1. Draw the complete curved-arrow mechanism for the base-catalyzed aldol condensation to form dehydrorheosmin (or d...
Show the mechanism for a base-catalyzed aldol condensation of the reaction. Use any appropriate base. Show the mechanism for an acid-catalyzed aldol concentration of the reaction. use any apporproate acid. 2. Draw and name the compound resulting from the aldol condensation of vanillin with creatinine. сн, NH но- 160°C NH CH Vanillin Creatinine 2. Draw and name the compound resulting from the aldol condensation of vanillin with creatinine. сн, но- NH 160 C NH сH, Vanillin Creatinine
answer all questions if possible. VI. Pre-Lab Problems 1. Draw the complete curved-amow mechanism for the base-catalyzed aldol com adol condemnation to form dehydrorheosmin (or dehydrozingerone) from acetone ar (or dehydrozingerone) from acetone and 4-rwydroxybenzaldehyde for varwin) (2 points) HGH HO Ho7 - o nucophilic Atau dehydration 2. Describe at least two different limitations to the aldol reaction. (1 point) 3. Provide the product for the intramolecular aldol reaction below. (1 point) i i NaOH. 4. Provide the starting reagents...
Complete the mechanism for an aldol condensation in base by drawing in the curved arrows where needed. Step 1. Generation of enolate nucleophile. Select Draw Rings More o @ 21@ Step 2. Nucleophilic addition of enolate to a carbonyl. Select Draw Rings More Erase Step 3. Generation of B-hydroxyketone. Select Draw Rings More Erase Step 4.Dehydration to a.B-unsaturated ketone. Select Draw Rings More Erase II | A || H > -H
Draw a mechanism (with arrow pushing) for the base-catalysed aldol addition and condensation of ethanal with itself, including both steps . Highlight the α hydrogen atoms in your scheme
23. a) Write a reasonable mechanism, using good curved arrow notation, for the aldol condensation of propanal. b) Show how you would prepare the following molecule from 1-propanol, formaldehyde, and ethylamine as the only source of carbon and nitrogen, using any necessary organic or inorganic reagents 23. a) Write a reasonable mechanism, using good curved arrow notation, for the aldol condensation of propanal. i H NaOH H2O heat b) Show how you would prepare the following molecule from 1-propanol, formaldehyde,...
Predict major product (WITH MECHANISM) of the base-catalyzed aldol condensation with dehydration of: methyl phenyl ketone + 2,2-dimethylpropanal
Propose a complete, stepwise, curved-arrow reaction mechanism for this base-catalyzed retro-aldo transformation. You do not need to worry about stereochemistry. Draw the best resonance contributor for each proposed intermediate excess NaOH mele H,O, Heat Өон Yo- 21
Define (reaction only) the base catalyzed cross-aldol condensation reaction between excess benzaldehyde and propanaldehyde (No mechanism needed)!
Draw an arrow pushing mechanism for the aldol condensation of cyclopentanone and p-methylbenzaldehyde. Please show all of the steps clearly. Thank you!
Draw a curved arrow mechanism for the following acid-catalyzed isomerization reaction. You must show all intermediates. (10 points) 80 - H20)