![[20 pts] It can be shown that the multiplicity of the macrostate with r quanta of energy in an Einstein solid with n oscillators is (a) For an Einstein solid with each of the following values of n and r, list all of the possible microstates, count them, and verify formula E. 1 above. (a-1) n 3,r 5 (a-2) n 3,r-7 (a-3) n 4, r 4 (a-4) n 1,r anything (a-5) n anything,1 (b) Compute the multiplicity of an Einstein solid with 50 oscillators and 50 units of energy. (Do not attempt to list all microstates)](http://img.homeworklib.com/questions/c9bd16c0-6f16-11ea-9bdf-41d3d737ee63.png?x-oss-process=image/resize,w_560)
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[20 pts] It can be shown that the multiplicity of the macrostate with r quanta of...
T2B.2 Calculate the multiplicity of an Einstein solid with N = 1 and U = 5€...
T2B.2 Calculate the multiplicity of an Einstein solid with N = 1 and U = 5€ by directly listing and counting the microstates. Check your work by using equation T2.7. macrostate of an Einstein solid. R2(0,N) - Vece +3N-1)! (9)! (3N-1)! Write down all of the microstates for a hypothetian HALI 3 Is the
Calcium carbonate can decompose into calcium oxide and carbon dioxide gas with the (c) reaction: CaCO3...
Calcium carbonate can decompose into calcium oxide and carbon dioxide gas with the (c) reaction: CaCO3 СаО + СО2 The change in enthalpy for this reaction is AH = +178 kJ/mol and the change in entropy is AS = +0.16 kJ/(K. mol) (i) Describe the concept of the Gibbs energy and how it is related to the enthalpy and entropy (ii Hence calculate the minimum temperature for the decomposition of calcium carbonate to proceed spontaneously An Einstein solid consists of...
A1.2. In the lectures we have seen that the multiplicity of an Einstein solid with q...
A1.2. In the lectures we have seen that the multiplicity of an Einstein solid with q energy units and N oscillators is given by 0(N, q) = (q + N-1 (a) Show that, in the "low-temperature limit, N, the multiplicity becomes (b) Using the above formula for the multiplicity, compute the entropy of an Einstein solid for q《N,
Use a computer to reproduce the table and graph in Figure 2.4: two Einstein solids, each...
Use a computer to reproduce the table and graph in Figure 2.4: two Einstein solids, each containing three harmonic oscillators, with a total of six units of energy. Then modify the table and graph to show the case where one Einstein solid contains six harmonic oscillators and the other contains four harmonic oscillators (with the total number of energy units still equal to six) Assuming that all microstates are equally likely, what is the most probable macrostate, and what is...
Consider two Einstein solids A and B that can exchange energy (but not oscillators/particles) wit...
Using matlab, evaluate the following system:Consider two Einstein solids \(A\) and \(B\) that can exchange energy (but not oscillators/particles) with one another but the combined composite system is isolated from the surroundings. Suppose systems \(A\) and \(B\) have \(N_{A}\) and \(N_{B}\) oscillators, and \(q_{A}\) and \(q_{B}\) units of energy respectively. The total number of microstates for this macrostate for the macrostate \(N_{A}, N_{B}, q, q_{A}\) is given by$$ \Omega\left(N_{A}, N_{B}, q, q_{A}\right)=\Omega\left(N_{A}, q_{A}\right) \Omega\left(N_{B}, q_{B}\right) $$where$$ \Omega\left(N_{i}, q_{i}\right)=\frac{\left(q_{i}+N_{i}-1\right) !}{q_{i} !\left(N_{i}-1\right)...
(TOTAL MARKS: 25) QUESTION 4 (15 marks] Q4(a) Assume 4 fermionic particles (N=N,+NA+N, -4) populate 3...
(TOTAL MARKS: 25) QUESTION 4 (15 marks] Q4(a) Assume 4 fermionic particles (N=N,+NA+N, -4) populate 3 degenerate energy levels E <E, <E, with 8, = 4,8, = 3.8, = 2 and N, 2N, 2N, What are the possible macrostates of this system ? (3 marks) (l) For each macrostate found at (), count the number of possible microstates using sketches showing the quantum state occupation number in each energy level. (7 marks) (H) Retrieve your results at (ii) if the...
2. Microcanonical ensemble: One-dimensional chain. (24 pts.) Consider a one-dimensional chain consisting of N segments as illus- trated in Figure 1. Let the length of each segment be a when the...
2. Microcanonical ensemble: One-dimensional chain. (24 pts.) Consider a one-dimensional chain consisting of N segments as illus- trated in Figure 1. Let the length of each segment be a when the long dimension of the segment is parallel to the chain and 0 when the long dimension is normal to the chain direction. Each segment has just two non-degenerate states: long dimension parallel to the chain or perpen- dicular to the chain. Now consider a macrostate of the chain in...
