1. Name the following transition metal complexes AND give the coordination number for each metal in the complex ion...
For each of the following metal complexes, specify the number of ligands, the coordination number of the metal, the oxidation number of the metal, the geometry of the complex and draw the structure. Transition metal complexes with four ligands usually form tetrahedral structures unless the metal has a d8 configuration, in which case it can form either tetrahedral or square planar structures. NH4[Co(NCS)4(py)2] [RhBr(CO)5](NO3)2 K4[Fe(CN)6] [HgI4]2- [Cu(NH3)4]Cl2
For each of the following transition metal complexes, determine the oxidation state of the metal, its coordination number, and the number of d electrons on that metal. (a) RuO4 (b) (CO(NH3).]3+ (c) [Cr(H2O).]8+ (d) Cr(H2O)3Cl2 (e) [Fe(H2O).]3+ (1) (Co(NH3).]2+ (9) MOCI (h) (Pt(CN)4]2- () [Mn(H2O).]2+ (1) Re(CO).Br (k) (Ag(CN 2] (1) [ReH9]?
Enter the coordination number for the transition metal in each compound. Note: Due to requirements to build this question, the complex ion is enclosed in { } rather than square brackets. K{Fe(H2O)2(ox)2} {Co(H2O)4(CN)2}Cl {Mn(NH3)4}Br2 {Ni(acac)2} {Cu(NH3)2}2SO4 Ca{MnEDTA}
Give the coordination number of the central metal ion in the following complex ions. a. [Ni(en)2(NH3)2]2+ b. [Fe(en)(ox)Cl2]- Please explain how you got them too? thanks
Determine the oxidation state and coordination number of the metal ion in each complex ion. [Cu(CN)2]1- [Ag(NH3)2]1+ [Cu(OH2)4]2+ [Pt(NH3)2Cl2] [Fe(CN)6]4- [Fe(OH2)6]2+ [Zn(CN)4]2- [Cd(NH3)4]2+ [Cu(CO)5] [CuCl5]3- [Fe(EDTA)]2- [Pt(en)2]2+
2. Give a systematic name for each of the following compounds, and give the number of d electrons for the transition metal: a. Cs2[FeCl4] b. W(CO)6 c. Na2[Cr(CO)5] d. [Ni(NH3)2(en)2](PF6)2 (PF6 is a (1-) ion, and is named as if phosphorus were a metal) e. [Ru(CN)6]3– f. K[OsF6]
Complete table C.N is coordination number O.N is Oxidation number Complex Formula C.N O.N of the metal Cationic or anionic complex Name of metal complex K4[Ni(CN)4] [Cr(OH2)4Cl2]Cl Na3[Co(C2O4)3] [CoCl2(en)2]F [Co(P(CH3)3)4]2(SO4)3 [Fe(NH3)6]SO4 Na2[MoOCl4] [Cr (NH3)6]Cl3 [Zn(OH)4]-2 [V(OH2)6](NO3)3
Calculate the (a) oxidation state of the metal and (b) the coordination number. Which of the following complexes has the highest value of the sum, a +b. The spectrochemical series is i <Br" <CI <F <OH <H20 < NH; <en< NO, <CN Select one: A. Two of complexes have the same highest value of the sum, a +b. B. Na[Cr(NH3),C13] C. [Ni(H20),(NO2)2] D. [Co(en) CICI E.K_[Cu(CN),
4. Give chemical names for the following coordination complexes. a) [Cu(NH3)4]2+ b) [Pt(NH3). Cl]* c) [Mn(CN):)". d) (Co(en)2(PPha)]PO... e) [Ni(bipy)](NO3)2. 5. Give chemical formulas for the following coordination complexes. a) Triammineaquadichlorocobalt(III) chloride. b) Potassium diaquabis(oxalate)manganate(III). c) Tris(acetylacetonato Jiron(III). d) Tri--carbonylbis(tricarbonyliron(O)). e) Li-oxo-bis(pentaamminechromium(III)). 5. Draw a d-orbital energy-level diagram, and predict the number of unpaired electrons. a) [Fe(CN).] b) [Fe(H20):] c) (CoCil (tetrahedral) 6. Of the two complexes (a) (CoFs] and (b) (Coſen)] + one appears yellow and the other appears...
2.(1) What does it mean when we say a transition metal complex (or a molecule) is chiral? 3.(3) Give the name or formula, as appropriate, for: a) [Co(CO)s]CO3 b) Ks[Fe(CN) 6] c) diaquabis(ethylenediamine)chromium(II) nitrate 4.(3) Give the coordination number, geometry, and hybridization of cobalt in [Co(NO2)2(en)2]2 5.(5) Draw all possible isomers of [CrNH)h(en)FJ. Label them as either geometrical or optical.