compare and contrast the colorimetric determination of a titration equivalence point using an acid-base indicator versus...
compare and contrast the colorimetric determination of a titration equivalence point using an acid-base indicator versus electrochemical determination of a titration equivalence point using a pH meter.
please explain pros and cons of both methods
Homework Answers
Acid-Base indicators (e.g., phenolphthalein, methyl orange) change colors depending on the pH. A drop of indicator solution is added to the titration at the start; when the color changes the endpoint has been reached, this is an approximation of the equivalence point. Whereas, an acid or a base is quantitatively determined by titration using pH meter to detect the equivalence point rather than using a visual indicator. This has the advantage that one actually monitors the change in pH at the equivalence point rather than just observing the change in color of a visual indicator. This eliminates any indicator blank error.
Acid-base indicator method is easy method whereas determination of equivalence point using pH meter is a tedious job, but it has more accuracy.
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compare and contrast the colorimetric determination of a titration equivalence point using an acid-base indicator versus...
A vinegar titration was completed using a pH meter as an indicator of the changing pH....
A vinegar titration was completed using a pH meter as an indicator of the changing pH. A 25.00 mL sample of diluted vinegar (diluted by a factor of 5) was placed in a beaker and subsequently titrated with 0.1098 M NaOH. A derivative curve of the titration suggested that the equivalence point occurred at 40.90 mL. Calculate the mass percent of CH_3COOH. (The density of vinegar is 1.008 g/mL.) Moles of base at the equivalence point = Moles of acid...
Mark each of the following statements about the ½ equivalence point of an acid-base titration TRUE...
Mark each of the following statements about the ½ equivalence point of an acid-base titration TRUE or FALSE. a. It is the point in the titration when the concentration of weak acid (HA) being titrated is equal to the concentration of the conjugate base (A− ). b. It is the point halfway between the beginning of the titration of a weak acid or weak base and the equivalence point. 2 c. When a strong acid is titrated with a strong...
Which of the following is true for the titration of a weak acid with a strong base? O a. The pH at the equivalence...
Which of the following is true for the titration of a weak acid with a strong base? O a. The pH at the equivalence point is acidic. b. A buffer solution is formed before the equivalence point. OC. The initial pH equals -log (conc. of the acid). Od. The indicator changes its color at the half-neutralization point.
2. Weak Acid versus Strong Base Derive a titration curve for the titration of 50.0 mL...
2. Weak Acid versus Strong Base Derive a titration curve for the titration of 50.0 mL of 0.100 M formic acid, HCHO2 (Ka 1.80 x 104) with 0.100 M N2OH. Calculate the pH for the following volumes of NaOH (0 mL, 10 mL, 25 mL, 40 mL, 50 mL, 55 mL, 60 mL). Volume of N2OH, in milliters pH (a) (b) (c) (d) (e) (f) (g) 0 10 25 40 50 55 60 pH at the equivalence point Specify your...
1. Strong Acid versus Strong Base Derive a titration curve for the titration of 50.0 mL...
1. Strong Acid versus Strong Base Derive a titration curve for the titration of 50.0 mL of 0.150 M HCl with 0.100 M NaOH. Calculate the pH for the following volumes of NaOH (0 mL, 25 mL, 50 mL, 70 mL, 75 mL, 80 mL, 90 mL, 100 mL). pH Volume of NaOH, in milliters 0 25 50 70 75 80 90 100 L(g) (h) pH at the equivalence point Specify your choice of indicator
Equivalence Point for Titration #1: 24.96 mL Equivalence Point for Titration #2: 25.40 mL Equivalence Point...
Equivalence Point for Titration #1: 24.96
mL
Equivalence Point for Titration #2: 25.40
mL
Equivalence Point for Titration #3: 25.20
mL
Midpoint pH for Titration #3: 9.80
QUESTIONS:
4) Set up the calculation required to determine
the concentration of the NaOH solution via titration of a given
amount of KHP. Include all numbers except the given mass of
KHP.
5) Set up the calculation required to determine
the concentration of the unknown strong acid via titration with a
known volume...
• Determination of the Dissociation Constant of a Weak Acid Report Sheet The pH at one-half the equivalence point...
• Determination of the Dissociation Constant of a Weak Acid Report Sheet The pH at one-half the equivalence point in an acid-base titration was found to be 5.67. What is the value of K, for this unknown acid? 8. If 30.15 mL of 0.0995 M NaOH is required to neutralize 0.279 g of an unknown acid, HA, what is the molar mass of the unknown acid? the Assuming that K is 1.85x10 for acetic acid, calculate the pH at one-half...
DATA AND CALCULATIONS Time at equivalence point (s) Time of color Trial *Equation for acid-base reaction...
DATA AND CALCULATIONS Time at equivalence point (s) Time of color Trial *Equation for acid-base reaction change (s) NaOH+HCI - 21 0s 1 250.5 NaOH+ HC2H3O2- 2 8l.55 99s 3 NH3+ HCl- 930s 4 NH3 + HC2H3O2- 90.55 81.Os Complete the reactions above. Attach copies of all four graphs to this report. 1. 2. Examine the time data for each of the Trials 1- -4. In which trial(s) did the indicator change color at about the same time as the...
