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4. The energy of binding a transition state complex (X) can be determined by writing an...
biochemistry if you could please help me answer the following questions! 741) (5 pts) Transition state theory relate...
biochemistry
if you could please help me answer the following questions!
741) (5 pts) Transition state theory relates the rate constant to the free energy of activation, AG. How can enzymes reduce the activation energy barrier? a) decrease the free energy of the product b) high affinity binding to the transition state c) increase the free energy of the substrate d) increase entropy upon release of product e) bind to the substrate with high affinity 2) (5 pts) Which is...
biochemistry if you could please help me answer the following questions! * 1. (5 pts) Which...
biochemistry
if you could please help me answer the following questions!
* 1. (5 pts) Which of the following is a catalytic mechanism utilize by enzymes? Multiple answers may be correct. Select all that are correct. 1. Acid-base a) acid-base catalysis d. metal-ion catalysis 12. Covalent b covalent catalysis e. transition state binding c. heterogeneou 3. Metalion . Proximin onentation, E 2. 76 pts) What is the "steady-state" assumption in the derivation of the s.clectrosch? Tynsin Michaelis-Menten equation? Sie binding...
Enzymes are important molecules in biochemistry that catalyze reactions. The energy diagram illustrates the difference between...
Enzymes are important molecules in biochemistry that catalyze reactions. The energy diagram illustrates the difference between a catalyzed reaction and an uncatalyzed reaction. Label the energy diagram. Answer Bank AG for reaction activation energy catalyzed reaction reactants (substrate) free energy uncatalyzed reaction reaction progress products transition state What ways do enzymatic catalysts increase the rates of reactions? They shift the reaction equilibrium toward the products. They lower the activation energy of the reaction They decrease the free energy of the...
SCHE 231 Chapter 6, Worksheet 1 Energy Diagrams 1. Why might it be important to understand...
SCHE 231 Chapter 6, Worksheet 1 Energy Diagrams 1. Why might it be important to understand the energy associated with a chemical reaction? What is this energy associated with? 2. Enthalpy What is Enthalpy (AH)? When is ΔΗ Positive? when is ΔΗ negative? In the diagram below, label which reaction is exothermic and which is endothermic Enthalpy 04) Enthalpy Sarting Products materials AN Starting materials Products Reaction coordinate Reaction coordnate 3. Entropy What is Entropy (AS) What contributes to entropy?...
Rodrigo is an enzyme engineer. He wants to know which of four peptide substrates is bound...
Rodrigo is an enzyme engineer. He wants to know which of four peptide substrates is bound most tightly by his engineered enzyme. Which value should he measure and pay attention to? Km KCAT Vo Both A and B kcat, [S], and [E]t Rodrigo's enzyme was assayed with three substrates (A, B, and C). The SAME enzyme concentration used was for each of the three reactions. The results of the three experiments are plotted as Lineweaver-Burke plots below. Considering what you...
1 2 3 4 5 6 7 8 9 Part A Which of the following is/are...
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Part A Which of the following is/are means whereby a catalyst can lower the activation energy of a reaction? quantum tunneling decreasing the number of reactive molecules permanently binding substrates inefficient collisions altering the temperature within the cell to one appropriate for reactions to proceed Subrnit Request Answer Part A An enzyme Obinds substrates in a manner that facilitates the formation of product decreases the rate of a reaction. is always...
Enzymes are important to biology because they can be used to Select one: O a. Control...
Enzymes are important to biology because they can be used to Select one: O a. Control when chemical reactions happen O b. Control where chemical reactions occur O c. Link different chemical reactions O d. Couple ATP hydrolysis to activity O e. All of the above Diffusion is the movement of solute propelled by collisions with water. Diffusion spontaneously transforms energy concentration gradients into energy equilibrium conditions just like any other spontaneous reaction. Select one: O a. high; high O...
21C.1(a) The reaction of propylxanthate ion in acetic acid buffer solutions has the mechanism A− +H+→P....
21C.1(a) The reaction of propylxanthate ion in acetic acid buffer
solutions
has the mechanism A− +H+→P. Near 30 °C the rate constant is given
by the
empirical expression kr=(2.05×1013) e−(8681K)/T dm3mol−1 s−1.
Evaluate the
energy and entropy of activation at 30 °C.
21C.1(b) The reaction A− +H+→P has a rate constant given by the
empirical
expression kr=(6.92×1012)e−(5925K)/T dm3mol−1 s−1. Evaluate the
energy and
entropy of activation at 25 °C.
Please explain why they calculated H=E-RT like that
like why is...
4. Anharmonic potential (15 points) The adjacent figure shows the experimentally determined potential energy curve of the electronic ground state of"Br2, with a few of the vibrational levels. The...
4. Anharmonic potential (15 points) The adjacent figure shows the experimentally determined potential energy curve of the electronic ground state of"Br2, with a few of the vibrational levels. The vibrational transitions are reasonably well described by a harmonic oscillator model, but much more accurately by including a small anharmonic correction term: En/hcVe(n 1/2) - vexe(n + 1/2)2. From fits to experimental data, the values of the constants are 325.32 cm and exe 1.08 cm .5 10 15 (a) Calculate the...
1) If the activation energy of a reaction is 34 kJ/mol and the amount of energy provided by the collision...
