Question

Draw the product of the following reaction between propanoyl chloride and p-methoxynitrobenzene. Include formal charges.

Draw the product of the following reaction between propanoyl chloride and p-methoxynitrobenzene. Include formal charges.

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Concepts and reason

Friedel craft acylation reaction is an electrophilic substitution reaction on aromatic rings, where the acyl cation acts as an electrophile in the process. This reaction process is catalyzed by a Lewis acid.

Fundamentals

General friedal craft acylation reaction

Orhm.
AlCl3
+
K
X

Acylation reaction proceeds through three steps

1.Generation of electrophile from the acyl chloride

2.Electrophile substitution on aryl ring

3.Transfer of proton to regain aromaticity

1.Generation of electrophile from the acyl chloride

The given acyl chloride is propionyl chloride

Lai
+
AlCl3
LO:
+ nicht
+
AI
OG

2.Electrophile substitution on aryl ring

3.Transfer of proton to attain aromiticity

НСІ
Stone
AICI4

Ans:

The complete reaction is

OS
AICI:
-C1

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