TSD.1 In this problem, we will see (in outline) how we can calculate the multiplicity of a monatomic ideal gas This derivation involves concepts presented in chapter 17 Note that the task is to...
TSD.1 In this problem, we will see (in outline) how we can calculate the multiplicity of a monatomic ideal gas This derivation involves concepts presented in chapter 17 Note that the task is to count the number of microstates that are compatible with a given gas macrostate, which we describe by specifying the gas's total energy u (within a tiny range of width dlu), the gas's volume V and the num- ber of molecules N in the gas. We will...
Problem 5. (20 pts) Let r,n N be two natural numbers with r < n. An...
Problem 5. (20 pts) Let r,n N be two natural numbers with r < n. An r x n matrix M consisting of r rows and n columns is said to be a Latin rectangle of size (r, n), if all the entries My belong to the set {1,2,3,..., n), for 1Si<T, 1Sj<T, and the same number does not appear twice in any row or in any column. By defini- tion, a Latin square is a Latin rectangle of size...
T2B.2 Calculate the multiplicity of an Einstein solid with N = 1 and U = 5€ by directly listing and counting the microstates. Check your work by using equation T2.7. macrostate of an Einstein solid. R2(0,N) - Vece +3N-1)! (9)! (3N-1)! Write down all of the microstates for a hypothetian HALI 3 Is the
Calcium carbonate can decompose into calcium oxide and carbon dioxide gas with the (c) reaction: CaCO3 СаО + СО2 The change in enthalpy for this reaction is AH = +178 kJ/mol and the change in entropy is AS = +0.16 kJ/(K. mol) (i) Describe the concept of the Gibbs energy and how it is related to the enthalpy and entropy (ii Hence calculate the minimum temperature for the decomposition of calcium carbonate to proceed spontaneously An Einstein solid consists of...
A1.2. In the lectures we have seen that the multiplicity of an Einstein solid with q energy units and N oscillators is given by 0(N, q) = (q + N-1 (a) Show that, in the "low-temperature limit, N, the multiplicity becomes (b) Using the above formula for the multiplicity, compute the entropy of an Einstein solid for q《N,
Use a computer to reproduce the table and graph in Figure 2.4: two Einstein solids, each containing three harmonic oscillators, with a total of six units of energy. Then modify the table and graph to show the case where one Einstein solid contains six harmonic oscillators and the other contains four harmonic oscillators (with the total number of energy units still equal to six) Assuming that all microstates are equally likely, what is the most probable macrostate, and what is...
Using matlab, evaluate the following system:Consider two Einstein solids \(A\) and \(B\) that can exchange energy (but not oscillators/particles) with one another but the combined composite system is isolated from the surroundings. Suppose systems \(A\) and \(B\) have \(N_{A}\) and \(N_{B}\) oscillators, and \(q_{A}\) and \(q_{B}\) units of energy respectively. The total number of microstates for this macrostate for the macrostate \(N_{A}, N_{B}, q, q_{A}\) is given by$$ \Omega\left(N_{A}, N_{B}, q, q_{A}\right)=\Omega\left(N_{A}, q_{A}\right) \Omega\left(N_{B}, q_{B}\right) $$where$$ \Omega\left(N_{i}, q_{i}\right)=\frac{\left(q_{i}+N_{i}-1\right) !}{q_{i} !\left(N_{i}-1\right)...
(TOTAL MARKS: 25) QUESTION 4 (15 marks] Q4(a) Assume 4 fermionic particles (N=N,+NA+N, -4) populate 3 degenerate energy levels E <E, <E, with 8, = 4,8, = 3.8, = 2 and N, 2N, 2N, What are the possible macrostates of this system ? (3 marks) (l) For each macrostate found at (), count the number of possible microstates using sketches showing the quantum state occupation number in each energy level. (7 marks) (H) Retrieve your results at (ii) if the...
2. Microcanonical ensemble: One-dimensional chain. (24 pts.) Consider a one-dimensional chain consisting of N segments as illus- trated in Figure 1. Let the length of each segment be a when the long dimension of the segment is parallel to the chain and 0 when the long dimension is normal to the chain direction. Each segment has just two non-degenerate states: long dimension parallel to the chain or perpen- dicular to the chain. Now consider a macrostate of the chain in...
TSD.1 In this problem, we will see (in outline) how we can calculate the multiplicity of a monatomic ideal gas This derivation involves concepts presented in chapter 17 Note that the task is to count the number of microstates that are compatible with a given gas macrostate, which we describe by specifying the gas's total energy u (within a tiny range of width dlu), the gas's volume V and the num- ber of molecules N in the gas. We will...
Problem 5. (20 pts) Let r,n N be two natural numbers with r < n. An r x n matrix M consisting of r rows and n columns is said to be a Latin rectangle of size (r, n), if all the entries My belong to the set {1,2,3,..., n), for 1Si<T, 1Sj<T, and the same number does not appear twice in any row or in any column. By defini- tion, a Latin square is a Latin rectangle of size...
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