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9. Considering the compounds a)-1) in #5, whicho -1) in #5, which one(s) would give: a...
5) Provide a structure consistent with all of the data for the following compounds. Unless otherwise...
5) Provide a structure consistent with all of the data for the following compounds. Unless otherwise stated, the IR data is not all inclusive, i.e. you may propose a structure which would include peaks not specifically noted but your structure must account for the peaks which are listed or which are excluded. a) Compound Q (C6H100) decolorizes Br2/CC14. IR peaks at 3500 cm- and 1640 cm"! NO absorption between 1700 and 1800 cm? b) Compound K (C6H100) does not decolorize...
Qualitative analysis lab Give structures for the following aromatic compounds. e. p-methylphenol 2. Give structures for...
Qualitative analysis lab
Give structures for the following aromatic compounds.
e. p-methylphenol 2. Give structures for the following aromatic compounds: a. A (C H10) positive 2,4-DNP; positive iodoform. b. B (C,HO) insoluble in NAOH; positive 2,4-DNP; negative iodoform hot KMnO, oxidation yields p-methoxybenzoic acid. c. C (C,H0,) soluble in NaHCO oxidation with KMn0, yields phthalic acid; IR peak at 1690 cm d. D (C,H,0,) soluble in NaHCO oxidation with KMnO, yields phthalic acid; IR peak at 1710 cm e. E...
5-14) A compound A has a strong, broad IR absorption at 3200–3500 cm–1 and the proton...
5-14) A compound A has a strong, broad IR absorption at
3200–3500 cm–1 and the proton NMR spectrum shown below. Treatment
of compound A with H2SO4 gives compound B, which has the NMR
spectrum shown at bottom and a molecular ion at m/z = 84 in its EI
mass spectrum. Identify compounds A and B.
Question 5 of 5 A compound A has a strong, broad IR absorption at 3200-3500 cm 1 and the proton NMR spectrum shown below. Treatment...
1. (6 pts) These are some of the preliminary tests that you will be doing on days 1-2. For each test, write down what type of molecule would give a positive test and what a positive result would...
1. (6 pts) These are some of the preliminary tests that you will be doing on days 1-2. For each test, write down what type of molecule would give a positive test and what a positive result would look like. DNP: Solubility Beilstein: Ignition: 2. (2 pts) For the 2,4-dinitrophenylhydrazine test, write a chemical reaction between that reagent and one of the "known" compounds that would give a positive result. 17
1. (6 pts) These are some of the preliminary...
How would you use IR and 1H-NMR spectroscopy to distinguish between these two isomeric compounds? For...
How would you use IR and 1H-NMR spectroscopy to distinguish between these two isomeric compounds? For IR, consider the absorption of the carbonyl group. For 1H-NMR, consider the number of signals observed. Select the IR frequency and number of NMR signals that is diagnostic for either isomer a or isomer b. Isomer A: N-methylbutanamide Isomer B: N,N-dimethylpropanamide IR: _______ cm-1 a-1680 a-1690 a-1735 a-1810 a-2250 b-1650 b-1690 b-1710 b-2250 1H-NMR: _____ signals a-4 a-5 b-3 b-4 b-5 b-6
S and give the m 0~시 2. How could you distinguish the following pairs of isomeric compounds usin...
s and give the m 0~시 2. How could you distinguish the following pairs of isomeric compounds using IR and MS? For some pairs- one of these spectral techniques may be different enough to distinguish the compounds. and (b) and 3. Analyne the IR and MS spectra below to predict a possible structure for each compound. Label the major peaks or (a) C,110 1500 1000 (b) CsHro 3000 2000 1500 1000 m/z ollowing problem is to ys ar wwight of...
6. Figure 21.13 (page 324) shows the IR spectrum of polystyrene. Which functional groups are present...
6. Figure 21.13 (page 324) shows the IR spectrum of polystyrene. Which functional groups are present in polystyrene? Which bands tell you this information? (give approximate wavenumbers) Transmission IR ATR IR 500 4000 3500 3000 2500 2000 1500 1000 Wavenumbers (cm) FIGURE 21.13 Comparison of (top) a transmission spectrum of polystyrene with (bottom) an ATR spectrum of polystyrene. Strong peak between 1820-1600 cm 1? YES NO Carbonyl Present Look for "companion" peaks broad 3400-2400 cm! (O-H) Carboxylic Acid medium (maybe...
1. Using the IR correlation table on the second image, indicate how you could distanguish between...
1. Using the IR correlation table on the second image,
indicate how you could distanguish between the following pairs of
compounds by using infrared spectroscopy. Give two specific
absence/appearance of wavrnumbers for each compound:
2. For this experiment, what is the purpose of adding acetone?
Predict what would happen if you omitted the acetone in the
experimental procedure.
3. Draw four different resonance structures of the
triphenylmethyl cation.
*IR correlation table
PRE-LAB QUESTIONS 1. Using the IR correlation table on...
Match the following spectral descriptions with one of the compounds shown below. A compound is NOT...
Match the following spectral descriptions with one of the compounds shown below. A compound is NOT used more than once. [ Select] AC4HO2 compound has a strong IR absorption at 3300-3400 cm-1. The 1 H NMR spectrum has two singlets at 8 4.2 and 4.4 ppm: relative areas 4:2..The 13C spectrum shows 2 signals at 8 85 and 52 ppm. [ Select] AC7HO compound has a strong IR absorption at 1700 cm?, The H NMR spectrum has a singlet at...
