Question

IH NMR 0.397 (ppm)

assign each signal from this spectrum in terms of integration and multiplicity and predict the structure of the product . the reaction acheived was the hetero Diels- Alder cycloaddition!
thanks

okay , actually N- phenylurazole was mixed with oxone(potassium peroxomonosulfate) and dichloromethane and potasium bromide!

more data required like what? be more specific please! in this reaction the mixture of N- phenylurazote , potassium peroxomonosulfate, potassium bromide and cycloheptatiene was used as reactants!
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Answer #1

Due to double bond in norbornene type structure in bicyclo compound the Hd protons in cyclopropane ring experiences electronic effects of alkene pi-orbitals electrons magnetic influence and Hd protons are under deshielded region, hence downfield shift compare to He protons.

IH NMR solvent CDC13 peak Ha / aromatic benzene ring protons appear as 5H, multiplet (ppm)

Hope this helped you!

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