2. (14 pts) Draw the major product for reactions H through M in the spaces provided....
14. (10 pts) Draw the major product(s) for reactions through w in the spaces provided. OH POE, SNCNT 1.CH MgBrother U LIAH, ether, VCHI (excess 2 CH OH 2. HO NaOH,
Draw the major organic product(s) for the following reactions;
(*) must include correct stereochemistry; double-dagger (‡) must
show
two products.
[H"]/HEAT H20 (excess) 1) 1 M BH, in THE +22°C/1h 2) 3 M NaOH(aq.)/30% H,02 [Na+/-OOH] 730-50 c/1h = -18.6 (73% yield) (1) Pupinene BH, in THF O'C/2h (m)" (3.0 equiv.) BH, in THE OC/2h (n) (3.0 equiv.) 1) BH, in THE O'C/2h 2) O C/3M NaOH(aq.) 30, H,0 /1h [Na+/-OOH] H.C. Brown. JACS, 1959, B1, 247, (05 fol. yield...
draw the major product of the following reactions
2. Draw the major product for the following reactions. OH ) TSCH 2) NaOEt, Heat 3) og 4) DMS 1) NBS, heat (l eq.) 2) NaNH, DMSO 3) KMnO, (aq) NaOH, cold 4) NaOCI. acetic acid 1) O, 2) H.O 3)Ni, H, 150°. 100 atm
13. (8 pts) Draw the major product(s) for reactions through F in the spaces provided. 1. Nah 1 Nal NaBH D 2. CH,CH,Bro CH,CH,OH CHCE 2 CH,CH,Br
Draw the major product for the following reactions.
-OH 2. Draw the major product for the following reactions. 1) TSCI 2) NaOEt, Heat 3) O; 4) DMS 1) NBS, heat (I cq.) 2) NaNH, DMSO 3) KMnO4 (aq) NaOH, cold 4) NaOCI, acetic acid 1) O 2) H,0 3)NI, H, 150, 100 atm 1) RBH 2) H.O, NaOH 3) NBS, heat (I eq) 1) KMnO heat 2) Na, NH, CH OH 3) Bry, light (I eq) 1) NBS, light 2)...
12. Draw all major products for the following reactions. Indicate any region specificity Mark, Non Mark, syn or anti addition were necessary. (36 points) HgSO H SO. Na NH 1.2 HB 2. cther R BH THE NaOH, HOA Bry CCL OH NaOCI HOAC o E HBr ROOR hy NBS, hy 1. Hg(OAC), H,O/THF 2. NaBHA Br 1. NaNH Br 1. LAIH 2. H0
draw the major product
TH"]/HEAT H0 (excess) 1 MBH, in THF 22 °C/1h 2) 3M NaOH(aq)/30% H2O Na+/-OOH/50-50 c/1h =-18.6 (73% yield) ()* -pinene BH, in THE o "C/2h (m)" (2.0 equiv) (n) (3.0 equiv) 1) BH, in THF O "C/2h 2) 0 °C/3M NaOH(aq.) 30% H,0/1h [Na/ "OOH H.C. Brown. JACS, 1959. 81, 247. (85 yield) fol 1) BH, 2) NaOH HẠO H₂O₂ (p) 1) BH, THF 2) NaOH / HOA PHOO/NA" 1) BH, THE 2) NaOH/H2O THOON 1)...
draw the major product of the following reactions.
nos 1) R-BH 2) H.O., NaOH 3) NBS, heat (I eq) 1) KMnO4, heat 2) Na, NH3, CH OH 3) Br, light (I eq) 1) NBS, light 2) NEL 3) Br 4) NaNH (45) 5) HO
2. Draw the major product for the following reactions.
6.Draw the final product for the following reactions
2. Draw the major product for the following reactions. 1) TCI 2) NaOEL, Heat 3) 0 4) DMS 1) NBS, heat (1 eq.) 2) NaNH, DMS0 3) KMnO4 (aq) NaOH, cold 4) NaCl acetic acid 1) , 2) H.O 3)Ni, 1, 150, 100 atm 1) R RH 2) H.O., NaOH 3) NBS, heat (I eq) 1) KMnO heat 2) Na, NH, CH,OH 3)...
11. Write out the structural formula of the product for the following reactions. (20 pts) (a) H2O H (b) 1) BH; 2) H2O2, NaOH (c) Br2 (2 moles) (d) H2 Lindlar catalyst (e) HO H, Hg?