Homework Answers
![1) BH, in THE 0 °C/2h 2) 0°C/3M NaOH(aq.) 30% H202/1h [Na+/-OOH] H. C. Brown. JACS, 1959, 81, 247. (90% yield) 0.00 HO НО (u](http://img.homeworklib.com/questions/aac9aec0-70d8-11ea-ab21-1350b661a072.png?x-oss-process=image/resize,w_560)
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draw the major product include correct stereochemostry
1) BH, in THE 0 °C/2h 2) 0 °C/3M...
draw the major product TH"]/HEAT H0 (excess) 1 MBH, in THF 22 °C/1h 2) 3M NaOH(aq)/30%...
draw the major product
TH"]/HEAT H0 (excess) 1 MBH, in THF 22 °C/1h 2) 3M NaOH(aq)/30% H2O Na+/-OOH/50-50 c/1h =-18.6 (73% yield) ()* -pinene BH, in THE o "C/2h (m)" (2.0 equiv) (n) (3.0 equiv) 1) BH, in THF O "C/2h 2) 0 °C/3M NaOH(aq.) 30% H,0/1h [Na/ "OOH H.C. Brown. JACS, 1959. 81, 247. (85 yield) fol 1) BH, 2) NaOH HẠO H₂O₂ (p) 1) BH, THF 2) NaOH / HOA PHOO/NA" 1) BH, THE 2) NaOH/H2O THOON 1)...
Draw the major organic product(s) for the following reactions; (*) must include correct stereochemistry; double-dagger (‡)...
Draw the major organic product(s) for the following reactions;
(*) must include correct stereochemistry; double-dagger (‡) must
show
two products.
[H"]/HEAT H20 (excess) 1) 1 M BH, in THE +22°C/1h 2) 3 M NaOH(aq.)/30% H,02 [Na+/-OOH] 730-50 c/1h = -18.6 (73% yield) (1) Pupinene BH, in THF O'C/2h (m)" (3.0 equiv.) BH, in THE OC/2h (n) (3.0 equiv.) 1) BH, in THE O'C/2h 2) O C/3M NaOH(aq.) 30, H,0 /1h [Na+/-OOH] H.C. Brown. JACS, 1959, B1, 247, (05 fol. yield...
draw the major product 1) BH, in THE - 06/26 2) "C/SM NaOH(aq) 30% H,O,/1h [Na/OOH...
draw the major product
1) BH, in THE - 06/26 2) "C/SM NaOH(aq) 30% H,O,/1h [Na/OOH H.C. Brown. JACS, 1959, 81, 247, (05 yield) (ul CH.CH CH,CI CH.CH CH.CH In CHCI,/ CHCh 130 min OS V 467(80-86% yield) HO-B Bry/H, DMSO THO-Br B /H, DMSO Boy (eld" Bry/CH, OH - L Сн,он Cl/H, HỆ CHI 15 20 C. OS I 158 70-73 yield) CI/H, но с Bry/H,0 THOB] CI/H,O Bry/ -78 °C in CH, CI, 76h (934 yield) (kk) Cl/H20...
45. Provide the structure of the major organic product of the reaction be 1. BH, THE...
45. Provide the structure of the major organic product of the reaction be 1. BH, THE 2. H2O, HO HO 16. Which of the following alkenes will yield am temperature? mg alkenes will yield a meso dihalide when reacted with Br2/CCl4 at room E both Band D 17. Draw the major organic products) generated in the reaction below. Pay particular attention to regio- and stereochemical detail. CC CHCOH H₃CH₂C CH₂CH3 18. Which of the following steps would successfully complete the...
draw the major product of the following reactions. nos 1) R-BH 2) H.O., NaOH 3) NBS,...
draw the major product of the following reactions.
nos 1) R-BH 2) H.O., NaOH 3) NBS, heat (I eq) 1) KMnO4, heat 2) Na, NH3, CH OH 3) Br, light (I eq) 1) NBS, light 2) NEL 3) Br 4) NaNH (45) 5) HO
Draw the major product for the following reactions. -OH 2. Draw the major product for the following reactions. 1) T...
Draw the major product for the following reactions.
-OH 2. Draw the major product for the following reactions. 1) TSCI 2) NaOEt, Heat 3) O; 4) DMS 1) NBS, heat (I cq.) 2) NaNH, DMSO 3) KMnO4 (aq) NaOH, cold 4) NaOCI, acetic acid 1) O 2) H,0 3)NI, H, 150, 100 atm 1) RBH 2) H.O, NaOH 3) NBS, heat (I eq) 1) KMnO heat 2) Na, NH, CH OH 3) Bry, light (I eq) 1) NBS, light 2)...
What major Organic product is formed after the following sequence of reactions? 1) NaH, THF 2)...
What major Organic product is formed after the following sequence of reactions? 1) NaH, THF 2) Br Br B1 (C) (b) Br Bi a. a Considering both regiochemistry and stereochemistry, what is the major Organic product of the following reaction? о ні. CH-CH, НСІ Снон HC "CH; но CH, НО CH, HCO CH-CH; CH «CH-CH, OCH; CH CH3 ОН нс СІ H; Н;С (6) (c) H.CO CH, Kotic CH.CH НО CH; Но CH.CH Сн, НП). CH,CH; ОН нс Н.С осн;...
