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13. For each of the following reactions show the reactive electrophile in the EAS reaction and...
9) Identify the electrophile in the sulfonation reaction of benzene. 2 Pt A. SO2 B. H2SO4...
9) Identify the electrophile in the sulfonation reaction of benzene. 2 Pt A. SO2 B. H2SO4 C. Sos* D. H2SO3 E. SO3 10) Write the mechanism for the following EAS reaction? 4 Pt CI. AICI 11) Predict the all possible products for the following reactions and circle the major product among them? 8 Pt olub HNO3. H,SO A) Yo Cl2, AICI: B) CH,CI, AICI: Сн, HNO3, H2SO4 D) OH
answer any that you can please B. Effect of substituents on EAS B1. Rank each of...
answer any that you can please
B. Effect of substituents on EAS B1. Rank each of the following sets from the most reactive (+1) to the least reactive (4) act more DANHAS CH WA B2. Predict the major product for the following reactions. If there is no reaction, write 'R' NO, C AICI: nog do m HOS нoss B Bra FeBig CHCI La AICI Falkijan we do 0, WALD 0.0 NO, HNO3 ON ON Brz FeBig OH H,SO C. Synthesis...
3. The electrophilic aromatic substitution (EAS) reaction is a great way to prepare substitute Provide the...
3. The electrophilic aromatic substitution (EAS) reaction is a great way to prepare substitute Provide the expected major product for each of the following EAS reactions. (12 pts) SO3H HNO3 H2SO4 CH2CH3 CI AICI en Enhen II Ph-C-NHÓh Br2 CH3 -CH₃ CH3 FeBr3
Draw the mechanism of the following reaction. Be sure to show all curved arrows and formal...
Draw the mechanism of the following reaction. Be sure to show all curved arrows and formal charges. (Show the formation of the electrophile and all resonance structures of the sigma complex). o to AICI: Does the substituent on the following benzene activate or deactivate the ring for EAS reactions? Explain your answer this should include drawing any relevant resonance structures!) NH Predict the major product of the following reaction. Explain the directing effects of the -OH group (this should include...
10) Write the mechanism for the following EAS reaction? 4P CL), AICI, 11) Predict the all...
10) Write the mechanism for the following EAS reaction? 4P CL), AICI, 11) Predict the all possible products for the following reactions and circle the major product among them? 8 Pt A) -CH2 HNO3, H,SO CI, AICI, B) C) CH,CI, AICI: сна HNO.H.SO. D) OH
organic chemistry revision problems. stuck on this page. 9. Which of the following compounds are aromatic?...
organic chemistry revision problems. stuck on this
page.
9. Which of the following compounds are aromatic? For those that are not provide a reason 10. Consider the following alkyl chlorides. Which would you expect to undergo an Syl substitution most readily? Justify your answer 11. Which of the following would you expect to be most acidic? Justify your answer. 12. Which of the following would you expect to be the stronger base? Justify your answer. 13. For each of the...
please help in all sections asap!! Which of the following reactions would produce isopropylbenzene as the...
please help in all sections asap!!
Which of the following reactions would produce isopropylbenzene as the major product? ОН AICI: H2SO4 H2SO4 AICI3 IV I all of these Predict the product for the following reaction fuming H2SO4 SO3H Predict the structure of the major product for the following reaction Which of the following compounds will not undergo nucleophilic aromatic substitution? 1-chloro-2,4-dinitrobenzene 1-bromo-4-nitrobenzene O-chloronitrobenzene m-chloronitrobenzene p-chloronitrobenzene Choose the correct sequence of reagents for the following transformation. 2) 3 . NH2 2)...
31. Which is the major product from the following consecutive reactions? CH2 HNO3 H2SO4 Br2 FeBrz...
31. Which is the major product from the following consecutive reactions? CH2 HNO3 H2SO4 Br2 FeBrz Br. C CH -NO2 -NO2 Br CH a) b) II c) III d) IV 32. Which is the best reaction sequence for preparing the following compound from benzene? (HINT: consider only the reaction product from electrophilic addition in the ortho position) OOH NO2 AICI; CH3CI K2Cr20 H2SO4 HNO3 H2SO4 HNO3 H2SO4 AICI; CH3CI K2Cr207 H2SO4 AICI: HNO3 CHCI H2SO4 AICI: K2Cr2O7 HNO3 H2SO4 H2SO4...
first let's see if the measuring. whst is the angle of tweetin Predict the products for...
first let's see if the measuring. whst is the angle of
tweetin
Predict the products for each of the following reactions
18.64 Predict the product(s) for each of the following reactions: 0 Cl2 AICI (a) HNO3 H2SO4 OCH 6) Fuming H2SO4 HNO3 H2SO4 5) Br NO2 8.65 When 2,4-dibromo-3-methyltoluene is treated with the presence of iron (Fe), a compound with the molecul H,Bra is obtained. Identify the structure of this product.
