Homework Answers
- carbon: The
carbon atom which is attached to halogen atom is alpha carbon.
- carbon: The
carbon atom which is attached to alpha carbon is called beta
carbon.
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label the alpha carbon and beta carbons in each of the
following compounds.
naming alkenes, E/Z...
1. Label the a carbon and B-carbons in each of the following compounds. *** 2. Determine the (E) and (Z) configurat...
1. Label the a carbon and B-carbons in each of the following compounds. *** 2. Determine the (E) and (Z) configuration and give the IUPAC name for the following alkenes.
1. Label the a carbon and ß-carbons in each of the following compounds, 2. Determine the...
1. Label the a carbon and ß-carbons in each of the following compounds, 2. Determine the (E) and (Z) configuration and give the IUPAC name for the following alkenes.
Chapter 11: 1. What is a prime rule in naming alkenes? a. Find the longest carbon...
Chapter 11: 1. What is a prime rule in naming alkenes? a. Find the longest carbon chain. b.Find the longest carbon chain containing the alkene. c. Find whether the alkene has a cis- or trans- configuration. d.Find how far the alkene functionality is from either end. 2. What is the IUPAC name of the following alkene? a. cis-5-methyl-2-heptene b. trans-2-ethyl-4-hexene c. trans-5-methyl-2-heptene d. trans-3-methyl-5-heptene 3. What is the hybridization, geometry, and bond angle of the carbon marked by an asterisk?...
a. First, circle the leaving group and label the alpha carbon as a. b. Then, label...
a. First, circle the leaving group and label the alpha carbon as a. b. Then, label the adjacent sp3 beta carbons as B. c. Finally, draw in the H's that can get eliminated along with the leaving group in each of these compounds. The first compound has been completed for you. HH می ) و CH3 2. Now, let's perform the elimination to make the Zaitsev (most substituted) product. Draw in the H from before and the curved arrows to...
Determine the (E) and (Z) configuration and give the IUPAC name for the following alkenes. Verify...
Determine the (E) and (Z) configuration and give the IUPAC
name for the following alkenes.
Verify answers if correct.
2. Determine the (E) and (Z) configuration and give the IUPAC name for the following alkenes. trans-but 2-ene cis-but-2-ene (2)-3-bromo-one (E)-but-2-ene (2)-but-2-ene. (E)-1-bromo-2- methyl-1- cyclohexene (E)-3-jodo-4-methyl- 3-hexene (2)-3,4-dimethyl-2-hexene
need help with 14-21 Stereochemistry of the Su2 reaction In the Sn2 reaction the tetrahedral carbon...
need help with 14-21
Stereochemistry of the Su2 reaction In the Sn2 reaction the tetrahedral carbon center is inverted. We describe the mechanism as nudeophilic (Nuc) back side attack; the leaving group (LG) is leav ing from the front side. Generally, the LG and the Nucare electron rich so it would be unfavorable for them to react from the same side (charge repuls ion). The geometry of the carbon at the transition state is trigonal planar. 14) Label the 2-bromobuta...
2. (1.5 pts) Label the following reagents as Good or Poor Nucleophiles AND as Strong or Weak Base...
2. (1.5 pts) Label the following reagents as Good or Poor Nucleophiles AND as Strong or Weak Bases. OK Na SH 3. (1.5 pt) Predict the productts) of the following reactions, if there are multiple products indicate which, if any, is the major product. Be sure to clearly mark the stereochemistry of chiral carbon atoms and draw multiple products if there is more than one stereoisomer that forms. HCI MeOH H2SO H2 Pd/BaSO4 quinoline 4. (3 pt) For the following...
8) Predict the product(s) of the following E2 reaction. Be sure to include solid wedges and...
8) Predict the product(s) of the following E2 reaction. Be sure to include solid wedges and dashed es on your product(s). Use conformational structures (the templates below) to show the mechanism and explain your reasoning Br CHCH ONa CH CH2OH, 70 °C Explanation(s): 9) Consider the E1 reaction of (3S)-3-bromo-2,3-dimethylpentane to form alkenes a) Draw the structure of the haloalkane (be sure to include stereochemistry). Clearly label any chiral carbon atoms with an asterisk ). b) Draw the structures of...
NAMING ALKENES 4.37 Give IUPAC names for the following compounds AND ALKYNES lal H20% HzCECH le)...
