(10 points) Provide the Starting Materials/Reagents/Major Products for the following transformations. YOU MUST INDICATE STEREOCHEMISTRY AS...
1. Predict the major product of the reaction. Clearly indicate stereochemistry, if necessary (3 pts) Ph H2 Lindlar cat. hexanes Me 2. Provide reagents to achieve the shown multi-step transformations. (6 pts) Br CH 3. Draw a detailed arrow-pushing mechanism for the following transformation. (4 pts) OME B OMe Me Me NaOH H2O2 Me Me H
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1. Predict the major product of the reaction. Clearly indicate stereochemistry, if necessary (3 pts) H 1.9-BBN-H THE Me Me 2. NaOH H202 2. Provide reagents to achieve the shown multi-step transformations. (6 pts) H Me Me Br Br Me Br Br 3. Draw a detailed arrow-pushing mechanism for the following transformation. (4 pts) Ph Li(0) Ph Ph Ph NH30)
3. (28 pts) Draw the starting material, reagents, or major products of the following reactions. Indicate stereochemistry where relevant. - 5 mino cat. NaOCH CH, OH bo He° °CH °CH, Z HOA L ambe also THF, CO, : HO. HO H. CH, OH en generall HD, HD
2. REAGENTS: Provide the reagents needed to accomplish the following transformations. Clearly indicate if you need to use more than one step. (12 pts.) - گره م . = . . - م م ه م . .. 3. MECHANISMS: Provide complete, arrow-pushing mechanisms for each of the reactions shown below. Only TWO of these will be graded but YOU MUST COMPLETE ALL FOUR TO EARN ANY CREDIT! (8 pts.) | مو | (note: only mechanism for step 1) 1....
1. The following reactions begin with starting materials of differing stereochemistry yet each provide the same stereoisomer of the product. Explain this observation using an arrow-pushing mechanism Tso сH,со; CH-со,н TsO CH,со, CH3CO2H
1. The following reactions begin with starting materials of differing stereochemistry yet each provide the same stereoisomer of the product. Explain this observation using an arrow-pushing mechanism. Tsoo- сн,со, CH3CO2H CH,CO, CH3CO2H
II. Reactions: Predict the major organic product(s) or write the appropriate reagents/starting materials for the following reactions. Indicate stereochemistry and regiochemistry when appropriate. Indicate reactions that are expected to result in a racemic mixture of products DBr 1. Н.О, CHCI он HSO, heat кон 1) вн, THF 3. 2) H202. HO 1) Hg(OAc)2, CH,OH 2) NaBH, OH 5. Br2 SH 6. HIO4 OH THF, H2O "он III. Synthesis: Starting from the alkenyl bromide below, devise a synthesis that produces the...
1) Please show appropriate major products or reagents for the following transformations (indicate regio- and stereochemistry as appropriate): (沭! A ? HBr 1) CH3CH2MgCl 2) Dil. aq. HCI C?
Q 10 - Synthesis question. Show how the starting material can be converted to the product through any of the reactions you have learned in Ochem-l and Ochem-Il. Show all the reagents you need and indicate the stereochemistry when appropriate. You do not need to show arrow pushing like in a mechanism question, only the reactions. If a chiral molecule is formed mark the chiral center with an asterisk (*) and write "racemic" below the structure. All carbon atoms in...
012- Synthesis question A-L. Show how the starting material can be converted to the product through any of the reactions you have learned in O.Chem-I and O.Chem-I1. Show all the reagents you need and indicate the stereochemistry when appropriate. You do not need to show arrow pushing like in a mechanism question, only the reactions. If a racemic mixture is formed indicate the chiral center/s with an ASTERISK( and write racemic next to the structure. All carbon atoms should come...