Question

7. A low concentration of NTA has equilibrated with PbCO3(s) at pH 7.00 in a medium having a final HCO3- concentration of 7.50x10-4 M.

a. Determine [Pb2+].

b. Write out KT and the overall reaction for KT.

c. What is the ratio of [Pb(NTA)- ] to [H(NTA)2-] in this solution?

Potentially useful data: Reaction Hg 2 +2e = Hgº(s) Feste = Fe2 Cu 2 +2e = Cuº(s) 2H + 2e = H2(g) Pb2 +2e=Pbº(s) Ca*2 + 2e =

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NTA equilibrium with PbCO3 at pH 7.00,

​Pka = -logKa

Pbcoz (s) As poet & co? Ksp = [Pb 2+ ] [ cor- . - - lig HINTA) 2- Kal H+ + (NTA) Ra= [H * ] [INTAI? Si -_ [H (NTA)2) Pb²+ +IN(a) from ean (i) Ksp = [Pb2+) [ron? os s²= Ksp 5 sakse } for Pb CO₂ (s) = 51.5lX90 13 ) Ksp = 1.57X10 = 3.89 x 107 concentrat

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