1) If the activation energy of a reaction is 34 kJ/mol and the amount of energy provided by the collision of reactants (in the correct orientation) is 28 kl/mol, will a reaction occur? Explain your answer. What could you do to attempt to get this reaction to occur? 2) Using the reaction below, explain what would occur to equilibrium position and why FeCl,(ag)+3KSCN(aq)Fe(SCN), (ag)+3KC[ (aq) + heat A. Performing the reaction in a freezer (ie. removing heat). B. Adding more...
biochemistry
if you could please help me answer the following questions!
741) (5 pts) Transition state theory relates the rate constant to the free energy of activation, AG. How can enzymes reduce the activation energy barrier? a) decrease the free energy of the product b) high affinity binding to the transition state c) increase the free energy of the substrate d) increase entropy upon release of product e) bind to the substrate with high affinity 2) (5 pts) Which is...
biochemistry
if you could please help me answer the following questions!
* 1. (5 pts) Which of the following is a catalytic mechanism utilize by enzymes? Multiple answers may be correct. Select all that are correct. 1. Acid-base a) acid-base catalysis d. metal-ion catalysis 12. Covalent b covalent catalysis e. transition state binding c. heterogeneou 3. Metalion . Proximin onentation, E 2. 76 pts) What is the "steady-state" assumption in the derivation of the s.clectrosch? Tynsin Michaelis-Menten equation? Sie binding...
Enzymes are important molecules in biochemistry that catalyze reactions. The energy diagram illustrates the difference between a catalyzed reaction and an uncatalyzed reaction. Label the energy diagram. Answer Bank AG for reaction activation energy catalyzed reaction reactants (substrate) free energy uncatalyzed reaction reaction progress products transition state What ways do enzymatic catalysts increase the rates of reactions? They shift the reaction equilibrium toward the products. They lower the activation energy of the reaction They decrease the free energy of the...
SCHE 231 Chapter 6, Worksheet 1 Energy Diagrams 1. Why might it be important to understand the energy associated with a chemical reaction? What is this energy associated with? 2. Enthalpy What is Enthalpy (AH)? When is ΔΗ Positive? when is ΔΗ negative? In the diagram below, label which reaction is exothermic and which is endothermic Enthalpy 04) Enthalpy Sarting Products materials AN Starting materials Products Reaction coordinate Reaction coordnate 3. Entropy What is Entropy (AS) What contributes to entropy?...
Rodrigo is an enzyme engineer. He wants to know which of four peptide substrates is bound most tightly by his engineered enzyme. Which value should he measure and pay attention to? Km KCAT Vo Both A and B kcat, [S], and [E]t Rodrigo's enzyme was assayed with three substrates (A, B, and C). The SAME enzyme concentration used was for each of the three reactions. The results of the three experiments are plotted as Lineweaver-Burke plots below. Considering what you...
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2
3
4
5
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8
9
Part A Which of the following is/are means whereby a catalyst can lower the activation energy of a reaction? quantum tunneling decreasing the number of reactive molecules permanently binding substrates inefficient collisions altering the temperature within the cell to one appropriate for reactions to proceed Subrnit Request Answer Part A An enzyme Obinds substrates in a manner that facilitates the formation of product decreases the rate of a reaction. is always...
Enzymes are important to biology because they can be used to Select one: O a. Control when chemical reactions happen O b. Control where chemical reactions occur O c. Link different chemical reactions O d. Couple ATP hydrolysis to activity O e. All of the above Diffusion is the movement of solute propelled by collisions with water. Diffusion spontaneously transforms energy concentration gradients into energy equilibrium conditions just like any other spontaneous reaction. Select one: O a. high; high O...
21C.1(a) The reaction of propylxanthate ion in acetic acid buffer
solutions
has the mechanism A− +H+→P. Near 30 °C the rate constant is given
by the
empirical expression kr=(2.05×1013) e−(8681K)/T dm3mol−1 s−1.
Evaluate the
energy and entropy of activation at 30 °C.
21C.1(b) The reaction A− +H+→P has a rate constant given by the
empirical
expression kr=(6.92×1012)e−(5925K)/T dm3mol−1 s−1. Evaluate the
energy and
entropy of activation at 25 °C.
Please explain why they calculated H=E-RT like that
like why is...
4. Anharmonic potential (15 points) The adjacent figure shows the experimentally determined potential energy curve of the electronic ground state of"Br2, with a few of the vibrational levels. The vibrational transitions are reasonably well described by a harmonic oscillator model, but much more accurately by including a small anharmonic correction term: En/hcVe(n 1/2) - vexe(n + 1/2)2. From fits to experimental data, the values of the constants are 325.32 cm and exe 1.08 cm .5 10 15 (a) Calculate the...
1) If the activation energy of a reaction is 34 kJ/mol and the amount of energy provided by the collision of reactants (in the correct orientation) is 28 kl/mol, will a reaction occur? Explain your answer. What could you do to attempt to get this reaction to occur? 2) Using the reaction below, explain what would occur to equilibrium position and why FeCl,(ag)+3KSCN(aq)Fe(SCN), (ag)+3KC[ (aq) + heat A. Performing the reaction in a freezer (ie. removing heat). B. Adding more...
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