Draw the major organic product(s) for the following reactions; (*) must include correct stereochemistry; double-dagger (‡)...
draw the major product TH"]/HEAT H0 (excess) 1 MBH, in THF 22 °C/1h 2) 3M NaOH(aq)/30% H2O Na+/-OOH/50-50 c/1h =-18.6 (73% yield) ()* -pinene BH, in THE o "C/2h (m)" (2.0 equiv) (n) (3.0 equiv) 1) BH, in THF O "C/2h 2) 0 °C/3M NaOH(aq.) 30% H,0/1h [Na/ "OOH H.C. Brown. JACS, 1959. 81, 247. (85 yield) fol 1) BH, 2) NaOH HẠO H₂O₂ (p) 1) BH, THF 2) NaOH / HOA PHOO/NA" 1) BH, THE 2) NaOH/H2O THOON 1)...
draw the major product include correct stereochemostry 1) BH, in THE 0 °C/2h 2) 0 °C/3M NaOH(aq.) 30% H2O2/1h [Na/OOH) H.C. Brown. JACS, 1959, 81, 247. (90 % yield) Br2 CH,Cl2 B12 CH,CI, CI,/CH,CI, Br2 CH,CI, Br2 (2). U Br2 CH,CI2 (aa)*
Draw the major organic product(s) for the following reactions; (*) must include correct stereochemistry; double-dagger (‡) must show two products. HBr (a)* HBr (b)+ (1.00 equiv.) HBr (c)* HCI (d) 48% wt. HBr A (e) 37% wt . HCl НЕАT (n* [H2SO]/H,O (g) [H2SOal/A CH,он (ехсess) (h) [H,SOl/H2O (1)* [H2SO/H2O Or
Draw the major organic product(s) for the following reactions; (*) must include correct stereochemistry; double-dagger (‡) must show two products. сь/н,о HOCIJ/15-20 c oS I 158 (70-73 % yield) (gg)" Cly/H2O (но-с (hh) Bry/MyO [но-ві] (i) Cly/ H,0 Br/-78 C in CH,Cl,/6 h (93% yield) (kk) Cl/H,0 Cl/H,0 (носу/о "с oS IV 157 (52-55 % yield) (mm)* mCРВА CH,Cl (nn)" mCРВА CH,Cl (oo) тCРВА CH,Cl (pp)* он - CoH MCPBA CI in Et,O/0-4 "C 10 d (60% yield; 75:25) /.(bb)...
draw the major product 1) BH, in THE - 06/26 2) "C/SM NaOH(aq) 30% H,O,/1h [Na/OOH H.C. Brown. JACS, 1959, 81, 247, (05 yield) (ul CH.CH CH,CI CH.CH CH.CH In CHCI,/ CHCh 130 min OS V 467(80-86% yield) HO-B Bry/H, DMSO THO-Br B /H, DMSO Boy (eld" Bry/CH, OH - L Сн,он Cl/H, HỆ CHI 15 20 C. OS I 158 70-73 yield) CI/H, но с Bry/H,0 THOB] CI/H,O Bry/ -78 °C in CH, CI, 76h (934 yield) (kk) Cl/H20...
Draw the major organic product(s) for the following reactions; (*) must include correct stereochemistry; double-dagger (‡) must show two products. 2019 MCPHS University 1-78 C 2) CH,SCH (ss)+ 1-78 °C 1) (tt) 2) CH,SCH Фе CH,SCH 1-78 °C 1) 2) (uu) # 1-78 "C 2) CH,SCH (vv) 1-78 C 1) сH,SCH, 2) (ww) 1-78 "C 1) in CH Cl 2) CH,SCH (x) Hy (pressure) Pd(C) in CH,OH (уу)" Hy (pressure) Pd(C) in CH,OH (zz)* н PHC) (аaа) Hа Pd C)...
Complete the following reactions. Provide the missing reactant(s) OR major organic product(s). Show correct regio- and stereochemistry for products you draw, where applicable Сн,, Zn(Cu) 1. OSONMO, pyridine 2. NaHSO, H,0 H2O* g. V 1. BH-THF 2. 1,0,, NaOH, HO - Y 1. MCPBA 2.4,00 DCM H,802, H2O heat 1., 2. Zn, AcOH
2. (14 pts) Draw the major product for reactions H through M in the spaces provided. B12 NaOH BY2M 1. NaNH (3 equiv) : 1. Hg(OA)2, H2O. BH Cou' n 2. H2O 2. NaBHA J Acete K 105. L HOM HO Acetic acid M
1. (24) Write structural formulas for the major organic product(s) for the following reactions. Be sure to indicate the stereochemistry when relevant. HC CH=CH2 H CH,OH CH2OH 1. Na, liq. NH (b) CH,CH.C=CCH CH3 HẠCH, B, P NH, 2.D2, Pt Cl2 HC CCH2CH=CH CH,CH HCC CH,Cl2 1. BH/THF (d) CH,CH,C=CH2 2. H,02, HO", H0 CH -0.47- CH; Br2 excess NaCl 1. 03,-78°C 2. (CH3)2S woboto (h) + Br₂ -
Predict the major product(s) of the following reactions. Show stereochemistry where appropriate. 3 CO3H i) OsO4 H ii) NaHSO3, H2O CHC13, KOH any cha, kot i) BH3, THF CECH 11) H2O2, NaOH Li NH (liquid) cm X Ft, H/HO (vii) Two Markovnikov products Draw the structure of alkene for each of the following reactions. OH i) BH, THF 11) H202, NaOH 1) Hg(OAc)2, H20 ii) NaBH4 1) 03 ii) Zn/H Styrene undergoes propagation to give polystyrene. Showing electron-flow using half-headed...