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pressure, find out the 1. For helium gas at moderate temperature T and low followings if the helium container's vol...
please solve 2 problems restriction on the total number of particles 4. For photons, there is no (a) Find out the numbe...
please solve 2 problems
restriction on the total number of particles 4. For photons, there is no (a) Find out the number of photons per quantum state 8T V 2 dv 4 (b) Find out the partition function, Z. cf. g(v)dv 15 e 1 In z n (1 e hulkT) for a (c) Calculate the internal energy, U single oscillator (d) Calculate the pressure, P. 4. For solids Einstein the vibrational levels given energy are as € (j+h, j 0,1,2,....
Question 10 Statistical thermodynamics may be used to find the radiation pressure P for cavity (or...
Question 10 Statistical thermodynamics may be used to find the radiation pressure P for cavity (or black body) radiation in terms of the energy per unit volume u. (a) An ideal quantum gas comprises non-interacting identical particles with discrete quantum states labelled 1, 2, ...,r ,....The partition function is given by Z (T,V,N)- > exp(-B(n,&, + п,&, +...)} пп. (i) Define the symbols n1, n2,...,n,...and 81, 82, ..., Er,... (iiExplain why, for photons, the partition function may be expressed as:...
Answer a total of any THREE out of the four questions. Put the solution to each problem in a separate blue book and put the number of the problem and your name on the front of each book. If you su...
Answer a total of any THREE out of the four questions. Put the solution to each problem in a separate blue book and put the number of the problem and your name on the front of each book. If you submit solutions to more than three problems, only the first three problems as listed on the exam will be graded. Some possibly useful information: Sterling's asymptotic series: N In N-N + 1 ln(2nN] In N! N → oo, as 2...
3. For diatomic ideal gases at room temperature, find out the change in entropy due to mixing using the following parti...
3. For diatomic ideal gases at room temperature, find out the change in entropy due to mixing using the following partition functions hv expl2kT T V( h2 Ztranslation rotation vibration h2 hv 1 exp 4. For solids, Einstein the vibrational levels given energy are as hv, j-0,1,2,.. Assuming that the N 2 strongly coupled atoms are +=3 equivalent to 3N simple harmonic independent oscillators, find out the followings (a) Equation for the vibrational energy as a function of temperature (b)...
02) Consider a hydrostatic system represented by the thermodynamic variables volume V, pressure P and temperature...
02) Consider a hydrostatic system represented by the thermodynamic variables volume V, pressure P and temperature T. a) Consider entropy S = S(T, V) and derive the equation TdS. Tas = Cvat +T (1) dV. V Show that this equation can be written as follows BT TdS = CydT + PDV where Cv is the thermal capacity at constant volume, B is the isobaric expansiveness and K is isothermal compressibility: b) Consider a gas described by the equation of state...
1 The Gibbs Paradox Consider N particles, each of mass m, in a 3-dimensional volume V at temperature T. Each particle i...
1 The Gibbs Paradox Consider N particles, each of mass m, in a 3-dimensional volume V at temperature T. Each particle i has momentum pi. Assume that the particles are non-interacting (ideal gas) and distinguishable. a) (2P) Calculate the canonical partition function N P for the N-particle system. Make sure to work out the integral. b) (2P) Calculate the free energy F--kBTlnZ from the partition function Z. Is F an extensive quantity? c) (2P) Calculate the entropy S F/oT from...
I need help with exercise #2. Your help will be really appreciated and rated. MAXWELL'S EQUATION...
I need help with exercise #2. Your help will be really
appreciated and rated.
MAXWELL'S EQUATION I. Maxwell's Equation: Our first (of mony) distribution functions. Very important A. The "Maxwell-Boltzman speed distribution" gives the speed distribution, fiv), of particles confined to NN()d, which a volume, V, and in thermal equilibrium at a temperature, T. () is the number of particles moving within dv of a speed, v Distributions of this type can be considered as the product of three terms...
105Pa, initial temperature T-300K, and an initial 1. An ideal gas with initial pressure 2 volume V - 1m3 expands isothermally to a final volume of 2m3. Then, the gas returns to its initial state, fir...
105Pa, initial temperature T-300K, and an initial 1. An ideal gas with initial pressure 2 volume V - 1m3 expands isothermally to a final volume of 2m3. Then, the gas returns to its initial state, first by constant pressure (isobaric) contraction, and then by a change at constant volume (isochoric) a) Draw a PV diagram of this process. What's the total change in thermal energy of the entire process? b) What's the work done by the environment on the gas?...
3,9? Part I: Choose five of these questions. (12 points each) Ana 1. Here is the...
3,9?
Part I: Choose five of these questions. (12 points each) Ana 1. Here is the van der Waals Equation for one mole of gas: P -by vary with dV and dT? Bethe Given this equation, how does the infinitesimal change in pressure, dl. as specific as possible. (In other words, evaluate the derivatives.) andard 2. A sample of gas molecules of density D N / Vwhere N is the numbe volume) is moving with a speed y, in the...
