For the combustion of cyclopropane at 25 ºC C3H6(g) + (9/2) O2(g) → 3 CO2(g) + 3 H2O(liq) ΔHºc(C3H6,g) = -2091 kJ / mol. What is the standard molar enthalpy of formation of cyclopropane(g) at 25 ºC if the standard molar enthalpies of formation of CO2(g) and H2O(liq) at that temperature are, respectively, -393.51 kJ / mol and -285.83 kJ / mol?
given combustion reaction of cyclopropane is given bellow
C3H6(g) + (9/2)O2 3CO2 +3H2O H0 = -2091KJ/mol
H0 C3H6= ? KJ/mol
rxnH0 = -2091KJ/mol
fH0 O2(g) = 0 KJ/mol
fH0 CO2(g) = -393.51 KJ/mol
fH0 H2O(g) = -285.83 KJ/mol
H0 = fH0 (Product) - fH0 (Reactant)
H0rxn= [(3 fH0 CO2) + (3fH0 H2O)] - [(fH0 C3H6) + (9/2fH0 O2)]
-2091 = [(3 (-393.15)) + (3 (-285.83))] - [fH0C3H9 + (9/2 (0)]
-2091 = [-2036.94] - [fHC3H9]
fH0C3H9 = 2091 - 2036.94 = +54.06KJ/mol
ans standard molar enthalpy of formation of cyclopropane is + 54.06 KJ/mol
For the combustion of cyclopropane at 25 ºC C3H6(g) + (9/2) O2(g) → 3 CO2(g) + 3 H2O(liq) ΔHºc(C3H6,g) = -2091 kJ / mol....
The standard enthalpy of combustion of cyclopropane is -2091 kJ/mol at 298 K. The enthalpy of formation of CO_2 (g) and H_2 O (I) are -393 kJ/mol and -286 kJ/mol, respectively. Calculate the enthalpy of formation of cyclopropane Given that the enthalpy of formation of propene is 20.42 kJ/mol, please calculate the enthalpy of isomerization of cyclopropane to propene.
help pt) A sample of 1.0 mol of liquid octane C8H18(1) undergoes combustion accord 5. (10 pt) A C3H18(0) + O2(g) → 8 CO2(g) + 9 H2O(l) Using the standard enthalpies of formation given calculate the change in enthalpy in kJ/mol associated with the combustion of 1.0 mol of C8H18(1) at 1.0 bar pressure and 25 °C. Substance AH® (kJ/mol) C8H18() -249.9 CO2(g) -393.51 H2O) -285.83
The standard molar enthalpy of combustion, deltacHm, of C2H6 (g) is -1559.8 kJ/mol. 1. Use some of the following data to calculate the molar enthalpy of formation of C2H6(g) at 298.15 K 2. Calculate the molar enthalpy of combustion of ethane at 500K Table provided gives values of standard enthalpy of formation values at 298.15 K Substance deltafH (kJ*mol^-1) Cpm (J*K^-1*mol^-1) CO2 (aq) -413.8 N/A CO2 (g) -393.51 37.11 H2O (l) -285.83 75.291 H2O(g) -241.82 33.58 C2H6(g) to be determined...
The standard enthalpy change of combustion [to CO2(g) and H2O()] at 25°C of the organic solid para-benzoquinone, C6H4O2(s), is determined to be -2767.0 kJ mol-1. What is the Hf° of C6H4O2(s) based on this value? Use the following data: Hf° H2O () = -285.83 kJ mol-1 ; Hf° CO2(g) = -393.51 kJ mol-1 kJ mol-1
The standard enthalpy change of combustion [to CO2(g) and H2O()] at 25°C of the organic solid bianthracene, C28H18(s), is determined to be -13924.1 kJ mol-1. What is the Hf° of C28H18(s) based on this value? Use the following data: Hf° H2O () = -285.83 kJ mol-1 ; Hf° CO2(g) = -393.51 kJ mol-1 _________ kJ mol-1
A sample of solid pyrene (C16H10) that weighs 0.5063 g is burned in an excess of oxygen to CO2(g) and H2O() in a constant-volume calorimeter at 25.00 °C. The temperature rise is observed to be 2.130 °C. The heat capacity of the calorimeter and its contents is known to be 9.233×103 J K-1. (a) Write and balance the chemical equation for the combustion reaction. Use the lowest possible coefficients. Use the pull-down boxes to specify states such as (aq) or...
), is determined to be -7835.7 kJ mol!! The standard enthalpy change of combustion [to CO2(g) and H200) at 25°C of the organic solid pyrene, CH What is the AH of C16H10(s) based on this value? Use the following data: AH? H20 () --285.83 kJ moll: AH? CO2(8) --393.51 kJ mol! kJ mol!
the enthalpy of combustion of CH4(g) to make H2O(l) and CO2(g) is -2340 kJ mol-1. The enthalpy of combustion of CH2(g) to make H2O(l) and CO2(g) is -2760 kJ mol-1. The enthalpy of formation of H2O(l) is -286 kJ mol-1. All the data are for 298 K. The heat capacities for O2(g), CHA(8), CH3(g), H2O(l) and CO2(8) are 29, 61, 71, 75 and 37 JK"mor", respectively. Deduce a) 4U298 for the combustion of C4H8(g). 5) AH for the combustion of...
is this correct or do i just plug in the values of the standard enthalpy of combustion and standard molar entropy given in the begining of the question into the gibbs equation 11. The standard enthalpy of combustion of ethyl ethanoate (CH3COOC2H5, liq.) is -2331 kJ mol at 298 K, and its standard molar entropy is 259.4 JK mol. Calculate the standard Gibbs energy for formation of the compound at 298 K. (The standard enthalpies of formation of CO2(g) and...
The standard enthalpy change for the combustion of 1 mole of propane is -2043.0 kJ. CzH3(g) + 5 O2(g) + 3 CO2(g) + 4H2O(g) Calculate 4, Hº for propane based on the following standard molar enthalpies of formation. molecule CO2(g) H2O(g) 4,Hº (kJ/mol-rxn) -393.5 -241.8