this need concept of esterification and polymerization.
7. Draw the structure of the missing major organic product(s) for each of the following reactions....
Draw the structure of the major principal organic product in each of the following reactions. Include correct relative stereochemistry. You don’t need to draw both enantiomers. NaOH BH3 THF H202, H20 HgSO4 H2SO4 H20 heat 1 mol Br2 LiBr HOAc
17. Draw the structure of the major organic product(s) for each of the following reactions. Indicate stereochemistry when appropriate. C(CH3)3 NASH Br (S)-2-bromononane - acetonitrile KOH CH,OH NaCN HE Br Acetonitrile C2H5 H, Br NaOH Acetone excess HBr ROOR HC1 + Br Na o DMSO
Draw the major organic product(s) for the following reactions; (*) must include correct stereochemistry; double-dagger (‡) must show two products. [H"]/HEAT H20 (excess) 1) 1 M BH, in THE +22°C/1h 2) 3 M NaOH(aq.)/30% H,02 [Na+/-OOH] 730-50 c/1h = -18.6 (73% yield) (1) Pupinene BH, in THF O'C/2h (m)" (3.0 equiv.) BH, in THE OC/2h (n) (3.0 equiv.) 1) BH, in THE O'C/2h 2) O C/3M NaOH(aq.) 30, H,0 /1h [Na+/-OOH] H.C. Brown. JACS, 1959, B1, 247, (05 fol. yield...
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
Draw the structure of the major organic product of these reactions. Do not write mechanisms. Но. (h) OH NADH two organic products; write both NHANH2 KOH (i) H H2O heat (1) H H+ CH3 () H.C C12H160 (2) PhCH,CH,Br (3) H307
For each of the following reactions fill in the box to give the missing product(s). If no reaction occurs, write N.R. If the reaction produces a mixture of products, such as stereoisomers or constitutional isomers, give the structure of each product. If a major product arises, label it as so. Be sure to show stereochemistry when needed. 1. NaOH ОН 2. 1-iodopropane THF OH 1. NaH THE 2. 1-bromobutane THF 1. methanol Hg(OAc)2 H2SO4 2. NaBH4 THE H2SO4 YOH 140...
Question 3 (32 pts.) For each of the following reactions: a) Provide the missing major organic product or reagents/conditions b) Pay attention to stereochemistry and identify any racemic mixtures using the (+) symbol. NH2 CO/HCI a) AICI: 1. KMnO/OH/boil b) 2. H307 NO2 1. H/Pd/C c) 2. Bry/FeBrz :0: d) SOZ/H2SO4
Draw the major organic product for each of the following reactions. The first and third product are correct, but the second one is not. I am getting a hint for the second one that: "a rearrangement will occur before water additions." Thanks. Draw the major organic product for each of the following reactions. 1. BH3, THF 1. Hg (OAC)2, H20 2. NaOH, H20, H202 H2SO4 2. NaBH4 H20
3. Give the major organic product(s) for each of the following reactions or sequences of reactions. Show all relevant stereochemistry. KMnO4 1. NaCN andere 2. H20, heat 1. LiAIH THE (c) Cou 2. H20 1. Mg, ether (d) -CHLB 2. CO2 3.H30 le) OH ether
Complete the following reactions. Provide the missing reactant(s) OR major organic product(s). Show correct regio- and stereochemistry for products you draw, where applicable Сн,, Zn(Cu) 1. OSONMO, pyridine 2. NaHSO, H,0 H2O* g. V 1. BH-THF 2. 1,0,, NaOH, HO - Y 1. MCPBA 2.4,00 DCM H,802, H2O heat 1., 2. Zn, AcOH