Question

(10 pts) The graph below shows solubility vs. pH for five solids (where solubility in M is the same as the dissolved metal cations). These solids are hydroxides of chromium (Cr), aluminum (Al), nickel (Ni), and iron (Fe in II and III oxidation states; often referred to as ferrous and ferric iron). Use this graph to answer parts a-c below.

  1. a) Which solid is among the least soluble at pH 12 and among the most soluble at pH 6?
  2. b) Over what pH range would it be possible to precipitate nickel hydroxide while leaving aluminum fully dissolved?

1.E+0 | * 1.E-01 - - -- - -Cr(OH)3| -- -Al(OH)3 +-Fe(OH)3 +-Ni(OHP --FeroHI2 * 1.E-02 1 1.E-03 X 1.E-04 Cations (moles: 1.E-0

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Answer #1

(a) from graph at pH = 12; least at PH=6; most (6) PH >7 clearly pH> 7; soluble. soluble. NiCOH)2 Fe (OH) from graph.

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