MAD ORG. CHEM. MIN. F2B Identify the functional groups present in each of the compounds below...
IR Worksheet-CHEM 2460 Spectrum A- Fare the IR spectra of the compounds shown, In Spectrum A-F, assign the major absorptions above 1500 em in the spectrum of each compound, (using and 8 2 [see background informationD) A. IR spectra of phenylethyne 100 80 40 20- 4000 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000800 Wavenumber (cm) IR spectra of n-butyl acetate 100 B. 80 60 40 CHsCO(CH2)30% 20 4000 3600 3200 2800 2400 2000 1800 1600 1400 1200...
6. An unknown compound, CsH10O2, gives the NMR and IR shown below. Propose a structure. wavelength (m) 9 10 11 12 13 14 15 16 100 80 60 40 20 ol 4000 3500 3000 2500 1400 1200 1000 800 2000 1800 1600 wavenumber(cm) 600 SOHE 5.5.6 7.11 70 690 200 156 LA 1.6 10 8 (ppm)
2. The following IR spectra each include the structure of the corresponding compound directly on the spectrum (continued on following pages). • Based on the given structures and the information provided in Tables 8.1 and 8.2, assign as many of the major absorptions as possible directly on the spectra o indicating what type of bond O and whether it corresponds to bending or a stretching vibration. Transmittance (%) 0 + 4000 3600 3200 2000 2400 1400 1200 1000 800 600...
9. (a) Identify the major signals and the corresponding bond types present in the compound having the following IR spectrum; Molecular formula CizH17NO2 (3 pts) 2.5 J00 3.5 4.5 5.5 6 7 8 9 10 11 12 13 14 15 16 80 60 40 20 ol 4000 2500 1400 1200 3500 3000 2000 1800 1600 wavenumber (cm 1000 800 600 (b) The 'H-NMR shown below is that of the same compound with the IR spectrum shown in (a). Determine its...
Spectrum A - Fare the IR spectra of the compounds showna. In Spectrum A -F. assign the major absorptions above .-1500 cm. in the spectrum of each compo and, (using Tables and 8 2 Isee background information). section C. IR spectra of N.N-dimethylacetamide 100 60 40 CH CN(CHsh 20 0-T 4000 3000 3200 2000 2400 2000 1 1600 1400 1200罒… Waverumtor (cmr*) D. IR spectra of diethyl ether (Also assign the peak at 1 1 10 cm-1) 100 80 60...
B/ You have absorption spectra for: 1/ Methylbenzene 3/1,3 Dimethylbenzene 2/ 1,2 Dimethylbenzene 4/1,4 Dimethyl benzene Connect each of the four structures to the corresponding compound, with the Inference: 1 2500 2000 1800 1600 1400 1200 1000 800 600 3500 3000 Frequency cm 8 9 10 12 15 3500 3000 2500 2000 1800 1600 1400 1200 1000 800 600 Frequency cm-1 The spectrum refers to the Geometrical Isomerism: The most important absorptions is:
Determine whether the compound is an akane, an alkene, an alkyne, or an aromatic hydrocarbon. More than one unsaturated group may be present. wavelength (am) 2.5 100b 33,5 4 4,5 5 5,5 6 7 89 10 11 12 13 14 15 16 80 60 N 40 T 20 4000 3500 3000 2500 2000 1800 1600 1400 1200 1000 800 600 wavenumber (em- Check all that apply. a alkane alkene alkyne Q aromatic hydrocarbon Previous Answers Request Answer
B. Determine the structure of and name the compound that gives rise to the following mass and IR spectra. 100 43 50 100 40 100 120 mlz waveiengin 3.5 4 4.5 5 5.5 6 7 8 9 10 11 12 13 14 15 16 100 80 800 2000 1800 1600 1400 1200 1000 2500 3000 3500 4000 wavenumber (cm
Draw the infrared spectrum of 3-butin-2-ol. Identify and assign the spectrum bands including vibrational mode. UUUUUU. UU.UU 4. Dibuja el espectro de infrarrojo de 3-butin-2-ol. Rotula y asigna las bandas incluyendo el modo vibracional al que corresponden. wavelength (um) 3 3.5 4 4.5 5 5.5 6 6.5 7 8 9 10 11 12 14 16 percent transmittance 4000 3500 3000 2500 1400 1200 1000 800 600 2000 1800 1600 wavenumber (cm )
6) Which compound would produce this IR spectrum? Wavelength, (um) 3,5 4 4,5 5 5,5 6 6,5 7 8 9 10 12 14 18 2.52,7 3 100 80 s 60 40 a 20 0 e 4000 3500 3000 2500 2000 1800 1600 1400 12001000 800 600 400 Wavenumber, (cm-1) (A) (В) CH СОН (C) (D) CH3 СОСН) 7) Which compound is consistent with this IR spectrum? Wavelength, (um) 1003.2 2,4 2.6 3 3,5 4 4,5 5 5,5 6 7 89...