Homework Answers
12) option D is correct
Explanation: NaBH4 is a mild reducing agent which reduces ketone to secondary alcohol and it cannot reduce carboxylic acid.
13) option C is correct
Explanation: PCC is a oxidizing agent which oxidizes primary alcohol to aldehyde and secondary alcohol to ketone.
14) option B is correct
Explanation: H2CrO4 is a strong oxidizing agent which oxidizes primary alcohol to carboxylic acid and secondary alcohol to ketone.
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12. What is the product of the following reaction? obubo THOCH(CH OH OH NaBH OH Hао...
Ch 16.1 Give the major product(s) or the following reaction ao,a OH N ? OH io...
Ch 16.1
Give the major product(s) or the following reaction ao,a OH N ? OH io OH H There is no reaction under these conditions or the correct product is not listed here Gve the major product(s) of the following reaction COCH OH N H OH 0 OH H There is no reaction under these conditions or the correct product is not listed here. В 1) BAIH (-Bu), (-78°C) (0.5 moles) 2) ное ? оо н ОН ОН OCH, OH...
What is the product of the 1 но reaction? so NO 6. What is the product...
What is the product of the 1 но reaction? so NO 6. What is the product of the reaction он HSO (B) (A) NO он NO HOS (B) (A) soH (D) (C) NOz OH HO. both (B) and (C) (D) (C) HO,S 2 What is the product of the reaction? NoOH Which compound will yield only one product after nitration with HNO/HSo 7. OH .сн, (A) (B) сHа- (B) (A) но,, сн, OH (C) (D) сH,сH, none of the these...
8. What is the major product of the following reaction? Cн, CH Cl (solvent) C сн, a сн, CH CH H OH H OH OH 9. What...
8. What is the major product of the following reaction? Cн, CH Cl (solvent) C сн, a сн, CH CH H OH H OH OH 9. What is the degree of unsaturation of C10H12N203? a 4 b.5 c. 6 d.7 10. Which of the following statement about using curved arrows in polar reaction mechanism is true? a. The nucleophile can be either negatively charged or positively charged. b. The electrophile must be neutral. c. Electrons move from a nucleophilic source...
11. What would be the major organic product of this base-catalyzed reaction? 8. What would be the major product of...
11. What would be the major organic product of this base-catalyzed reaction? 8. What would be the major product of this reaction? CH CH2CH CH (CH)yC-CH+CH.CCH, O o (A) CH-CH.CH,сснсн сH,CH, (в) сн.CH.CH,CH, он снсH,CH,COO, он о CH CH CH,CHCHCH сHCH, CH CH9 снс-CH-с—сн сн, (A) (C) OH O CHy сне-с-с-сн, сH, сн, (B) он (D) CH смссн,-с-с-сн, CH он сн снссн сн-с-сн, сн, (C) CHCH CH CHCH,CH CH,CH 9. Which of these is not a step in the mechanism...
25) What is the product of the reaction below? OH H2SO4 heat OH A) A В)...
25) What is the product of the reaction below? OH H2SO4 heat OH A) A В) В C)D D C 26) Which of the synthetic procedures below would carry out the following transformation? 26) OH н,с сн; H3COCH; A) LiAlH, followed by H2SO./heat B) O, followed by (CH), C) PCC/CHCl, followed by HIO, D) NaBH,/methanol followed by HIO A) A B)B C)C D) D
What is the major Organic product of the following reaction? o CH N OH O NH...
What is the major Organic product of the following reaction? o CH N OH O NH CH; woon OCH; (a) (b) (c) N NH, CH; (d) ce Considering both regiochemistry and stereochemistry, what is the major Organic product of the following reaction? о H,C, 1) -MgCI 2) Н,0* ОН ОН нс ОН не КА HC ІН (b) (c) CH ОН H О Н HC H нс, What is the major Organic product of the following sequence of reactions? 1) NaH,...
12-14 confused helpp 12. What is the major organic product obtained from the following reaction? -сн,...
12-14 confused helpp
12. What is the major organic product obtained from the following reaction? -сн, Нс- ОН pyridine CH3 1 a. b. 2 3 с. d. 4 13. What is the major organic product obtained from the following reaction? 1 H-SO он SH 4 3 1 a. b. 3 с. 4 d. What is the major organic product obtained from the following reaction? 14. CrO3 OH H2SO, H2O 1-butene, CH2CH CH-CH butanal, CH,CH,CH,CHO butanone, CH:CH-COCH butanoic acid, CH CH-CH,COOH...
25) What is the product of the reaction below? OH - H2SO4 heat ОН D) D)...
25) What is the product of the reaction below? OH - H2SO4 heat ОН D) D) i A) A B) B C)D DC 26) Which of the synthetic procedures below would carry out the following transformation? 26) OH H.C CH3 H H .C CH3 A) LiAlH, followed by H,SO,/heat B) O, followed by (CH3)2S C) PCC/CH,Cl, followed by HIO D) NaBH,/methanol followed by HIO B) B C)C D) D A A
Predict the product from the following sequence: H OH H07 NaBH CH;OH ? heat (-H2O) OH...
