The concept used to solve this problem is based on the Haworth projection of an organic compound.
The Haworth projection is basically used to represent sugars in the cyclic form. It tells which atom is above the plane and which is below the plane.
The Haworth structure can be drawn from the Fischer projection. The characteristics of Haworth projection is as follow.
The carbon atom is implicit type of atom in the Haworth structure. The carbon present on the 1 number is known as anomeric carbon.
Hydrogen atoms are present on carbon atom.
A thicker line represents the atoms which are closer to observer.
First write the Fischer projection of D-fructose as follow.
Now, assign numbers to each carbon in the structure as follow.
Now, from the Fischer projection draw the Haworth projection as follow.
The atoms on left side of Fischer projection will present on upper position in the five-membered ring and the atoms on right side will present lower position in the ring.
Ans:The Haworth projection of -D-fructose is as follow.
Draw the Haworth projection of beta-D-fructose by labeling the furanose ring. The anomeric carbon is shown....
Draw the Haworth projection of alpha-D-galactose by labeling the pyranose ring. The anomeric carbon is shown. Labels may be used more than once.
Draw the cyclic Haworth projection of the beta-furanose form of D-fructose. Show the mecahnism behind it.14 (2).pdf
Convert the Fischer projection to the Haworth projection of the B-furanose form by moving the substituents to the appropriate positions. The anomeric carbon is shown. Convert the Fischer projection to the Haworth projection of the B-furanose form by moving the substituents to the appropriate positions. The anomeric carbon is shown. CH2OH =0 HO—C—H Cyclization H-¢-OH Answer Bank CH OH H—¢-OH CH,OH CH2OH
Convert the Fischer projection to the Haworth projection of the a-furanose form by moving the substituents to the appropriate positions. The anomeric carbon is shown.
Use the Haworth projection to draw D-ribose in the beta-furanose and alpha-pyranose forms.
Complete the Haworth projection of -D-galactose by placing labels on the pyranose ring. Labels may be used more than once. Note, there are two different hydroxy labels-make sure the oxygen is next to the bond. Answer Bank HO OH H СН2ОН
5 a) identify the anomeric carbon in the below molecule b) identify the thpe of ring pyranose or furanose c) identify if it is a or b 6 a) identify the anomeric carbon in the below molecule b) identify the thpe of ring pyranose or furanose c) identify if it is a or b 7 The structure of 6-carbon ketose sugar is shown. Draw the common cyclic structure of this structure (both a and b form) 8 Identify the relationship...
1. use the Haworth projection formula to draw each of the following monosaccharides: a.alpha-D-Glucose 6-phosphate b. alpha-D-Deoxyribose c. alpha-L-Fructose
1. Draw glucose B-D-glucose in a chair form, and circle the anomeric carbon. Why is the anomeric carbon significant? 2. Why is cyclization of sugars important? What does the concept of mutarotation indicate to us about dual roles of monosaccharides? Two part question: 3. Why are monosaccharides most commonly found in pyran and furan ring forms, rather than: A) other ring motifs -(think along the lines of: why NOT 3,4, or 7 membered rings)? B) in their linear form? 4....
organic chem 11. (a) (6 points) D-tagatose is shown below. Draw the Haworth projection for B-D-tagatopyranose. CH2OH EO HO НО. -OH CH2OH D-tagatose (b) (4 points) Draw Fischer projection for L-tagatose. CH2OH EO HO НО. -OH CH2OH D-tagatose