For each reaction predict the product. If isomers are possible only show the major product. H3C...
For
each reaction predict the product. If isomers are possible only
show the major product.
H3C Br SO3 H2SO4 ("fuming') AICI HNO3 a) c) H3C H2SO4 Cl d) CH3 (internal F-C AICl3 alkylation) H3C
9) Identify the electrophile in the sulfonation reaction of benzene. 2 Pt A. SO2 B. H2SO4 C. Sos* D. H2SO3 E. SO3 10) Write the mechanism for the following EAS reaction? 4 Pt CI. AICI 11) Predict the all possible products for the following reactions and circle the major product among them? 8 Pt olub HNO3. H,SO A) Yo Cl2, AICI: B) CH,CI, AICI: Сн, HNO3, H2SO4 D) OH
answer any that you can please
B. Effect of substituents on EAS B1. Rank each of the following sets from the most reactive (+1) to the least reactive (4) act more DANHAS CH WA B2. Predict the major product for the following reactions. If there is no reaction, write 'R' NO, C AICI: nog do m HOS нoss B Bra FeBig CHCI La AICI Falkijan we do 0, WALD 0.0 NO, HNO3 ON ON Brz FeBig OH H,SO C. Synthesis...
3. The electrophilic aromatic substitution (EAS) reaction is a great way to prepare substitute Provide the expected major product for each of the following EAS reactions. (12 pts) SO3H HNO3 H2SO4 CH2CH3 CI AICI en Enhen II Ph-C-NHÓh Br2 CH3 -CH₃ CH3 FeBr3
Draw the mechanism of the following reaction. Be sure to show all curved arrows and formal charges. (Show the formation of the electrophile and all resonance structures of the sigma complex). o to AICI: Does the substituent on the following benzene activate or deactivate the ring for EAS reactions? Explain your answer this should include drawing any relevant resonance structures!) NH Predict the major product of the following reaction. Explain the directing effects of the -OH group (this should include...
10) Write the mechanism for the following EAS reaction? 4P CL), AICI, 11) Predict the all possible products for the following reactions and circle the major product among them? 8 Pt A) -CH2 HNO3, H,SO CI, AICI, B) C) CH,CI, AICI: сна HNO.H.SO. D) OH
organic chemistry revision problems. stuck on this
page.
9. Which of the following compounds are aromatic? For those that are not provide a reason 10. Consider the following alkyl chlorides. Which would you expect to undergo an Syl substitution most readily? Justify your answer 11. Which of the following would you expect to be most acidic? Justify your answer. 12. Which of the following would you expect to be the stronger base? Justify your answer. 13. For each of the...
please help in all sections asap!!
Which of the following reactions would produce isopropylbenzene as the major product? ОН AICI: H2SO4 H2SO4 AICI3 IV I all of these Predict the product for the following reaction fuming H2SO4 SO3H Predict the structure of the major product for the following reaction Which of the following compounds will not undergo nucleophilic aromatic substitution? 1-chloro-2,4-dinitrobenzene 1-bromo-4-nitrobenzene O-chloronitrobenzene m-chloronitrobenzene p-chloronitrobenzene Choose the correct sequence of reagents for the following transformation. 2) 3 . NH2 2)...
31. Which is the major product from the following consecutive reactions? CH2 HNO3 H2SO4 Br2 FeBrz Br. C CH -NO2 -NO2 Br CH a) b) II c) III d) IV 32. Which is the best reaction sequence for preparing the following compound from benzene? (HINT: consider only the reaction product from electrophilic addition in the ortho position) OOH NO2 AICI; CH3CI K2Cr20 H2SO4 HNO3 H2SO4 HNO3 H2SO4 AICI; CH3CI K2Cr207 H2SO4 AICI: HNO3 CHCI H2SO4 AICI: K2Cr2O7 HNO3 H2SO4 H2SO4...
first let's see if the measuring. whst is the angle of
tweetin
Predict the products for each of the following reactions
18.64 Predict the product(s) for each of the following reactions: 0 Cl2 AICI (a) HNO3 H2SO4 OCH 6) Fuming H2SO4 HNO3 H2SO4 5) Br NO2 8.65 When 2,4-dibromo-3-methyltoluene is treated with the presence of iron (Fe), a compound with the molecul H,Bra is obtained. Identify the structure of this product.
For
each reaction predict the product. If isomers are possible only
show the major product.
H3C Br SO3 H2SO4 ("fuming') AICI HNO3 a) c) H3C H2SO4 Cl d) CH3 (internal F-C AICl3 alkylation) H3C
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