from the Table to carry out the following conversions. Use...
Question 9.27, 9.30 Choose one reagent from the Table to carry out the following conversions. Use letters from the table to specify reagents. Reagents КMnO,/ Н,о* O3 d 1. Br2 g a 2. KOH in ethanol H2/ Lindlar catalyst hr H20/ H2SO4/ HgSO4 е 1. NaNH2 in NH3 2. CH3Br Li in NH3 1 equiv Br2 f 1. BH3 in THF C 2. H202 in NaOH a) CHACH,сH,сH,CECH CHн-CH-CH-CH2CH-CH CHз b) сHa-CHa-CEс-сн, CH3CH2 The following synthesis requires more than one...
Which of these anions would be the most nucleophilic towards methyl iodide in an ethanol solution?...
Which of these anions would be the most nucleophilic towards methyl iodide in an ethanol solution? LI. CH,CH2-C- Which reagent would be best for carrying out this transformation он (B) HO",heat (C) HIO, N-H Cro,cr (PCC) @ C+--Ο- Which reaction sequence would accomplish this t- What is che best rearest or set of reagents to accomplish ICH CH (B) H2, Pd NBS HBr, peroxides (A) KMnO/KOH (B) MCPBA 5 Which series of reactions would best accomplish this 1eWhas is the...
13. (12 pts-4 pts each) Show how you could carry out th how you could carry...
13. (12 pts-4 pts each) Show how you could carry out th how you could carry out the following synthesis reactions by placing the letters corresponding to the appropriate reagents above each ar must be in the correct order to receive full credit. priate reagents above each arrow. The reagents A. HBr, ether B. Br2, CH2Cl2 C. Br2, H2O D. 1. Hg(OAC)2, H2O/THF 2. NaBH4 E. 1. BH3, THF 2. H2O2, OH F. H2SO4, H2O/HgSO4 G. NBS, hy H. H/Pd/C...
the following synthesis requires more than one step. specify the reagents you would use to carry...
the following synthesis requires more than one step. specify
the reagents you would use to carry it out.
The following synthesis requires more than one step. Specify the reagents you would use to carry it out. Specify reagents using letters from the table, first reagent on the left. Exawple: ab HH CH3CH2CH2CH2C=CH HC-H CH3CH2CH2CH2 CH3 Reagents Br2 CH?l2 / Zn(Cu) / ether i 1.03 2. Zn/H30* b CH31 Hz / Lindlar catalyst Li in NH3 CH3CH2! 9 Hz over Pd/C...
CHE 310 Homework #8 Due WED NOV 6 Name Score: DIRECTIONS: You must complete the entire...
CHE 310 Homework #8 Due WED NOV 6 Name Score: DIRECTIONS: You must complete the entire assignment. 1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) HO 1. Hg(OA), CH, OH H, SO 2. NaBH4 1 BH-THF 2) H2O2, KOH Bry, H,0 1. BH-THF 2. H2O2, NaOH H20, H2SO4 1, NaNH, H-CEC-CH2 CH2 CH 2. CH,CH,B1 Lindlar cat 1....
References] tyle (Specify the reagents you would use to carry out the conversion by using letters...
References] tyle (Specify the reagents you would use to carry out the conversion by using letters from the table. Write the letters in the order that they are used, e.g., abe.) Scheme 1: OIDIOK- CH CH CH3 CHs Br ОН Scheme 2: сн, сн, сн Br ot Reagents Available a. BH3. THF then H2O2, OH . b. PBr h. NBS, CC i HBr H2, Lindlar's catalyst pr c. Mg, ether then H3O d. (CHshCuLi k. RCOOOH I. Os then Zn,...
How would you synthesize the following compound from acetylene and reagents in the table? Choose the...
How would you synthesize the following compound from acetylene and reagents in the table? Choose the most efficient route. Specify reagents using letters from the table, first reagent on the left. Example: ab H H CH3CH2CH2 CH2CH3 a. Br2 b. CH3CH I Reagents available d. CH3 CH2CH2CH2Br g. KOH/ ethanol e. Hy / Lindlar's catalyst | h. NaNH / NH3 f. 1. BHz in THF 2. H2O2 in NaOH c. CH3 CH, CH,Br Reagents (in order of use) are Submit...
Homework 9: Alpha Be sure to answer all parts. Report Synthesize (2)-hept-5-en-2-one from ethyl a...
Homework 9: Alpha Be sure to answer all parts. Report Synthesize (2)-hept-5-en-2-one from ethyl acetoacetate (CH,COCH Co,Et) and the given starting material. Sol Br Guided (z)-hept-5-en-2-one Draw four organic reaction intermediates, and seleet the single best set of reaction steps. reagents for each of CHCoCH2CO2Et [1] NaOEt, [2] HC-CCH2Br [1 HCL, [21 HC CCH2Br O I1 Mg, 12] HC CCH2Br draw structure 0 H2 (2 equiv), Pd-C H2 (2 equiv), Pd c mCPBA H,SO4 11,0+,a HOCH CH,OH, TSOH LIAIH KMno,...
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions...
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
Choose reagents to convert 2-cyclohexenone to the following compounds. Syntheses may require several steps. Use letters...