1,4? Part I: Choose five of these questions. (12 points each) 1. Here is the van...
1,4?
Part I: Choose five of these questions. (12 points each) 1. Here is the van der Waals Equation for one mole of gas P Given this equation, how does the infinitesimal change in pressure, or as specific as possible. (In other words, evaluate the derivatives.) with d V and dT? B e-NV, where is the sity her of molecules and V is the fshe wall perpendicular to the 2. A sample of gas molecules of density N e e...
please solve 2 problems
restriction on the total number of particles 4. For photons, there is no (a) Find out the number of photons per quantum state 8T V 2 dv 4 (b) Find out the partition function, Z. cf. g(v)dv 15 e 1 In z n (1 e hulkT) for a (c) Calculate the internal energy, U single oscillator (d) Calculate the pressure, P. 4. For solids Einstein the vibrational levels given energy are as € (j+h, j 0,1,2,....
Question 10 Statistical thermodynamics may be used to find the radiation pressure P for cavity (or black body) radiation in terms of the energy per unit volume u. (a) An ideal quantum gas comprises non-interacting identical particles with discrete quantum states labelled 1, 2, ...,r ,....The partition function is given by Z (T,V,N)- > exp(-B(n,&, + п,&, +...)} пп. (i) Define the symbols n1, n2,...,n,...and 81, 82, ..., Er,... (iiExplain why, for photons, the partition function may be expressed as:...
Answer a total of any THREE out of the four questions. Put the solution to each problem in a separate blue book and put the number of the problem and your name on the front of each book. If you submit solutions to more than three problems, only the first three problems as listed on the exam will be graded. Some possibly useful information: Sterling's asymptotic series: N In N-N + 1 ln(2nN] In N! N → oo, as 2...
3. For diatomic ideal gases at room temperature, find out the change in entropy due to mixing using the following partition functions hv expl2kT T V( h2 Ztranslation rotation vibration h2 hv 1 exp 4. For solids, Einstein the vibrational levels given energy are as hv, j-0,1,2,.. Assuming that the N 2 strongly coupled atoms are +=3 equivalent to 3N simple harmonic independent oscillators, find out the followings (a) Equation for the vibrational energy as a function of temperature (b)...
02) Consider a hydrostatic system represented by the thermodynamic variables volume V, pressure P and temperature T. a) Consider entropy S = S(T, V) and derive the equation TdS. Tas = Cvat +T (1) dV. V Show that this equation can be written as follows BT TdS = CydT + PDV where Cv is the thermal capacity at constant volume, B is the isobaric expansiveness and K is isothermal compressibility: b) Consider a gas described by the equation of state...
1 The Gibbs Paradox Consider N particles, each of mass m, in a 3-dimensional volume V at temperature T. Each particle i has momentum pi. Assume that the particles are non-interacting (ideal gas) and distinguishable. a) (2P) Calculate the canonical partition function N P for the N-particle system. Make sure to work out the integral. b) (2P) Calculate the free energy F--kBTlnZ from the partition function Z. Is F an extensive quantity? c) (2P) Calculate the entropy S F/oT from...
I need help with exercise #2. Your help will be really
appreciated and rated.
MAXWELL'S EQUATION I. Maxwell's Equation: Our first (of mony) distribution functions. Very important A. The "Maxwell-Boltzman speed distribution" gives the speed distribution, fiv), of particles confined to NN()d, which a volume, V, and in thermal equilibrium at a temperature, T. () is the number of particles moving within dv of a speed, v Distributions of this type can be considered as the product of three terms...
105Pa, initial temperature T-300K, and an initial 1. An ideal gas with initial pressure 2 volume V - 1m3 expands isothermally to a final volume of 2m3. Then, the gas returns to its initial state, first by constant pressure (isobaric) contraction, and then by a change at constant volume (isochoric) a) Draw a PV diagram of this process. What's the total change in thermal energy of the entire process? b) What's the work done by the environment on the gas?...
3,9?
Part I: Choose five of these questions. (12 points each) Ana 1. Here is the van der Waals Equation for one mole of gas: P -by vary with dV and dT? Bethe Given this equation, how does the infinitesimal change in pressure, dl. as specific as possible. (In other words, evaluate the derivatives.) andard 2. A sample of gas molecules of density D N / Vwhere N is the numbe volume) is moving with a speed y, in the...
1,4?
Part I: Choose five of these questions. (12 points each) 1. Here is the van der Waals Equation for one mole of gas P Given this equation, how does the infinitesimal change in pressure, or as specific as possible. (In other words, evaluate the derivatives.) with d V and dT? B e-NV, where is the sity her of molecules and V is the fshe wall perpendicular to the 2. A sample of gas molecules of density N e e...
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