10. Please Check 1 by 1 and read carefully. I would need a perfect score for...
Need Help. Will Rate If Complete. Q 8- The following molecules can be formed by either: Michael Reaction; Enamine Acylation; Acetoacetic Ester Synthesis; Michael Addition; Malonic Ester Synthesis; Robinson Annulation; Aldol Condensation; Claisen Condensation; Intramolecular Aldol Condensation; Dieckmann Condensation or a Combination of two of the above listed reaction. In each case write the proper of the reaction on the line and dissect the product into appropriate starting material. In some cases there might only be one starting material. You...
28- The following molecules can be formed by either: Michael Reaction; Enamine Acylation; Acetoacetic Ester Synthesis; Michael Addition; Malonic Ester Synthesis; Robinson Annulation; Aldol Condensation; Claisen Condensation; Intramolecular Aldol Condensation; Dieckmann Condensation or a Combination of two of the above listed reaction. In each case write the proper of the reaction on the line and dissect the product into appropriate starting material. In some cases there might only be one starting material. You may use any one of the above...
how to approach these reactions? 08. The following molecules can be formed by either: Michael Reaction; Enamine Acylation; Acetoacetic Ester Synthesis; Michael Addition; Malonic Ester Synthesis; Robinson Annulation; Aldol Condensation; Claisen Condensation; Intramolecular Aldol Condensation; Dieckmann Condensation or a Combination of two of the above listed reaction. In each case write the proper of the reaction on the line and dissect the product into appropriate starting material. In some cases there might only be one starting material. You may use...
Need Help. Will Rate If Complete. 1) NaoEt, EtOH Br 2) O 3) H30+ / A. 1) NaoEt, EtOH (s) ar 2) Y Br 3) Hz0+ / A 1) NaOme/MeOH ~ Br OMe 3) Hz0+/A. 1) NaOEt, EtOH 2) V Br 3) NaOEt, EtOH COOEt 5) H30+/A Robinson Annulation NaoEt, EtOH/A come lui OMe 28- The following molecules can be formed by either: Michael Reaction; Enamine Acylation; Acetoacetic Ester Synthesis; Michael Addition; Malonic Ester Synthesis; Robinson Annulation; Aldol Condensation; Claisen...
1. Draw the aldol product formed from an aldol/Claisen reaction with the given starting material(s) using OH or RO in H20 or ROH. (Hint: the product of an aldol reaction is a B-hydroxy carbonyl compound or an a,b- unsaturated carbonyl compound. The a,ß-unsaturated carbonyl will be the major product unless elimination of H2O cannot form the conjugated system.) он Но, но Н,0 НО. ОН НО. он H, H НО. НО.
Post-lab questions (1) In a Michael reaction, an α carbon attacks the β carbon of an α,β-unsaturated carbonyl com pound to afford a 1,5-dicarbonyl compound. Ethyl acetoacetate has two a carbons: why does the a carbon sandwiched between the two carbonyls conduct the attack? Ph Ph 0 Ph Michael OCH2CH3 5 OCH2CH3 OCH2CH 0 This forms... ...not this: Why? (2) In a Robinson annulation, an α,β-unsaturated carbonyl compound reacts with a carbonyl compound to afford a (new) cyclic α,β-unsaturated ketone...
1. A Robinson annulation is a reaction that involves: (i) a Michael addition of an enolate onto an ,ß-unsaturated enone followed by (ii) an intramolecular aldol reaction. The molecule shown below (cyclohexenone X) can be made through two different Robinson annulation reactions. (A) Show the two different sets of starting materials (i.e. ketone 1 &a,p-unsaturated enone 1 and ketone 2 & a,B-unsaturated enone 2) for each Robinson annulation. Draw the reagents/reaction conditions. (B) Then pick one set and draw an...
Answer all please! Thank you in advance. Many of the condensations we have studied are reversible. The reverse reactions are often given the prefix retro-, the Latin word meaning "backward." Propose mechanisms to account for the following reactions 22-76 CH H CH CH3 н* (b) (а) CH С- (сн), —сно CH ОН (retro-aldol and further condensation) но. (retro-aldol) CH OH (d) "ОСн, CH OН OH H,C-CH-CN СООCH (retro-Michael) (retro-aldol and crossed Claisen)
11. What would be the major organic product of this base-catalyzed reaction? 8. What would be the major product of this reaction? CH CH2CH CH (CH)yC-CH+CH.CCH, O o (A) CH-CH.CH,сснсн сH,CH, (в) сн.CH.CH,CH, он снсH,CH,COO, он о CH CH CH,CHCHCH сHCH, CH CH9 снс-CH-с—сн сн, (A) (C) OH O CHy сне-с-с-сн, сH, сн, (B) он (D) CH смссн,-с-с-сн, CH он сн снссн сн-с-сн, сн, (C) CHCH CH CHCH,CH CH,CH 9. Which of these is not a step in the mechanism...
please answer ALL. will give a thumbs up. thank you! Predict the product of the following reaction. (CH3)2NH NaBH CN HO NH OH Determine the product of the following reaction. НСІ о ? ОН СІ ОН -ОН CI None of these products will be formed. СІ ОН Predict the product of the following intramolecular Aldol reaction. NaOH, HAO A i H o مل os