Predict the product from the following sequence: H OH H07 NaBH CH;OH ? heat (-H2O) OH OH Z and E) H ОН ОН II DI (Z and E) OH H H OH IV O A. IV OB. OC. V OD. 11 E. III
Predict the products Predict the Product. Provide the stable organic product(s) for each reaction below NaBH...
Predict the products
Predict the Product. Provide the stable organic product(s) for each reaction below NaBH CHOH 1 2 HCI, H,0 NaBH, (1 вg.)., сн,он 1. 2. HC, н,о 1. NaBH(осH (1 eq.), сн,он CI 2. HCI, H,O 1. LIAIH (1 eq.), THF Br 2. HCI, H2O
Ch 16.1
Give the major product(s) or the following reaction ao,a OH N ? OH io OH H There is no reaction under these conditions or the correct product is not listed here Gve the major product(s) of the following reaction COCH OH N H OH 0 OH H There is no reaction under these conditions or the correct product is not listed here. В 1) BAIH (-Bu), (-78°C) (0.5 moles) 2) ное ? оо н ОН ОН OCH, OH...
What is the product of the 1 но reaction? so NO 6. What is the product of the reaction он HSO (B) (A) NO он NO HOS (B) (A) soH (D) (C) NOz OH HO. both (B) and (C) (D) (C) HO,S 2 What is the product of the reaction? NoOH Which compound will yield only one product after nitration with HNO/HSo 7. OH .сн, (A) (B) сHа- (B) (A) но,, сн, OH (C) (D) сH,сH, none of the these...
8. What is the major product of the following reaction? Cн, CH Cl (solvent) C сн, a сн, CH CH H OH H OH OH 9. What is the degree of unsaturation of C10H12N203? a 4 b.5 c. 6 d.7 10. Which of the following statement about using curved arrows in polar reaction mechanism is true? a. The nucleophile can be either negatively charged or positively charged. b. The electrophile must be neutral. c. Electrons move from a nucleophilic source...
11. What would be the major organic product of this base-catalyzed reaction? 8. What would be the major product of this reaction? CH CH2CH CH (CH)yC-CH+CH.CCH, O o (A) CH-CH.CH,сснсн сH,CH, (в) сн.CH.CH,CH, он снсH,CH,COO, он о CH CH CH,CHCHCH сHCH, CH CH9 снс-CH-с—сн сн, (A) (C) OH O CHy сне-с-с-сн, сH, сн, (B) он (D) CH смссн,-с-с-сн, CH он сн снссн сн-с-сн, сн, (C) CHCH CH CHCH,CH CH,CH 9. Which of these is not a step in the mechanism...
25) What is the product of the reaction below? OH H2SO4 heat OH A) A В) В C)D D C 26) Which of the synthetic procedures below would carry out the following transformation? 26) OH н,с сн; H3COCH; A) LiAlH, followed by H2SO./heat B) O, followed by (CH), C) PCC/CHCl, followed by HIO, D) NaBH,/methanol followed by HIO A) A B)B C)C D) D
What is the major Organic product of the following reaction? o CH N OH O NH CH; woon OCH; (a) (b) (c) N NH, CH; (d) ce Considering both regiochemistry and stereochemistry, what is the major Organic product of the following reaction? о H,C, 1) -MgCI 2) Н,0* ОН ОН нс ОН не КА HC ІН (b) (c) CH ОН H О Н HC H нс, What is the major Organic product of the following sequence of reactions? 1) NaH,...
12-14 confused helpp
12. What is the major organic product obtained from the following reaction? -сн, Нс- ОН pyridine CH3 1 a. b. 2 3 с. d. 4 13. What is the major organic product obtained from the following reaction? 1 H-SO он SH 4 3 1 a. b. 3 с. 4 d. What is the major organic product obtained from the following reaction? 14. CrO3 OH H2SO, H2O 1-butene, CH2CH CH-CH butanal, CH,CH,CH,CHO butanone, CH:CH-COCH butanoic acid, CH CH-CH,COOH...
25) What is the product of the reaction below? OH - H2SO4 heat ОН D) D) i A) A B) B C)D DC 26) Which of the synthetic procedures below would carry out the following transformation? 26) OH H.C CH3 H H .C CH3 A) LiAlH, followed by H,SO,/heat B) O, followed by (CH3)2S C) PCC/CH,Cl, followed by HIO D) NaBH,/methanol followed by HIO B) B C)C D) D A A
Predict the product from the following sequence: H OH H07 NaBH CH;OH ? heat (-H2O) OH OH Z and E) H ОН ОН II DI (Z and E) OH H H OH IV O A. IV OB. OC. V OD. 11 E. III
Predict the products
Predict the Product. Provide the stable organic product(s) for each reaction below NaBH CHOH 1 2 HCI, H,0 NaBH, (1 вg.)., сн,он 1. 2. HC, н,о 1. NaBH(осH (1 eq.), сн,он CI 2. HCI, H,O 1. LIAIH (1 eq.), THF Br 2. HCI, H2O
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