Question

A diprotic acid, H2A,H2A, has acid dissociation constants of ?a1=4.15×10−4Ka1=4.15×10−4 and ?a2=3.73×10−12.Ka2=3.73×10−1...

A diprotic acid, H2A,H2A, has acid dissociation constants of ?a1=4.15×10−4Ka1=4.15×10−4 and ?a2=3.73×10−12.Ka2=3.73×10−12. Calculate the pH and molar concentrations of H2A,H2A, HA−,HA−, and A2−A2− at equilibrium for each of the solutions.

A 0.176 M0.176 M solution of H2A.H2A.

pH =

[H2A]=[H2A]=

MM

[HA−]=[HA−]=

MM

[A2−]=[A2−]=

MM

A 0.176 M0.176 M solution of NaHA.NaHA.

pH=

[H2A]=[H2A]=

MM

[HA−]=[HA−]=

MM

[A2−]=[A2−]=

MM

A 0.176 M0.176 M solution of Na2A.Na2A.

pH=

[H2A]=[H2A]=

MM

[HA−]=[HA−]=

MM

[A2−]=[A2−]=

M

0 0
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Answer #1


- 1) 0.176m of HA H2A = H+HAⓇ 0.176 o o initial -x tx ax change (0.176-x) x equilibrium ka = [H* ][HA] [444] 4.15x15 =0.0083

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A diprotic acid, H2A,H2A, has acid dissociation constants of ?a1=4.15×10−4Ka1=4.15×10−4 and ?a2=3.73×10−12.Ka2=3.73×10−1...
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