ACID-BASE TITRATION 4) What is the purpose of the indicator? 5) Does the indicator participate in...
ACID-BASE TITRATION 4) What is the purpose of the indicator? 5) Does the indicator participate in the reaction with the acid and base? 6) Define endpoint. Define equivalence point. Calculate the volume in mL of 0.100M NaOH required to neutralize 2.50mL of 0.150M HC2H302 HC2H302(aq) + NaOH(aq) + NaC2H2O2(aq) + H2O(1)
1. What is the definition of an 'equivalence point' in an acid/base titration? (1 point) 2....
1. What is the definition of an 'equivalence point' in an acid/base titration? (1 point) 2. In part one of the experiment, you will prepare the acid solutions being titrated from a stock solution. Describe how you will accurately prepare 10.00 mL of 0.100 M HCl solution using a 1.00 M HCl stock solution. In your response to this question, be very specific about the quantities of stock solution and deionized water to be used in the dilution and the...
A vinegar titration was completed using a pH meter as an indicator of the changing pH. A 25.00 mL sample of diluted vinegar (diluted by a factor of 5) was placed in a beaker and subsequently titrated with 0.1098 M NaOH. A derivative curve of the titration suggested that the equivalence point occurred at 40.90 mL. Calculate the mass percent of CH_3COOH. (The density of vinegar is 1.008 g/mL.) Moles of base at the equivalence point = Moles of acid...
Which of the following is true for the titration of a weak acid with a strong base? O a. The pH at the equivalence point is acidic. b. A buffer solution is formed before the equivalence point. OC. The initial pH equals -log (conc. of the acid). Od. The indicator changes its color at the half-neutralization point.
2. Weak Acid versus Strong Base Derive a titration curve for the titration of 50.0 mL of 0.100 M formic acid, HCHO2 (Ka 1.80 x 104) with 0.100 M N2OH. Calculate the pH for the following volumes of NaOH (0 mL, 10 mL, 25 mL, 40 mL, 50 mL, 55 mL, 60 mL). Volume of N2OH, in milliters pH (a) (b) (c) (d) (e) (f) (g) 0 10 25 40 50 55 60 pH at the equivalence point Specify your...
1. Strong Acid versus Strong Base Derive a titration curve for the titration of 50.0 mL of 0.150 M HCl with 0.100 M NaOH. Calculate the pH for the following volumes of NaOH (0 mL, 25 mL, 50 mL, 70 mL, 75 mL, 80 mL, 90 mL, 100 mL). pH Volume of NaOH, in milliters 0 25 50 70 75 80 90 100 L(g) (h) pH at the equivalence point Specify your choice of indicator
Equivalence Point for Titration #1: 24.96
mL
Equivalence Point for Titration #2: 25.40
mL
Equivalence Point for Titration #3: 25.20
mL
Midpoint pH for Titration #3: 9.80
QUESTIONS:
4) Set up the calculation required to determine
the concentration of the NaOH solution via titration of a given
amount of KHP. Include all numbers except the given mass of
KHP.
5) Set up the calculation required to determine
the concentration of the unknown strong acid via titration with a
known volume...
• Determination of the Dissociation Constant of a Weak Acid Report Sheet The pH at one-half the equivalence point in an acid-base titration was found to be 5.67. What is the value of K, for this unknown acid? 8. If 30.15 mL of 0.0995 M NaOH is required to neutralize 0.279 g of an unknown acid, HA, what is the molar mass of the unknown acid? the Assuming that K is 1.85x10 for acetic acid, calculate the pH at one-half...
DATA AND CALCULATIONS Time at equivalence point (s) Time of color Trial *Equation for acid-base reaction change (s) NaOH+HCI - 21 0s 1 250.5 NaOH+ HC2H3O2- 2 8l.55 99s 3 NH3+ HCl- 930s 4 NH3 + HC2H3O2- 90.55 81.Os Complete the reactions above. Attach copies of all four graphs to this report. 1. 2. Examine the time data for each of the Trials 1- -4. In which trial(s) did the indicator change color at about the same time as the...
ACID-BASE TITRATION 4) What is the purpose of the indicator? 5) Does the indicator participate in the reaction with the acid and base? 6) Define endpoint. Define equivalence point. Calculate the volume in mL of 0.100M NaOH required to neutralize 2.50mL of 0.150M HC2H302 HC2H302(aq) + NaOH(aq) + NaC2H2O2(aq) + H2O(1)
1. What is the definition of an 'equivalence point' in an acid/base titration? (1 point) 2. In part one of the experiment, you will prepare the acid solutions being titrated from a stock solution. Describe how you will accurately prepare 10.00 mL of 0.100 M HCl solution using a 1.00 M HCl stock solution. In your response to this question, be very specific about the quantities of stock solution and deionized water to be used in the dilution and the...
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