NAMING ALKENES 4.37 Give IUPAC names for the following compounds AND ALKYNES lal H20% HzCECH le) 4.28 Draw structures corresponding to the following IUPAC names 3-Ethylhept-1-yne (b) 3,5-Dimethylhex-4-en-1-yne (c) Hepta-1,5-diyne (d) 1-Methyleyclopenta-1,3-diene 4.29 The following two hydrocarbons have been isolated from plants in sunflower family. Name them according to lUPAC rules. (a) CH3CH-CHC-CC-CCH-CHCH-CHCH=CH2 (all trans) Draw and name all the possible pentyne isomers, CsHs the six are conjugated dienes? 4.30 4.31 Draw and name the six possible diene isomers of...
Determine the stereoconfiguration (E or Z) for each double bond in the following alkenes, as applicable....
Determine the stereoconfiguration (E or Z) for each double bond
in the following alkenes, as applicable.
Determine the stereoconfiguration (E or Z) for each double bond in the following alkenes, as applicable b. d. a. Br C. он CI H-N HO Br
1. Label the a carbon and B-carbons in each of the following compounds. *** 2. Determine the (E) and (Z) configuration and give the IUPAC name for the following alkenes.
1. Label the a carbon and ß-carbons in each of the following compounds, 2. Determine the (E) and (Z) configuration and give the IUPAC name for the following alkenes.
a. First, circle the leaving group and label the alpha carbon as a. b. Then, label the adjacent sp3 beta carbons as B. c. Finally, draw in the H's that can get eliminated along with the leaving group in each of these compounds. The first compound has been completed for you. HH می ) و CH3 2. Now, let's perform the elimination to make the Zaitsev (most substituted) product. Draw in the H from before and the curved arrows to...
Determine the (E) and (Z) configuration and give the IUPAC
name for the following alkenes.
Verify answers if correct.
2. Determine the (E) and (Z) configuration and give the IUPAC name for the following alkenes. trans-but 2-ene cis-but-2-ene (2)-3-bromo-one (E)-but-2-ene (2)-but-2-ene. (E)-1-bromo-2- methyl-1- cyclohexene (E)-3-jodo-4-methyl- 3-hexene (2)-3,4-dimethyl-2-hexene
need help with 14-21
Stereochemistry of the Su2 reaction In the Sn2 reaction the tetrahedral carbon center is inverted. We describe the mechanism as nudeophilic (Nuc) back side attack; the leaving group (LG) is leav ing from the front side. Generally, the LG and the Nucare electron rich so it would be unfavorable for them to react from the same side (charge repuls ion). The geometry of the carbon at the transition state is trigonal planar. 14) Label the 2-bromobuta...
2. (1.5 pts) Label the following reagents as Good or Poor Nucleophiles AND as Strong or Weak Bases. OK Na SH 3. (1.5 pt) Predict the productts) of the following reactions, if there are multiple products indicate which, if any, is the major product. Be sure to clearly mark the stereochemistry of chiral carbon atoms and draw multiple products if there is more than one stereoisomer that forms. HCI MeOH H2SO H2 Pd/BaSO4 quinoline 4. (3 pt) For the following...
8) Predict the product(s) of the following E2 reaction. Be sure to include solid wedges and dashed es on your product(s). Use conformational structures (the templates below) to show the mechanism and explain your reasoning Br CHCH ONa CH CH2OH, 70 °C Explanation(s): 9) Consider the E1 reaction of (3S)-3-bromo-2,3-dimethylpentane to form alkenes a) Draw the structure of the haloalkane (be sure to include stereochemistry). Clearly label any chiral carbon atoms with an asterisk ). b) Draw the structures of...
NAMING ALKENES 4.37 Give IUPAC names for the following compounds AND ALKYNES lal H20% HzCECH le) 4.28 Draw structures corresponding to the following IUPAC names 3-Ethylhept-1-yne (b) 3,5-Dimethylhex-4-en-1-yne (c) Hepta-1,5-diyne (d) 1-Methyleyclopenta-1,3-diene 4.29 The following two hydrocarbons have been isolated from plants in sunflower family. Name them according to lUPAC rules. (a) CH3CH-CHC-CC-CCH-CHCH-CHCH=CH2 (all trans) Draw and name all the possible pentyne isomers, CsHs the six are conjugated dienes? 4.30 4.31 Draw and name the six possible diene isomers of...
Determine the stereoconfiguration (E or Z) for each double bond
in the following alkenes, as applicable.
Determine the stereoconfiguration (E or Z) for each double bond in the following alkenes, as applicable b. d. a. Br C. он CI H-N HO Br
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