For each of the following transition metal complexes, determine the oxidation state of the metal, its...
2. Determine the oxidation state of the metal in each of the following coordination complexes: (a) Mn (CO). (b) [Re:Br2] ; (c) [Fe(H20).(OH)2]; (d) (CO(NH3),C1]
6 Identify the coordination number (C.N.), metal oxidation state(O.S.) and the number of metal d electrons for each of the following complexes. (a) [Ni(CN):) C.N. = _ ; O.S. = __, d-electrons = d-electrons = (b) [Pd(Cl)]2 C.N. = _ ; O.S. = ___, d-electrons = (c) [Cr(CN)]C.N. =__; O.S. = —, (d) [Fe(CO).]? C.N. = __; O.S. = ___, d-electrons =- (e) [Cr(CI):]& C.N. = ___; O.S. = __, d-electrons = (1) [Ag(CN)2] C.N. = ___; O.S. = ___,...
6 Identify the coordination number (C.N.), metal oxidation state(O.S.) and the number of metal d electrons for each of the following complexes. (a) [Ni(CN)s] C.N. = __;0.S. = ___, d-electrons = (b) (Pd(C1).]C.N. = ____; O.S. - ___, d-electrons = (c) (Cr(CN)] C.N. - ___.O.S. = ___, d-electrons = (d) [Fe(CO).)? C.N. = ___; O.S. = ___, d-electrons = (e) (Cr(Cl)s) C.N. = ____ ; O.S. = ____ d-electrons =_ (1) (Ag(CN)2] C.N. = _ ; O.S. = _ ,...
1. Name the following transition metal complexes AND give the coordination number for each metal in the complex ion: Name Coordination # (a) K[Fe(CN).] (b)Ks[Fe(ox).] (c) Cr(en).]C13 (d) (Cr(NH3):(HO)](NO3) (e)ky [Cr(NH3),Cla]
Determine the oxidation state and coordination number of the metal ion in each complex ion. [Cu(CN)2]1- [Ag(NH3)2]1+ [Cu(OH2)4]2+ [Pt(NH3)2Cl2] [Fe(CN)6]4- [Fe(OH2)6]2+ [Zn(CN)4]2- [Cd(NH3)4]2+ [Cu(CO)5] [CuCl5]3- [Fe(EDTA)]2- [Pt(en)2]2+
(b) Determine the oxidation state of the metal, the d electron configuration, the number of unpaired electrons and the ligand field stabilisation energy for the following complexes: (i) [Co(NH3)5Br]2+ (ii) [MnO4]- (iii) [Fe(CN)6]3- (iv) [Cu(H2O)6]2+
O THE TRANSITION METALS Determining the oxidation state of the metal in a coordination... Determine the oxidation state of the transition metal in each of these coordination compounds. compound oxidation state of the transition metal K,[Coc (1,0), D [TiBr(co),]CI [MocI,(NH) ]c, O THE TRANSITION METALS Naming complex cations with one type of ligand Write the chemical formula of the following complex ions. formula name tetraaquachromium(III) pentacarbonylcobalt(III) hexaaquairon(III)
Calculate the (a) oxidation state of the metal and (b) the coordination number. Which of the following complexes has the highest value of the sum, a +b. The spectrochemical series is i <Br" <CI <F <OH <H20 < NH; <en< NO, <CN Select one: A. Two of complexes have the same highest value of the sum, a +b. B. Na[Cr(NH3),C13] C. [Ni(H20),(NO2)2] D. [Co(en) CICI E.K_[Cu(CN),
Q1) For each of the following compounds, determine the formal oxidation state of the transition metal and the corresponding number of d electrons. State whether each one is likely to be stable enough to be characterized. (1) [Re(CO)5] (2) [HFe(CO)4]- (3) ((ŋ6-C5H5)2Fe) (4) ((ŋ6-C6H6)2Cr) (5) ((ŋ5-C5H5)ZrCl(OCH3) (6) (IrCl(PPh3)3) (7) (Mo(CO)3(PPh3)3) (8) (Fe(CO)4(C2H4)) (9) (W(CO)5Cl)- (10) Ni(CO)4)Q2) Use the 18-electron rule to predict the number of carbonyl ligands, n, in each of the following complexes: (1) [Cr(CO)n] (2) [Fe(CO)n(PPh3)2)] (3) [Mo(CO)n(PMe3)3] ...
For each of the following metal complexes, specify the number of ligands, the coordination number of the metal, the oxidation number of the metal, the geometry of the complex and draw the structure. Transition metal complexes with four ligands usually form tetrahedral structures unless the metal has a d8 configuration, in which case it can form either tetrahedral or square planar structures. NH4[Co(NCS)4(py)2] [RhBr(CO)5](NO3)2 K4[Fe(CN)6] [HgI4]2- [Cu(NH3)4]Cl2