7. The following reaction is monitored by GCMS. After 5 hours the reaction is complete with two major products,A and B....
5. Show the major organic products after each step of the following reac reactant and products with according to their major functional groups. (6 pts 2 pts for functional groups) total: 2 pts per structure, O HaO+ (catalyst) H30+ (catalyst) CH,OH CH3CH2OH 6. The ether shown below can be prepared by Williamson ether synthesis. (a) Show the structures of the starting materials (alcohol and alkyl halide). (4 pts) (b) Show the complete arrow pushing mechanism that accounts for the formation...
Name Topic: Reaction Mechanisms: Predict your ability: For each of the following reactions, predict the major and minor product, underlining the major product. After, draw a complete arrow-pushing mechanism to obtain each product. СНЗ Good Average Needs Improvement 1. H30+, H20 CH S. CH Br2, H2O
2) Fill in each of the following boxes with the structure of the major reaction product(s) from each of the following reactions. (28 points total). a) Pd(PPhale NaOH b) + Pd(OA) (CH CHN CN 1. NaBH 2. H2O HH OH но -н H- OH HH OH CH,OH HNO, но NH,OH trace of acid 1. CHI (excess 2. Ag,0 H2O, heat CI 1 CRUS POY Grubbs catalyst) Page 2 of 5
29. Which are the major reaction products of the following reaction, which is carried out in an inert solvent? AICI: solvent NO2 Oló - o 02 a) I and II b) III and IV c) I and IV d) II and III 30. Which is the major product of the following reactions? CH3CI Cl2 K2Cr207 FeCl3 FeCl3 H2SO4 a) para-chlorobenzoic acid b) meta-chlorobenzoic acid c) a mixture of para- and meta-chlorobenzoic acid d) a mixture of ortho- and para-chlorobenzoic acid...
Question 10 20 pts The following reaction leads to two products: conjugated system A and unknown product B. NaOH, H2O + FO ? А B Determine the structure of product B and provide a complete arrow-pushing mechanism for the reaction. Upload Choose a File
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For questions 1 - 5. predict the major organic products for the following transformations. Clearly indicate formal charges and stereochemistry if applicable. The use of a squiggly bond is not permitted; all stereoisomers should be clearly indicated for full credit. OH 1. a) Croy, H,SO,,H,O (Jones reagent) b) workup 2. a) HCI (cat.), CH, OH b) workup Q2 1. a) Croy, pyridine, HCl, solvent (PCC) b) workup 2. a) HCI (cat.), CH, OH b) workup a) NaOH, solvent,...
1) Draw the major product of the following intramolecular
reaction.
2) Draw the major product of the following reaction that begins
with a retro-aldol, followed by an intramolecular aldol
condensation.
3) Determine and draw the structures of compounds
A and B only. Do not draw the
structure of compound X. Place each structure
above its letter. HINT: Both A and
B are esters.
4) Draw a curved arrow mechanism for the following
acid-catalyzed isomerization reaction. You must show all
intermediates....
What is the major organic product after each step of the following multi-step reaction? The products are labeled (1) and (2) in red in the figure. 1) Br/λν 2) t-BuOK/t-BuOH/A 1) Bry/2v 2) t-BuOK/t-BuOHA What is the major organic product of the following reaction? 1) Hg(OAc)2/THF/H20 2) NaBH, What is the major organic product after each step of the following multi-step reaction? The products are labeled (1) and (2) in red in the figure. Br 1) NaOCHz/CH,OH/A 2) H, (excess)/Pd-C...
1a. Draw the product in the following lb. Draw the two diastereomeric substitution products reaction and clearly indicate the obtained in the reaction below. stereochemistry CH OH - CHJÕH, BC DMSO 1-BOK 1 equiv + -BOH +KCI 1e. Draw the reactive conformation (with ld. The most favored and least favored compounds arrow pushing) and the product for the that could be obtained by treatment of 2,4 reaction below (show stereochemistry). dimethylpenta-1,3-diene with one equivalent of HBr. + BOH BUOK +...
5) What is the major product formed in the following reaction? Br wek Bra) b) HBr Br OH heat Br c) d) Br Br f) 6) Consider the following reaction: acetone (50%) H20 (50%) CI SCH3 Which of the following scenarios would decrease the rate of the reaction? Choose all that apply a) Changing the solvent ratio to - acetone (75%): H20 (25%) b) Changing 2-chlorobutane to 1-chlorobutane c) Increasing the concentration of the electrophile d) Changing the solvent ratio...