14. (10 pts) Draw the major product(s) for reactions through w in the spaces provided. OH...
13. (8 pts) Draw the major product(s) for reactions through F in the spaces provided. 1. Nah 1 Nal NaBH D 2. CH,CH,Bro CH,CH,OH CHCE 2 CH,CH,Br
2. (14 pts) Draw the major product for reactions H through M in the spaces provided. B12 NaOH BY2M 1. NaNH (3 equiv) : 1. Hg(OA)2, H2O. BH Cou' n 2. H2O 2. NaBHA J Acete K 105. L HOM HO Acetic acid M
Part II: Draw the structure of the major product for each of the following reactions: OH 1) NaBH, OCH, 2) H,0 OH CH O- mi + ,0 — HCC OCH 1) CH,MgBr/ ether 2) H₃0'
4. Synthesis Reactions. Draw the feature product of the following reactions. (8 x 3 pts) 1. Mg Ph Br 2. CO2 3. H a "NH2 Ph 1. NaOH, CI 2. LAIH b. CHỊCH NHA NaBHgCN, H+ Ph C. Br (excess) NH d NaOH H HO OH H CH e. 1. NaOH H2O NH 2. H+ o= 1. NaOH H2O 2. SOCI N(CH3)2 3 HO
Draw the major product for the following reactions. -OH 2. Draw the major product for the following reactions. 1) TSCI 2) NaOEt, Heat 3) O; 4) DMS 1) NBS, heat (I cq.) 2) NaNH, DMSO 3) KMnO4 (aq) NaOH, cold 4) NaOCI, acetic acid 1) O 2) H,0 3)NI, H, 150, 100 atm 1) RBH 2) H.O, NaOH 3) NBS, heat (I eq) 1) KMnO heat 2) Na, NH, CH OH 3) Bry, light (I eq) 1) NBS, light 2)...
(10 pts) Predict the major product for each of the following reactions. 2. Ho Br 1. NaOH/Br 2. H,O NaOH/H20 1. NaOCH,CH 2. H,0 1. NaOCH,CH, 2 HO (10 pts) Predict the major product for each of the following reactions. 2. Ho Br 1. NaOH/Br 2. H,O NaOH/H20 1. NaOCH,CH 2. H,0 1. NaOCH,CH, 2 HO
7. Draw the structure of the missing major organic product(s) for each of the following reactions. There is no “No Reaction in any of the answers. Show correct stereochemistry when needed! NO ON Na S204 (excess) NaOH, H20, heat Sebacoyl chloride PhCH OH OH (excess) 0 H2SO4, heat Aryl Bromide 1) Mg, THF 2) CH2=0 3) H20, H307 PhCH,CH,OH1 H2SO4 (catalytie) T heat H2Cro (excess)
Draw the product of the following reaction in the box provided. Draw the product of the following reaction in the box provided. HO HO K,Cr,0,1H,SO ОН (excess) Draw the product of the following reaction in the box provided. v Hcro, H,Cro, OH Draw the product of the following reaction in the box provided. PCC OH CH CIR Draw the product of the following reaction in the box provided. MgBr Draw the product of the following reaction in the box provided....
14. (4 points each) Complete the following reactions showing the major organic product). 2 CH,NH CH CH,OH Ci pyridine 2. 2CH,NH2 Ci AICl I. excess CH,MgBr 2. H CH,CH,CH OH NaOH 14. (4 points each) Complete the following reactions showing the major organic product). 2 CH,NH CH CH,OH Ci pyridine 2. 2CH,NH2 Ci AICl I. excess CH,MgBr 2. H CH,CH,CH OH NaOH
17. Draw the structure of the major organic product(s) for each of the following reactions. Indicate stereochemistry when appropriate. C(CH3)3 NASH Br (S)-2-bromononane - acetonitrile KOH CH,OH NaCN HE Br Acetonitrile C2H5 H, Br NaOH Acetone excess HBr ROOR HC1 + Br Na o DMSO