Starting Material Reagent Major Product? H2, Pd/C 1) 050 2) aq. KHSO3 1) CH3CO3H 2) NaOH/H20...
Starting Material Reagent Major Product? H2, Pd/C 1) 050 2) aq. KHSO3 1) CH3CO3H 2) NaOH/H20 Braz/H20 1) 0; 2) Zn/HOÁC Provide reagents and/or starting materials to accomplish the following transformations pH ن – EC–CH = ا سے ہی الا) CH3 0CH3 H.C ) م any alkene CH3 H3C- Hy, Pd/C CH3 optically active diterpene mixture of diastereomers 1) 0, 2) Zn/HOÁC нэс CH3 + 0 + 0 + H нас
draw the major product
TH"]/HEAT H0 (excess) 1 MBH, in THF 22 °C/1h 2) 3M NaOH(aq)/30% H2O Na+/-OOH/50-50 c/1h =-18.6 (73% yield) ()* -pinene BH, in THE o "C/2h (m)" (2.0 equiv) (n) (3.0 equiv) 1) BH, in THF O "C/2h 2) 0 °C/3M NaOH(aq.) 30% H,0/1h [Na/ "OOH H.C. Brown. JACS, 1959. 81, 247. (85 yield) fol 1) BH, 2) NaOH HẠO H₂O₂ (p) 1) BH, THF 2) NaOH / HOA PHOO/NA" 1) BH, THE 2) NaOH/H2O THOON 1)...
Draw the major organic product(s) for the following reactions;
(*) must include correct stereochemistry; double-dagger (‡) must
show
two products.
[H"]/HEAT H20 (excess) 1) 1 M BH, in THE +22°C/1h 2) 3 M NaOH(aq.)/30% H,02 [Na+/-OOH] 730-50 c/1h = -18.6 (73% yield) (1) Pupinene BH, in THF O'C/2h (m)" (3.0 equiv.) BH, in THE OC/2h (n) (3.0 equiv.) 1) BH, in THE O'C/2h 2) O C/3M NaOH(aq.) 30, H,0 /1h [Na+/-OOH] H.C. Brown. JACS, 1959, B1, 247, (05 fol. yield...
draw the major product
1) BH, in THE - 06/26 2) "C/SM NaOH(aq) 30% H,O,/1h [Na/OOH H.C. Brown. JACS, 1959, 81, 247, (05 yield) (ul CH.CH CH,CI CH.CH CH.CH In CHCI,/ CHCh 130 min OS V 467(80-86% yield) HO-B Bry/H, DMSO THO-Br B /H, DMSO Boy (eld" Bry/CH, OH - L Сн,он Cl/H, HỆ CHI 15 20 C. OS I 158 70-73 yield) CI/H, но с Bry/H,0 THOB] CI/H,O Bry/ -78 °C in CH, CI, 76h (934 yield) (kk) Cl/H20...
45. Provide the structure of the major organic product of the reaction be 1. BH, THE 2. H2O, HO HO 16. Which of the following alkenes will yield am temperature? mg alkenes will yield a meso dihalide when reacted with Br2/CCl4 at room E both Band D 17. Draw the major organic products) generated in the reaction below. Pay particular attention to regio- and stereochemical detail. CC CHCOH H₃CH₂C CH₂CH3 18. Which of the following steps would successfully complete the...
draw the major product of the following reactions.
nos 1) R-BH 2) H.O., NaOH 3) NBS, heat (I eq) 1) KMnO4, heat 2) Na, NH3, CH OH 3) Br, light (I eq) 1) NBS, light 2) NEL 3) Br 4) NaNH (45) 5) HO
Draw the major product for the following reactions.
-OH 2. Draw the major product for the following reactions. 1) TSCI 2) NaOEt, Heat 3) O; 4) DMS 1) NBS, heat (I cq.) 2) NaNH, DMSO 3) KMnO4 (aq) NaOH, cold 4) NaOCI, acetic acid 1) O 2) H,0 3)NI, H, 150, 100 atm 1) RBH 2) H.O, NaOH 3) NBS, heat (I eq) 1) KMnO heat 2) Na, NH, CH OH 3) Bry, light (I eq) 1) NBS, light 2)...
What major Organic product is formed after the following sequence of reactions? 1) NaH, THF 2) Br Br B1 (C) (b) Br Bi a. a Considering both regiochemistry and stereochemistry, what is the major Organic product of the following reaction? о ні. CH-CH, НСІ Снон HC "CH; но CH, НО CH, HCO CH-CH; CH «CH-CH, OCH; CH CH3 ОН нс СІ H; Н;С (6) (c) H.CO CH, Kotic CH.CH НО CH; Но CH.CH Сн, НП). CH,CH; ОН нс Н.С осн;...
Starting Material Reagent Major Product? H2, Pd/C 1) 050 2) aq. KHSO3 1) CH3CO3H 2) NaOH/H20 Braz/H20 1) 0; 2) Zn/HOÁC Provide reagents and/or starting materials to accomplish the following transformations pH ن – EC–CH = ا سے ہی الا) CH3 0CH3 H.C ) م any alkene CH3 H3C- Hy, Pd/C CH3 optically active diterpene mixture of diastereomers 1) 0, 2) Zn/HOÁC нэс CH3 + 0 + 0 + H нас
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