3) Four of the compounds below contain carbonyl functional groups. a). What stretching frequency will they...
3) Four of the compounds below contain carbonyl
functional groups.
a). What stretching frequency will they have in common? Name the
bond and typical cm^-1
b). Are there variations in the stretching frequency that you named
above for the different carbonyl functional groups? If so,
what?
Infrared Absorption Bands Frequency (cm ) Type of Vibration Intensity C-H Alkanes -CH --CH, Alkenes (stretch) (bend) (bend) (stretch) (out-of-plane bend) (stretch) (out-of-plane bend) (stretch) 3000-2850 1450 and 1375 1465 3100-3000 1000-650 3150-3050 900-690...
5) Provide a structure consistent with all of the data for the following compounds. Unless otherwise stated, the IR data is not all inclusive, i.e. you may propose a structure which would include peaks not specifically noted but your structure must account for the peaks which are listed or which are excluded. a) Compound Q (C6H100) decolorizes Br2/CC14. IR peaks at 3500 cm- and 1640 cm"! NO absorption between 1700 and 1800 cm? b) Compound K (C6H100) does not decolorize...
Qualitative analysis lab
Give structures for the following aromatic compounds.
e. p-methylphenol 2. Give structures for the following aromatic compounds: a. A (C H10) positive 2,4-DNP; positive iodoform. b. B (C,HO) insoluble in NAOH; positive 2,4-DNP; negative iodoform hot KMnO, oxidation yields p-methoxybenzoic acid. c. C (C,H0,) soluble in NaHCO oxidation with KMn0, yields phthalic acid; IR peak at 1690 cm d. D (C,H,0,) soluble in NaHCO oxidation with KMnO, yields phthalic acid; IR peak at 1710 cm e. E...
5-14) A compound A has a strong, broad IR absorption at
3200–3500 cm–1 and the proton NMR spectrum shown below. Treatment
of compound A with H2SO4 gives compound B, which has the NMR
spectrum shown at bottom and a molecular ion at m/z = 84 in its EI
mass spectrum. Identify compounds A and B.
Question 5 of 5 A compound A has a strong, broad IR absorption at 3200-3500 cm 1 and the proton NMR spectrum shown below. Treatment...
1. (6 pts) These are some of the preliminary tests that you will be doing on days 1-2. For each test, write down what type of molecule would give a positive test and what a positive result would look like. DNP: Solubility Beilstein: Ignition: 2. (2 pts) For the 2,4-dinitrophenylhydrazine test, write a chemical reaction between that reagent and one of the "known" compounds that would give a positive result. 17
1. (6 pts) These are some of the preliminary...
s and give the m 0~시 2. How could you distinguish the following pairs of isomeric compounds using IR and MS? For some pairs- one of these spectral techniques may be different enough to distinguish the compounds. and (b) and 3. Analyne the IR and MS spectra below to predict a possible structure for each compound. Label the major peaks or (a) C,110 1500 1000 (b) CsHro 3000 2000 1500 1000 m/z ollowing problem is to ys ar wwight of...
6. Figure 21.13 (page 324) shows the IR spectrum of polystyrene. Which functional groups are present in polystyrene? Which bands tell you this information? (give approximate wavenumbers) Transmission IR ATR IR 500 4000 3500 3000 2500 2000 1500 1000 Wavenumbers (cm) FIGURE 21.13 Comparison of (top) a transmission spectrum of polystyrene with (bottom) an ATR spectrum of polystyrene. Strong peak between 1820-1600 cm 1? YES NO Carbonyl Present Look for "companion" peaks broad 3400-2400 cm! (O-H) Carboxylic Acid medium (maybe...
1. Using the IR correlation table on the second image,
indicate how you could distanguish between the following pairs of
compounds by using infrared spectroscopy. Give two specific
absence/appearance of wavrnumbers for each compound:
2. For this experiment, what is the purpose of adding acetone?
Predict what would happen if you omitted the acetone in the
experimental procedure.
3. Draw four different resonance structures of the
triphenylmethyl cation.
*IR correlation table
PRE-LAB QUESTIONS 1. Using the IR correlation table on...
Match the following spectral descriptions with one of the compounds shown below. A compound is NOT used more than once. [ Select] AC4HO2 compound has a strong IR absorption at 3300-3400 cm-1. The 1 H NMR spectrum has two singlets at 8 4.2 and 4.4 ppm: relative areas 4:2..The 13C spectrum shows 2 signals at 8 85 and 52 ppm. [ Select] AC7HO compound has a strong IR absorption at 1700 cm?, The H NMR spectrum has a singlet at...
3) Four of the compounds below contain carbonyl
functional groups.
a). What stretching frequency will they have in common? Name the
bond and typical cm^-1
b). Are there variations in the stretching frequency that you named
above for the different carbonyl functional groups? If so,
what?
Infrared Absorption Bands Frequency (cm ) Type of Vibration Intensity C-H Alkanes -CH --CH, Alkenes (stretch) (bend) (bend) (stretch) (out-of-plane bend) (stretch) (out-of-plane bend) (stretch) 3000-2850 1450 and 1375 1465 3100-3000 1000-650 3150-3050 900-690...
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