Choose reagents to convert 2-cyclohexenone to the following compounds. Syntheses may require several steps. Use letters from the table to list reagents in the order used (first at the left) with no commas. Reagents 1. Li(CH3)2Cu 2. H30* 1. NaBHA 2. H30* NH3 / KOH 1. Li(CH3)2Cu 2. H30* CH2lz / Zn(Cu) /ether 1. Li(CH2=CH)2Cu 2. H30* (C6H5)3P*-CH2 b C k H2 over Pd/C 1. CH3 MgBr / dry ether 2 H30* HN(CH3)2 d H2NNH2 / KOH h KMnO4 /H30*...
Question 9.27, 9.30 Choose one reagent from the Table to carry out the following conversions. Use letters from the table to specify reagents. Reagents КMnO,/ Н,о* O3 d 1. Br2 g a 2. KOH in ethanol H2/ Lindlar catalyst hr H20/ H2SO4/ HgSO4 е 1. NaNH2 in NH3 2. CH3Br Li in NH3 1 equiv Br2 f 1. BH3 in THF C 2. H202 in NaOH a) CHACH,сH,сH,CECH CHн-CH-CH-CH2CH-CH CHз b) сHa-CHa-CEс-сн, CH3CH2 The following synthesis requires more than one...
Which of these anions would be the most nucleophilic towards methyl iodide in an ethanol solution? LI. CH,CH2-C- Which reagent would be best for carrying out this transformation он (B) HO",heat (C) HIO, N-H Cro,cr (PCC) @ C+--Ο- Which reaction sequence would accomplish this t- What is che best rearest or set of reagents to accomplish ICH CH (B) H2, Pd NBS HBr, peroxides (A) KMnO/KOH (B) MCPBA 5 Which series of reactions would best accomplish this 1eWhas is the...
13. (12 pts-4 pts each) Show how you could carry out th how you could carry out the following synthesis reactions by placing the letters corresponding to the appropriate reagents above each ar must be in the correct order to receive full credit. priate reagents above each arrow. The reagents A. HBr, ether B. Br2, CH2Cl2 C. Br2, H2O D. 1. Hg(OAC)2, H2O/THF 2. NaBH4 E. 1. BH3, THF 2. H2O2, OH F. H2SO4, H2O/HgSO4 G. NBS, hy H. H/Pd/C...
the following synthesis requires more than one step. specify
the reagents you would use to carry it out.
The following synthesis requires more than one step. Specify the reagents you would use to carry it out. Specify reagents using letters from the table, first reagent on the left. Exawple: ab HH CH3CH2CH2CH2C=CH HC-H CH3CH2CH2CH2 CH3 Reagents Br2 CH?l2 / Zn(Cu) / ether i 1.03 2. Zn/H30* b CH31 Hz / Lindlar catalyst Li in NH3 CH3CH2! 9 Hz over Pd/C...
CHE 310 Homework #8 Due WED NOV 6 Name Score: DIRECTIONS: You must complete the entire assignment. 1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) HO 1. Hg(OA), CH, OH H, SO 2. NaBH4 1 BH-THF 2) H2O2, KOH Bry, H,0 1. BH-THF 2. H2O2, NaOH H20, H2SO4 1, NaNH, H-CEC-CH2 CH2 CH 2. CH,CH,B1 Lindlar cat 1....
References] tyle (Specify the reagents you would use to carry out the conversion by using letters from the table. Write the letters in the order that they are used, e.g., abe.) Scheme 1: OIDIOK- CH CH CH3 CHs Br ОН Scheme 2: сн, сн, сн Br ot Reagents Available a. BH3. THF then H2O2, OH . b. PBr h. NBS, CC i HBr H2, Lindlar's catalyst pr c. Mg, ether then H3O d. (CHshCuLi k. RCOOOH I. Os then Zn,...
How would you synthesize the following compound from acetylene and reagents in the table? Choose the most efficient route. Specify reagents using letters from the table, first reagent on the left. Example: ab H H CH3CH2CH2 CH2CH3 a. Br2 b. CH3CH I Reagents available d. CH3 CH2CH2CH2Br g. KOH/ ethanol e. Hy / Lindlar's catalyst | h. NaNH / NH3 f. 1. BHz in THF 2. H2O2 in NaOH c. CH3 CH, CH,Br Reagents (in order of use) are Submit...
Homework 9: Alpha Be sure to answer all parts. Report Synthesize (2)-hept-5-en-2-one from ethyl acetoacetate (CH,COCH Co,Et) and the given starting material. Sol Br Guided (z)-hept-5-en-2-one Draw four organic reaction intermediates, and seleet the single best set of reaction steps. reagents for each of CHCoCH2CO2Et [1] NaOEt, [2] HC-CCH2Br [1 HCL, [21 HC CCH2Br O I1 Mg, 12] HC CCH2Br draw structure 0 H2 (2 equiv), Pd-C H2 (2 equiv), Pd c mCPBA H,SO4 11,0+,a HOCH CH,OH, TSOH LIAIH KMno,...
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
Choose reagents to convert 2-cyclohexenone to the following compounds. Syntheses may require several steps. Use letters from the table to list reagents in the order used (first at the left) with no commas. Reagents 1. Li(CH3)2Cu 2. H30* 1. NaBHA 2. H30* NH3 / KOH 1. Li(CH3)2Cu 2. H30* CH2lz / Zn(Cu) /ether 1. Li(CH2=CH)2Cu 2. H30* (C6H5)3P*-CH2 b C k H2 over Pd/C 1. CH3 MgBr / dry ether 2 H30* HN(CH3)2 d H2NNH2 / KOH h KMnO4 /H30*...
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